University of Central Florida Research Foundation, Inc.

University of Illinois

University of California

University of Florida Research Foundation, Incorporated

Cornell University

Florida State University Research Foundation, Inc.

Fernando Javier Uribe-Romo

Joaquin Rodriguez Lopez

Demetrius Vazquez-Molina

Gavin Pour

James K Harper

David Fairchild

Omar M Yaghi

Kenneth Hanson

William R Dichtel

David K Britt

Gavin S Mohammad-Pour

Wesley Newsome

Felipe Gandara-Barragan

Jesus Cordova-Guerrero

Hasan Arslan

Suliman Ayad

Matthew W Logan

Various embodiments relate to a method for producing a metal-organic framework (MOF) having a desired redox conductivity and including redox-active linkers, having ω-alkyl-ferrocene groups, via de novo solvothermal synthesis. Various embodiments relate to a metal-organic framework (MOF) linker comprising an ω-alkyl-ferrocene group. Various embodiments relate to a metal-organic framework (MOF), having a first plurality of redox-active linkers, each having an ω-alkyl-ferrocene group. The MOF according to various embodiments, may further have one or more redox-inactive linkers. Various embodiments relate to materials, apparatuses, and components that include the MOF according to various embodiments. For example, various embodiments relate to thin-films, bulk powders, or electrodes.

Solid solution approach for redox active metal organic frameworks with tunable redox conductivity

Covalent organic frameworks (COFs) usually crystallize as insoluble powders and their processing for suitable devices has been thought to be limited. Here, it is demonstrated that COFs can be mechanically pressed into shaped objects having anisotropic ordering with preferred orientation between the hk0 and 00l crystallographic planes. Pellets prepared from bulk COF powders impregnated with LiClOdisplayed room temperature conductivity up to 0.26 mS cmand stability up to 10.0 V (vs. Li/Li). This outcome portends use of COFs as solid-state electrolytes in batteries.

Mechanically shaped 2-dimensional covalent organic frameworks

Disclosed herein are metal-organic frameworks and methods of making and use thereof.

Photo-redox titanium containing organic frameworks and methods of making and use thereof

Multivariate metal-organic framework compositions and methods of producing multivariate metal-organic frameworks. The metal-organic framework including at least one light-emitting linker in an amount sufficient for the composition to produce broadband emission spectra in high efficiencies.

Multivariate metal-organic frameworks for fine-tuning light emission

Covalent organic frameworks (COFs) usually crystallize as insoluble powders and their processing for suitable devices has been thought to be limited. Here, it is demonstrated that COFs can be mechanically pressed into shaped objects having anisotropic ordering with preferred orientation between the hk0 and 00/ crystallographic planes. Pellets prepared from bulk COF powders impregnated with LiClOdisplayed room temperature conductivity up to 0.26 mS cmand stability up to 10.0 V (vs. Li/Li). This outcome portends use of COFs as solid-state electrolytes in batteries.

Provided are graphene nanoribbons (GNRs), methods of making GNRs, and uses of the GNRs. The methods can provide control over GNR parameters such as, for example, length, width, and edge composition (e.g., edge functional groups). The methods are based on a metal catalyzed cycloaddition reaction at the carbon-carbon triple bonds of a poly(phenylene ethynylene) polymer. The GNRs can be used in devices such a microelectronic devices.

Graphene nanoribbons derived from poly(phenylene ethynylene) polymer, methods of making same, and uses thereof

The disclosure provides for novel metal-triazolate frameworks, methods of use thereof, and devices comprising the frameworks thereof.

Preparation of metal-triazolate frameworks

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Orlando, FL, United States of America

Fernando Javier Uribe-Romo