Heraeus Deutschland Gmbh & Co Kg

Heraeus Precious Metals Gmbh & Co. Kg

Florian Eweiner

Richard Walter

Walter Lässig

Christian Neumann

Jörg Becker

Sascha Pihan

Julie Michaud-Bernlochner

Dominik Samuelis

Jörg Fuchs Alameda

Rainer Kiemel

Christian Breuer

Leonard Stoica

Gabriele Przibilla

Mark Neuschütz

Walter Låssig

Walter Laessig

Markus Nesselberger

Nadia Kuwertz

Frédéric Hasché

Rianne Schöffler

Walter Lassig

Jorg Fuchs Alameda

Frederic Hasche

Claudia Ramirez Castro

The present invention relates to a method for producing a membrane for a fuel cell or electrolytic cell, in which (i) a liquid coating composition, which contains a supported catalyst containing precious metal and also contains an ionomer, is applied to a polymer electrolyte membrane which contains an ionomer, the ionomer of the liquid coating composition and the ionomer of the polymer electrolyte membrane each being a copolymer which contains as monomer a fluoroethylene and a fluorovinyl ether containing a sulfonic acid group, (ii) the coated polymer electrolyte membrane is heated to a temperature in the range from 178° C. to 250° C.

Method for producing a catalyst-coated membrane

Method for the production of tetrakis(trihydrocarbylphosphane)palladium(0) in organic solvent, whereby 50 to 100% by weight of the organic solvent consist of at least one polar-aprotic solvent, characterised in that a) at least one palladium compound selected from the group consisting of palladium(II) compounds and palladium(IV) compounds that are soluble in the organic solvent is reacted with b) at least one base, selected from the group consisting of alkali metal hydroxides, alkali metal carbonates, alkali metal hydrogen carbonates, alkali metal-C-C-alcoholates, ammonium carbonate, ammonium hydrogen carbonate, alkaline earth metal hydroxides, alkaline earth metal carbonates, alkaline earth metal hydrogen carbonates, alkaline earth metal-C-C-alcoholates, and alkylamines with a total of 2 to 12 carbon atoms; c) at least one trihydrocarbylphosphane; and d) at least one organic reducing agent that is different from the remaining components that are used in the method.

Method for producing tetrakis (trihydrocarbyl phosphane) palladium(0)

Method for the production of tetrakis(trihydrocarbyl phosphane)palladium(0)

A known method for producing porous graphitized carbon material covered with metal nanoparticles involves infiltrating a porous template framework of inorganic material with a carbon precursor. After thermal treatment of the precursor, the template is removed and the particulate porous carbon material is covered with a catalytically active substance. According to the invention, in order to keep the proportion of the noble metal loading at a low level, the thermal treatment of the precursor first involves carbonization, and the material is not graphitized into graphitized, particulate, porous carbon material until the template has been removed. The graphitized carbon material has a hierarchical pore structure with a pore volume of at least 0.5 cm/g and at least 75% of the pore volume is apportioned to macropores with, size 100 to 5000 nm. Before covering with catalytically active substance, the carbon material is subjected to an activation treatment in an oxidizing atmosphere.

Catalyst support and method for producing porous graphitized carbon material covered with metal nanoparticles

The production of noble metal oxalate complexes from noble metal precursors and oxalic acid and/or oxalic acid salts is an exothermic reaction, in which heat and COare produced, is described. The temperature can increase above the decomposition point of the noble metal oxalate complexes in the course of the reaction, which simultaneously releases more CO. For safety reasons, when the reaction is carried out on a large scale, it is therefore necessary to take into consideration that the product must not be decomposed by heat that is produced during the reaction. Therefore, according to the invention, a method for the production of noble metal oxalate complexes is provided, in which the product noble metal oxalate complexes are added to the reaction mixture as an auto-catalyst.

Method for the production of noble metal oxalate complexes

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Hanau, Germany

Florian Eweiner