New Technology Ventures, Inc.

Phillips Petroleum Company

Chemical Products Industries, Inc.

Capshew, Charles E.

Farha, Floyd E., Jr.

Miro, Nemesio D.

Floyd E Farha

Veronica M Irurzun

Max P McDaniel

Emory W Pitzer

James A Kane

Eugene C Fendley, Ii

Max P Mcdaniel

The invention involves the formation of a sulfided stable iron (II) compound from an iron (II) oxide and/or hydroxide and where the molar ratio of sulfur to iron (II) is greater than 1. Preferably these oxides and/or hydroxides are present as nanoparticles in the 5-10 nanometer range. It has been discovered that such particles can be formed at lower cost and with fewer impurities by using ferrous carbonate (FeCO) from siderite as compared to known processes from various iron salts such as sulfates and chlorides.

Sulfided iron (II) compound and method of manufacture

The invention involves the formation of a stable iron (II) oxide and/or hydroxide. Preferably these oxides and/or hydroxides are present as nanoparticles in the 5-10 nanometer range. It has been discovered that such particles can be formed at lower cost and with fewer impurities by using ferrous carbonate (FeCO) from siderite as compared to known processes from various iron salts such as sulfates and chlorides. The novel nanoparticles are particularly adapted to removing sulfur compounds such as HS from liquid and/or gaseous streams, such as hydrocarbon streams.

Highly active nano iron catalyst for the absorption of hydrogen sulfide

Finely divided ferrous carbonate absorbent, siderite granules or absorbent particles made by mixing, agglomerating and shaping finely powdered ferrous carbonate, preferably siderite, in combination with minor effective amounts of water or an optional binder, followed by drying, are used to treat and significantly reduce concentrations of hydrogen sulfide, carbonyl sulfide, organic disulfides, mercaptans and other sulfurous compounds and contaminants in gaseous and liquid fluid streams such as natural gas, light hydrocarbon streams, crude oil, acid gas mixtures, carbon dioxide gas and liquid streams, anaerobic gas, landfill gas, geothermal gases and liquids, and the like. Methods for absorbing sulfur compounds in a moist atmospheric environment and for regenerating the absorbent by contacting it with air and steam or, continuously, by mixing the feed stream with moist air are also disclosed.

Sulfur removal using ferrous carbonate absorbent

A method of using a sulfided iron reagent to remove oxygen from gaseous and liquid fluid streams such as natural gas, light hydrocarbon streams, crude oil, acid gas mixtures, carbon dioxide gas and liquid streams, anaerobic gas, landfill gas, geothermal gases and liquids, and the like is disclosed. In a preferred embodiment, the reagent is made by mixing, agglomerating and shaping finely powdered ferrous carbonate, preferably siderite which are used to remove oxygen from a hydrocarbon or carbon dioxide stream that also contains sulfur compounds such as hydrogen sulfide.

Method for reducing oxygen content of fluid streams containing sulfur compounds

Finely divided ferrous carbonate absorbent, siderite granules or absorbent particles made by mixing, agglomerating and shaping finely powdered ferrous carbonate, preferably siderite, in combination with minor effective amounts of water or an optional binder, followed by drying, are used to treat and significantly reduce concentrations of hydrogen sulfide, carbonyl sulfide, organic disulfides, mercaptans and other sulfurous compounds and contaminants in gaseous and liquid fluid streams such as natural gas, light hydrocarbon streams, crude oil, acid gas mixtures, carbon dioxide gas and liquid streams, anaerobic gas, landfill gas, geothermal gases and liquids, and the like.

A process for the removal of trace metals from a hydrocarbon stream includes contacting the hydrocarbon stream with an absorbent material comprising antimony pentoxide supported on an absorbent substrate. The hydrocarbon product is then withdrawn from the absorbent material to provide a purified product in which 99.5 wt. % of the trace metal has been removed. Preparation of the antimony pentoxide-promoted absorbent entails treating a particulate porous substrate with an aqueous solution of antimony pentoxide. The absorbent substrate has an average particle size within the range of 1-5 mm and an average pore volume within the range of 0.7-0.85 cubic centimeters per gram. At least 80% of the surface area of the support is contained within the internal pore volume of the absorbent. The absorbent support is contacted with the antimony pentoxide solution. Once the solution has been applied to the support, the mixture is agitated to ensure even distribution of the antimony pentoxide in the internal pore volume of the support. The antimony pentoxide support is then dried at an elevated temperature.

Promoted absorbents for the removal of contaminants

Fine, pure, boehmite alumina crystallites are peptized, partially precipitated and phosphated, hardened, and dried to form a zerogel. The alumina can be impregnated with a chromium compound. The chromium-containing catalyst is activated by calcination. The activated catalyst can be used as a polymerization catalyst to polymerize mono-1-olefins.

Growing community of inventors

Oklahoma City, OK, United States of America

Floyd E Farha