Sumitomo Chemical Company, Limited

Cambridge Display Technology Limited

Sumitomo Chemical Companylimited

Sumitmoor Chemical Company Limited

Florence Bourcet

Sheena Zuberi

Kiran Timothy Kamtekar

Thomas Kugler

Martin Humphries

Ruth Pegington

Jonathan Nigel Pillow

Annette Steudel

Richard J Wilson

James Morey

Jean-Benoit Giguere

Matthew Roberts

William Tarran

Tania Zuberi

Michael Cass

Simon King

Martina Pintani

Robert Sidney Archer

Yonek Hleba

Andrey Nikolaenko

A compound of formula (I): (Core)n-(X)m wherein Core is a core group; n is 0 and m is 1, or n is 1 and m is at least 1; and X is a group of formula (II): wherein: R, Rand Rare each independently H or a substituent; Rand Rare each a substituent; one of R-Ris a direct bond or divalent linking group linking the group of formula (II) to Core in the case where n is 1; x and y are 0, 1, 2, 3 or 4; and the compound of formula (I) is substituted with at least one ionic substituent. The compound may be used as an n-dopant to dope an organic semiconductor.

Dopant, charge transfer salt and organic electronic device

A charge-transfer salt formed from a material comprising a repeat unit of formula (I) and an n-dopant: wherein BG is a backbone group of the repeat unit; Ris a ionic substituent comprising at least one cationic or anionic group; n is at least 1; Ris a non-ionic substituent; and m is 0 or a positive integer; the material further comprising a counterion balancing the charge of the cationic or anionic group. 

Charge transfer salts and uses thereof

A compound of formula (I) or (III) (Formulae (I), (III)) wherein: one Y is a substituent Rbound directly to the fluorene unit of formula (I) by an sp-hybridised carbon atom; the other Y is an aryl or heteroaryl group Arthat may be unsubstituted or substituted with one or more substituents; Aris an arylene or heteroarylene group; Ris a substituent; b is 0, 1, 2, 3 or 4; c is 0, 1, 2 or 3; and X is a group of formula (II): (Formula (II)) wherein Z is O or S; Rindependently in each occurrence is a substituent; each x is independently 0, 1, 2 or 3; and * is a bond to the fluorene unit of formula (I). The compounds may be used as host materials for phosphorescent dopants in organic light-emitting devices. 

Compound, composition and organic light-emitting device

A polymer comprising a repeat unit of formula (I): (I) wherein each Arand each Arindependently represents a substituted or unsubstituted aromatic or heteroaromatic group; each Cy independently represents a saturated heterocyclic or carbocyclic ring that may be unsubstituted or substituted with one or more substituents; n is 1, 2 or 3; and adjacent groups Armay be linked by a divalent linking group in the case where n is 2 or 3. The polymer may be used as a charge-transporting material or light-emitting material in an organic light-emitting device. 

Polymer

A method of forming an n-doped organic semiconductor, the method comprising: formation of an n-dopant reagent by reaction of a composition comprising two or more precursor units for forming the n-dopant reagent and an organic semiconductor; and n-doping the organic semiconductor. One or more of the precursor units may be a substituent of a polymeric repeat unit. The n-doped organic semiconductor may be an electron-injection layer of an organic light-emitting device.

Method and composition

A method of forming a crosslinked polymer and an anion, the method comprising the step of reacting a first polymeric substituent comprising a nucleophilic group and a second polymeric substituent comprising an electrophilic group wherein the first polymeric substituent is a substituent of a first polymer and the second polymeric substituent is a substituent of the first polymer or a second polymer. The first and second polymers may be non-conjugated or conjugated. The crosslinked polymers may be used in electrochemical devices, for example battery cells.

Method of forming and use of a crosslinked polymer

A composition comprising a first material substituted with at least one group of formula (I) and a second material substituted with at least one group selected from groups of formulae (IIa) and (IIb): wherein: Spand Spare spacer groups; NB independently in each occurrence is a norbornene group that may be unsubstituted or substituted with one or more substituents; n1 and n2 are 0 or 1; m1 is 1 if n1 is 0 and m1 is at least 1 if n1 is 1; m2 is 1 if n2 is 0 and m2 is at least 1 if n2 is 1; Arrepresents an aryl or heteroaryl group; Rindependently in each occurrence is H or a substituent; and * represents a point of attachment to the first or second material. The composition may be used to form a layer of an organic electronic device, for example the hole-transporting layer of an organic light-emitting device.

Hole transporting compounds and compositions

A material substituted with a group of formula (I): wherein: Aris an aryl or heteroaryl group; Sprepresents a first spacer group; n1 is 0 or 1; m1 is 1 if n1 is 0 and m1 is at least 1 if n1 is 1; Rindependently in each occurrence is H or a substituent, with the proviso that at least one R1 is a group R11 selected from: alkyl comprising a tertiary carbon atom directly bound to a carbon atom of the cyclobutene ring of formula (I); branched alkyl wherein a secondary or tertiary carbon atom of the branched alkyl is spaced from a carbon atom of the cyclobutene ring of formula (I) by at least one &#x2014;CH&#x2014; group; and alkyl comprising a cyclic alkyl group; or with the proviso that at least two Rgroups are linked to form a ring.

Hole transporting cyclobutene compound

A polymer comprising a fluorescent light-emitting repeating unit comprising a group of formula ED-EA wherein ED is an electron-donating unit; EA is an electron-accepting unit; and a band gap Egof a charge-transfer state formed from the electron-donating unit and the electron-accepting unit is smaller than the bandgap of either the electron-accepting unit Egor that of the electron-donating unit Eg.

Organic light-emitting polymer and device

Methods of metal-catalysed polymerisation are described using a metal catalyst of formula (III): wherein Rin each occurrence is independently selected from Calkyl and aryl that may be unsubstituted or substituted with one or more substituents; y is 0 or 2; and Zis an anion. Methods described include Buchwald-type and Suzuki-type polymerisation.

Method of forming polymers

A compound of formula (I) wherein: wherein X is O or S; Rindependently in each occurrence is H or a substituent; Rindependently in each occurrence is H or a substituent; p independently in each occurrence is 0, 1, 2, 3 or 4; q is 0, 1, 2 or 3; and * represents a bond to Ar. Use of compounds of formula (I) as a host for phosphorescent emitters is disclosed.

A method of forming a crosslinked polymer comprising the step of reacting a crosslinkable group in the presence of a polymer, wherein: 

Polymers, monomers and methods of forming polymers

Methods of metal-catalyzed polymerization are described using a metal catalyst of formula (III): wherein Rin each occurrence is independently selected from Calkyl and aryl that may be unsubstituted or substituted with one or more substituents; y is 0 or 2; and Zis an anion. Methods described include Buchwald-type and Suzuki-type polymerization.

A method of forming a crosslinked polymer comprising the step of reacting a crosslinkable group in the presence of a polymer, wherein: the crosslinkable group comprises a core unit substituted with at least one crosslinkable unit of formula (I): the crosslinkable group is bound to the polymer or is a crosslinkable compound mixed with the polymer; Ar is aryl or heteroaryl which may be unsubstituted or substituted with one or more substituents independently selected from monovalent substituents and a divalent linking group linking the unit of formula (I) to the core unit; and R is independently in each occurrence H, a monovalent substituent or a divalent linking group linking the unit of formula (I) to the core unit, with the proviso that at least one R is not H. 

A composition comprising a polymer and a phosphorescent material wherein the polymer comprises repeat units of formula (I): wherein A is a heteroaryl group containing a nitrogen atom, and A may be unusubstituted or substituted with one or more substituents;

Growing community of inventors

Godmanchester, United Kingdom

Florence Bourcet