Technic, Inc.

Florence P Butler

Harry H Kroll

Therese R Souza

Michael D Gernon

Hanoch S Elroi

Brenda A DeCesare

This invention relates to additives for methanesulfonic acid based tin and tin alloy plating formulations. Specifically, the invention involves the use of gallic acid in the multiple roles of antioxidant, grain refiner, selective precipitant, and selective chelator in methanesulfonic acid based tin or tin alloy plating formulations.

Gallic acid as a combination antioxidant, grain refiner, selective

Heteroaromatic compounds having at least two nitrogen atoms may be used to regulate consistency of alloy content and of deposit thickness. Modified nonionic surfactants which lack terminal hydroxy groups are used as grain refiners having low tendency to cause foam build-up in electroplating baths. Dioxolanes may be used to produce deposits having, as desired, a white uniform matte, a semi-bright plate, or a mirror bright surface. Antioxidants are used to prevent oxidation of divalent tin.

Additives for electroplating compositions and methods for their use

Heteroaromatic compounds having at least two nitrogen atoms may be used to regulate consistency of alloy content and of deposit thickness. Modified nonionic surfactants which lack terminal hydroxy groups are used as grain refiners having low tendency to cause foam build-up in electroplating baths. Dioxolanes may be used to produce deposits having, as desired, a white uniform matte, a semi-bright plate, or a mirror bright surface.

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Smithfield, RI, United States of America

Florence P Butler