Saudi Arabian Oil Company

Membrane Technology and Research, Inc

Other

Feras Hamad

Richard W Baker

Esam Zaki Hamad

Sebastien Andre Duval

Milind M Vaidya

Ahmad Abdullah Bahamdan

Faisal D Al-Otaibi

Kaaeid A Lokhandwala

Tim Merkel

Jean-Pierre R Ballaguet

Iran D Charry-Prada

Rashid M Othman

Seung-Hak Choi

John Patrick O'Connell

Megat A Rithauddeen

Taib Abang

Aadesh Harale

Bandar A Fadhel

Veera Venkata R Tammana

Georgios Lithoxoos

Garba Oloriegbe Yahaya

Mohammad S Al-Qahtani

Ahmed Abdullah Bahamdan

Ghulam Shabbir

Ivy Huang

Ahmed Ameen

Abdulaziz Yousef Al-Ammar

Abdulaziz Naser Al-Mulhim

Ayman Khaled Rashwan

Ahmed Al-Talib

Nasser Al-Aslai

Ahmad A Bahamdan

Wajdi Issam Al-Sadat

Ahmed A Ba-Hamdan

Methods and systems for recovering sulfur dioxide from a Claus unit process emissions stream are provided. The method comprises the steps of generating a process emissions stream from a thermal oxidizer or other combustion device, introducing the emissions stream to an SOremoval system, introducing the SOrich stream from the SOremoval system to a COremoval system, and introducing an enriched SOstream back to the Claus unit. The SOremoval system can include one or more SOselective membranes. The COremoval system can include one or more COselective membranes.

Improving sulfur recovery operations with processes based on novel COover SOselective membranes and its combinations with SOover COselective membranes

Methods are provided for reducing the quantity of acid gas reinjected into a reservoir by partial COremoval processes. The methods include acid gas removal, acid gas enrichment, generation of a COrich stream and an HS rich stream, and reinjection of the HS rich stream into the reservoir. The acid gas enrichment can be performed by a solvent-based acid gas enrichment unit, a membrane-based acid gas enrichment unit, or a combination of a solvent-based acid gas enrichment unit a and membrane-based acid gas enrichment unit. The system includes an acid gas removal unit, one or more acid gas enrichment units, and an acid gas reinjection compressor. The acid gas enrichment unit can be a solvent-based acid gas enrichment unit, a membrane-based acid gas enrichment unit, or a solvent-based acid gas enrichment unit and a membrane-based acid gas enrichment unit.

Reservoir management by controlling acid gas build-up in reservoir by partial CO2 removal processes

This invention relates to a system and method for improving sulfur recovery from a Claus unit. More specifically, this invention provides a sorption based SOselective crosslinked polyionic liquid system and method for treating acid gas streams and minimizing sulfur dioxide emissions therefrom.

Reducing sulfur emissions of sulfur recovery plant by a sorption based SOselective crosslinked polyionic liquid system

This invention relates to a system and method for improving sulfur recovery from a Claus unit. More specifically, this invention provides a steam swept membrane tail gas treatment system and method for treating acid gas streams and minimizing sulfur dioxide emissions therefrom.

Enhanced tail gas treatment of sulfur recovery unit with steam swept membranes

A membrane module includes a housing. The housing includes a housing, comprising: a first plurality of porous hollow fiber membranes, and a second plurality of porous hollow fiber membranes different from the first plurality of porous hollow fiber membranes. The first plurality of porous hollow fiber membranes has a first length, and the second plurality of porous hollow fiber membranes has a second length that is at least 1.1 times greater than the first length. The membrane module can be used in separation methods, such as membrane distillation methods.

Hollow fiber membrane module and method of making and using same

A process for recovering sulfur from a sour gas is provided. The process includes the steps of: providing the sour gas to a membrane separation unit having a carbon dioxide-selective membrane that comprises a perfluoropolymer, wherein the sour gas comprises carbon dioxide and at least 1 mol % hydrogen sulfide; separating the sour gas using the carbon dioxide-selective membrane in the membrane separation stage to obtain hydrogen sulfide-enriched gas and hydrogen sulfide-stripped gas, wherein the hydrogen sulfide-enriched gas has a hydrogen sulfide concentration of at least 20 mol %, and wherein the hydrogen sulfide-stripped gas comprises carbon dioxide; and processing the hydrogen sulfide-enriched gas in a sulfur recovery unit to obtain sulfur.

Hydrogen sulfide-carbon dioxide membrane separation systems and processes

A process for sweetening a syngas stream, the process comprising the steps of: providing a syngas stream to a nonselective amine absorption unit, the sour syngas stream comprising syngas, carbon dioxide, and hydrogen sulfide; separating the syngas stream in the nonselective amine absorption unit to obtain an overhead syngas stream and an acid gas stream; introducing the acid gas stream to a membrane separation unit, the acid gas stream comprising hydrogen sulfide and carbon dioxide; separating the acid gas stream in the membrane separation unit to produce a retentate stream and a permeate stream, wherein the retentate stream comprises hydrogen sulfide, wherein the permeate stream comprises carbon dioxide; introducing the retentate stream to a sulfur recovery unit; processing the retentate stream in the sulfur recovery unit to produce a sulfur stream and a tail gas stream, wherein the sulfur stream comprises liquid sulfur.

Process of improved sulfur capture from a syngas mixture

Methods and systems are provided for treating the tail gas stream of a sulfur recovery plant. The methods including generating a tail gas stream from a sulfur recovery plant, treating the tail gas stream with a hydrogen sulfide removal unit and a hydrogen selective membrane unit, generating a stream low in hydrogen sulfide and a stream rich in hydrogen. The hydrogen sulfide rich stream is recycled to the sulfur recovery unit. The hydrogen selective membrane unit includes a glassy polymer membrane selective for hydrogen over hydrogen sulfide and carbon dioxide.

Membrane process for H2 recovery from sulfur recovery tail gas stream of sulfur recovery units and process for environmentally greener sales gas

Recovering helium from a gaseous stream includes contacting an acid gas removal membrane with a gaseous stream to yield a permeate stream and a residual stream, removing a majority of the acid gas from the residual stream to yield a first acid gas stream and a helium depleted clean gas stream, removing a majority of the acid gas from the permeate stream to yield a second acid gas stream and a helium rich stream, and removing helium from the helium rich stream to yield a helium product stream and a helium depleted stream. A helium removal system for removing helium from a gaseous stream including hydrocarbon gas, acid gas, and helium includes a first processing zone including a first acid gas removal unit, a second processing zone including a second acid gas removal unit, a third processing zone, and a helium purification unit.

Helium recovery from gaseous streams

A process for recovering sulfur and carbon dioxide from a sour gas stream, the process comprising the steps of: providing a sour gas stream to a membrane separation unit, the sour gas stream comprising hydrogen sulfide and carbon dioxide; separating the hydrogen sulfide from the carbon dioxide in the membrane separation unit to obtain a retentate stream and a first permeate stream, wherein the retentate stream comprises hydrogen sulfide, wherein the permeate stream comprises carbon dioxide; introducing the retentate stream to a sulfur recovery unit; processing the retentate stream in the sulfur recovery unit to produce a sulfur stream and a tail gas stream, wherein the sulfur stream comprises liquid sulfur; introducing the permeate stream to an amine absorption unit; and processing the permeate stream in the amine absorption unit to produce an enriched carbon dioxide stream.

Sulfur recovery operation with improved carbon dioxide recovery

A method for recovering sulfur from an acid gas feed is provided. The method comprising the steps of mixing the acid gas feed and an absorption process outlet stream to form a combined Claus feed, introducing the combined Claus feed and a sulfur dioxide enriched air feed to a Claus process to produce a Claus outlet gas stream, introducing the Claus outlet gas stream to a thermal oxidizer, treating the thermal oxidizer outlet stream in a gas treatment unit to produce a dehydrated stream, introducing the dehydrated stream to a membrane sweeping unit to produce a sweep membrane residue stream and a sulfur dioxide enriched air feed, introducing a sweep air stream to a permeate side of the membrane sweeping unit, and introducing the sweep membrane residue stream to a sulfur dioxide absorption process to produce the absorption process outlet stream and a stack feed.

Enhancement of claus tail gas treatment by sulfur dioxide-selective membrane technology and sulfur dioxide-selective absorption technology

Compositions of and methods for separating components of a natural gas stream are disclosed. In one embodiment, the method includes receiving an inlet stream comprising natural gas, the inlet stream having an inlet pressure, and the inlet stream further comprising methane, helium, and an impurity. The method includes allowing the inlet stream to contact a block co-polyimide membrane, the block co-polyimide membrane exhibiting both higher permeability for and higher selectivity for the helium and the impurity than for the methane at the inlet pressure of the inlet stream and separating the methane from the helium and the impurity to create a retentate stream, the retentate stream comprising an increased concentration of methane relative to the inlet stream. The method also includes creating a permeate stream comprising the helium and the impurity at an increased concentration of helium and impurity relative to a concentration of helium and impurity in the inlet stream.

Sour gas feed separations and helium recovery from natural gas using block co-polyimide membranes

A method for removing sulfur-containing compounds from a sulfur recovery unit (SRU) tail gas stream includes the steps of introducing the SRU tail gas stream to a reducing unit to produce a membrane feed, the reducing unit configured to reduce the sulfur-containing compounds to hydrogen sulfide, introducing the membrane feed to a hydrogen sulfide membrane unit, the hydrogen sulfide membrane unit comprising a membrane, wherein the membrane feed comprises hydrogen sulfide, allowing the membrane feed to contact a feed side of the membrane such that hydrogen sulfide permeates through the membrane to a permeate side, and collecting the retentate gases that fail to permeate through the membrane to produce a stack feed, wherein the stack feed comprises retentate gases.

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Dhahran, Saudi Arabia

Feras Hamad