Montedison S.p.a.

Ausimont S.p.a.

Consiglio Nazionale Delle Ricerche

Other

Enichem Synthesis S.p.a

Montedison Fibre S.p.a.

Eniricherche S.p.a.

Filippo M Carlini

Antonio Marraccini

Antonio Pasquale

Giorgio Bornengo

Giorgio Bottaccio

Michele Pontevivo

Giorgio Maranzana

Camillo Paffoni

Giorgio Guglielmo

Vittorio Alesse

Gioacchino Boffa

Giampiero Pieri

Carlo Neri

Edoardo Platone

Enrico Borgarello

Anna M Marabini

Alberto Osti

Lino Conte

Maria A Marabini

An improved process for the preparation of perfluoropropene oxide by the reaction of perfluoropropene with hydrogen peroxide in an aqueous alkaline medium is described. The improved process is characterized by carrying out the reaction in the presence of a phase-transfer catalyst selected from the group consisting of quaternary ammonium salts, phosphonium salts, and lipophilic complexing agents for cations, and by carrying out the addition of an aqueous solution of an inorganic base to the reaction mixture gradually so that a constant reaction temperature between -10.degree. C. and -60.degree. C. is maintained.

Process for preparation of perfluoropropane oxide

A single-phase, either isotropic or anisotropic formulation is disclosed, which contains perfluorinated oil and one or more surfactant(s), is useful as an excipient for cosmetic and dermatologic formulations and is characterized in that at least one surfactant is selected from those having the following general formula: ##STR1## wherein: R.sub.F is an F--(CF.sub.2 --CF.sub.2).sub.i -- group;

Single-phase composition containing a perfluorinated oil and one or more

Ionic organic collecting agents for the selective flotation of lead and zinc ores, said agents having the following general formula ##STR1## wherein the symbols employed have the meaning given below: R represents H, CH.sub.3, C.sub.2 H.sub.5, or an alkoxyalkyl group,

Collecting agents for the selective flotation of lead and zinc ores and

Preparation of fluoroxy-halo-compounds by direct reaction between fluorine and organic compounds having a molecular structure in which at least one oxygen atom is directly bound to a carbon atom in the carbonylic form, in the presence of a fluorination catalyst, in gaseous phase, at an absolute pressure of between 50 and 800 kPa and at a temperature between -5.degree. and +100.degree. C., under conditions of a continuous feeding of the reactants and a continuous removal of the reaction product.

Process for the preparation of fluoroxy-halo-compounds

Process for the preparation of 2-perfluoropropoxy-perfluoropropionyl fluoride by dimerization of hexafluoropropene epoxide in aprotic polar medium, in the presence of N,N,N',N'-tetrasubstituted diaminodifluoromethane as catalyst, characterized in that the dimerization reaction is carried out in the presence of a co-catalyst constituted by a nitrogenous organic base having structure of aniline, or of pyridine, or of a derivative thereof, wherein the nitrogen atom is not linked to hydrogen atoms and, in the case of the pyridine-type structure, it is sterically hindered by substituent groups on ortho-position relatively to it.

Process for the preparation of 2-perfluoropropoxy-perfluoropropionyl

Organic ionic collecting agents for the selective flotation of lead and zinc ores, said agents having the following general formula: ##STR1## wherein the symbols have the following meanings: R represents an alkoxyl group having from 3 to 12 carbon atoms;

Collecting agents for the selective flotation of lead and zinc ores

Silane quinacridone dyes, composite pigments obtainable therefrom by association with an inorganic substrate, and the processes for preparing them. The dyes have the general formula: ##STR1## wherein X is an --SO.sub.2 NHR group, where R is an alkyl group, linear or branched, having from 1 to 6 carbon atoms, a cycloalkyl group, a phenyl group optionally substituted by one or more alkyl or alkoxy groups (C.sub.1 -C.sub.6), a halogen;

Silanated quinacridone dyes and composite pigments

Silane diimidic tetracarboxylic perylene dyes, the composite pigments obtainable therefrom by means of grafting onto an inorganic substrate, and the processes for preparing same. The dyes have the general formula: ##STR1## in which R is the residue of a silane group of formula: ##STR2## in which n is 3, 4 or 5; q is 0 or 1; p and m are such integers than when q is 0, p is 3 and m is 0, 1, 2 or 3, and when q is 1, p is 2 and m is 0, 1 or 2; R.sub.2 is an alkyl C.sub.1 -C.sub.4 or a phenyl; R.sub.3 is an alkoxyl C.sub.1 -C.sub.2 ; R.sub.1 may be the same as R or represent an alkyl C.sub.1 -C.sub.6, a cycloalkyl, a phenyl optionally substituted by one or more alkyl or alkoxyl groups C.sub.1 -C.sub.6 or a halogen. The dyes and the composite pigments obtained from said dyes are utilized in paints, air and stove enamels, in the pigmentation of plastic materials, and in printing inks.

Silane diimidic tetracarboxylic perylene dyes and composite pigments

Silane diimidic tetracarboxylic perylene dyes, the composite pigments obtainable therefrom by means of grafting onto an inorganic substrate, and the processes for preparing same. The dyes have the general formula: ##STR1## in which R is the residue of a silane group of formula: ##STR2## in which n is 3, 4 or 5; q is 0 or 1, p and m are such integers than when q is 0, p is 3 and m is 0, 1, 2 or 3, and when q is 1, p is 2 and m is 0, 1 or 2; R.sub.2 is an alkyl C.sub.1 -C.sub.4 or a phenyl; R.sub.3 is an alkoxyl C.sub.1 -C.sub.2 ; R.sub.1 may be the same as R or represent an alkyl C.sub.1 -C.sub.6, a cycloalkyl, a phenyl optionally substituted by one or more alkyl or alkoxyl groups C.sub.1 -C.sub.6 or a halogen. The dyes and the composite pigments obtained from said dyes are utilized in paints, air and stove enamels, in the pigmentation of plastic materials, and in printing inks.

Silane diimidic tetracarboxylic perylene dyes

This invention relates to organic dyes containing silane groups; composite pigments obtainable by grafting said dyes onto an inorganic substrate; and, the respective processes for preparing said dyes and composite pigments. The dyes have general formula: ##STR1## wherein R.sub.1 and R.sub.2, which may be equal or different, are selected from the group consisting of H, --NH.sub.2, --NHR wherein R is an alkyl group having from 1 to 4 carbon atoms or a phenyl group, --NHCOCH.sub.3, --NHCOC.sub.6 H.sub.5, --NO.sub.2, a halogen, --OH, --O--C.sub.6 H.sub.5 and --S--C.sub.6 H.sub.5 ; n is a number selected from 3, 4 and 5; W is selected from the group consisting of an alkyl group having from 1 to 4 carbon atoms and a phenyl group; Y is an alkoxy group having from 1 to 4 carbon atoms; q is a number selected from 0 and 1; X is 3 and m is a number selected from 0, 1, 2 and 3 when q is 0; x is 2 and m is a number selected from 0, 1 and 2 when q is 1. The composite pigments obtained from said dyes are employed in the painting products, air enamels and stoving enamels, in the pigmentation of plastic materials, in the inks and in the printing of fabrics.

Organic dyes containing silane groups and process for preparing same

Silane quinacridone dyes, composite pigments obtainable therefrom by association with an inorganic substrate, and the processes for preparing them. The dyes have the general formula: ##STR1## wherein X is an --SO.sub.2 NHR group, where R is an alkyl group, linear or branched, having from 1 to 6 carbon atoms, a cycloalkyl group, a phenyl group optionally substituted by one or more alkyl or alkoxy groups (C.sub.1 -C.sub.6), a halogen; Y and Z indicate a silane group having the formula: ##STR2## wherein R.sub.1 is an alkoxy group (C.sub.1 -C.sub.2), R.sub.2 is an alkyl group (C.sub.1 -C.sub.4) or a phenyl group; n is 3, 4 or 5; q is 0 or 1; p and m are integers, such that when q is 1, p is 2 and m is 0, 1 or 2, and when q is 0, p is 3 and m is 0, 1, 2 or 3; W indicates an --SO.sub.3 H group; a, b and c are 0 or 1, selected in such a way that the sum a+b+c is equal to 1. The composite pigments obtained from said dyes are used in paints, air enamels and stove enamels, in the pigmentation of plastics, and in printing inks.

Silanated quinacridone dyes

There are described silanic phtalocyaninic dyes; composite pigments obtainable by grafting said dyes on an inorganic substrate, and, processes for preparing said dyes and said composite pigments. The dyes are of the following general formula: ##STR1## wherein: Pc is the residue of the phtalocyanine which may be metallized with a metal selected from the group consisting of Co, Ni and Cu; R.sub.1 is selected from the group consisting of H and alkaline metals; R.sub.2 and R.sub.3, equal or different, are selected from the group consisting of H, alkyls having up to 4 carbon atoms, cycloalkyls and aryls; R.sub.4 is selected from the group consisting of an alkyl with from C.sub.1 to C.sub.4 and phenyl; R.sub.5 is an alcoxyl C.sub.1 -C.sub.4 ; n is 3, 4 or 5; q is 0,1; p and m are such integers that when q is 0 p is 3 and m is 0, 1, 2 or 3, and when q is 1, p is 2 and m is 0, 1, 2; a and c are numbers in the range of 1 to 3 and b is a number in the range of 0 to 2, chosen in such a way that the sum a+b+c.ltoreq.4; and wherein each of the four benzenic rings of the phtalocyanine is bound to only one single sulphonic group (--SO.sub.3 R.sub.1) or sulphonamidic group. The composite pigments obtained from above mentioned dyes find their use in varnishes, air-drying or stoving enamels, in the pigmentation of plastic materials as well as in printing inks.

Silanic phtalocyaninic dyes and composite pigments

There are described organic-inorganic ternary composite pigments consisting of 70%-90% by weight of an inorganic binary titanium dioxide/aluminum hydrate component and, from 10% to 30% by weight, of a co-precipitated organic component consisting of an organic dye, containing in its structure at least one carboxylic and/or sulphonic acid function, having the formula: ##STR1## wherein R.sub.1 is selected from the group consisting of NO.sub.2 --SO.sub.3 H and --COOH; R.sub.2 is selected from the group consisting of NO.sub.2, --SO.sub.3 H, alkyl and alkoxyl; R.sub.3 is selected from the group consisting of H, halogen and alkyl; R.sub.4 and R.sub.5 are each selected from the group consisting of H, halogen, alkyl and alkoxyl; R.sub.6 is selected from the group consisting of H, halogen and alkoxyl; and wherein the --COOH and/or --SO.sub.3 H group of dye (I) is salified with metal cations. The pigments are obtained by co-precipitation acidifying an aqueous solution and/or dispersion of acid dye (I) in sodium aluminate, in the presence of TiO.sub.2, maintained at 40.degree.-80.degree. C. and at pH=9.5-10.5, by then treating it with any aqueous solution of an alkaline-earth (Ca, Ma, Al, Ba, Sr) salt or of Mn or Zn.

Photostable yellow composite pigments and process for their preparation

A plastosoluble fluorescent organic dye is disclosed that is derived from benzanthrone, and having the general formula: ##STR1## wherein X = --H or --Br; and Y = --H, --OCH.sub.3 or --OC.sub.2 H.sub.5. A process for the preparation of a dye of the general formula (I) is also disclosed. These dyes are useful in the bulk dyeing of polystyrene, polymethylmethacrylate, rigid PVC, polyethylene, acrylonitrile/butadiene/styrene copolymers, polycarbonates or mineral oils.

Fluorescent benzanthronic dyes

A fluorescent azabenzanthronic dye is disclosed having the general formula (I): ##STR1## wherein X = --NH-- or --S--; and Y = --OCH.sub.3 or --OC.sub.2 H.sub.5. A process for the preparation of a dye of the general formula (I) is also disclosed. These dyes are useful in the bulk dyeing of polystyrene, polymethylmethacrylate, rigid PVC, polyethylene, acrylonitrile/butadiene/styrene copolymers, polycarbonates or mineral oils.

Growing community of inventors

Novara, Italy

Filippo M Carlini