Jiangnan University

National Center for Advanced Packaging Co., Ltd

Feng Jiang

Yuebing Xu

Xiaohao Liu

Bing Liu

Dapeng Liu

Ting Wang

Daquan Yu

The present disclosure discloses a multistage nanoreactor catalyst and preparation and application thereof, belonging to the technical field of synthesis gas conversion. The catalyst consists of a core of an iron-based Fischer-Tropsch catalyst, a transition layer of a porous oxide or porous carbon material, and a shell layer of a molecular sieve having an aromatization function. The molecular sieve of the shell layer can be further modified by a metal element or a non-metal element, and the outer surface of the molecular sieve is further modified by a silicon-oxygen compound to adjust the acidic site on the outer surface and the aperture of the molecular sieve, thereby inhibiting the formation of heavy aromatic hydrocarbons. According to the disclosure, the shell layer molecular sieve with a transition layer and a shell layer containing or not containing auxiliaries, and with or without surface modification can be prepared by the iron-based Fischer-Tropsch catalyst through multiple steps. The catalyst can be used for direct preparation of aromatic compounds, especially light aromatic compounds, from synthesis gas; the selectivity of light aromatic hydrocarbons in hydrocarbons can be 75% or above, and the content in the liquid phase product is not less than 95%; and the catalyst has good stability and good industrial application prospect.

Multistage nanoreactor catalyst and preparation and application thereof

The present disclosure disclosures a graphene modified iron-based catalyst and preparation and application thereof for use in Fischer-Tropsch reaction, belonging to the technical field of catalytic conversion of synthesis gas. The catalyst consists of, by mass percent, 0.01-30% of graphene, 0-20% of promoter and 60-99.99% of iron oxide powder. The preparation process of the catalyst is as follows: the graphene, the iron oxide powder and the promoter are sequentially placed in an aqueous solution for ultrasonic treatment and stirring, and then rotary evaporation, drying and calcining are conducted. The preparation method is simple. The catalyst shows excellent activity in the Fischer-Tropsch reaction, and maintains a high CO conversion rate of 90% or above for a long time at a very high reaction space velocity; meanwhile, the alkane content in a product is low, and an olefin-alkane ratio can reach 14, thus having an extremely high industrial application value.

Graphene modified iron-based catalyst and preparation and application thereof for use in Fischer-Tropsch reaction

A mechanical debonding method and system are provided. A mechanical debonding method, used to debond temporary bonding wafers formed by bonding a device wafer and a carrier wafer by an adhesive, includes: obtaining the height position of the adhesive through a thickness measurement apparatus; moving a cutting apparatus to a position between the device wafer and the carrier wafer based on the height position of the adhesive, then removing the adhesive at the edge of the temporary bonding wafers by the cutting apparatus; removing the carrier wafer from the temporary bonding wafers; cleaning the adhesive left on the surface of the device wafer.

Mechanical debonding method and system

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Wuxi, China

Feng Jiang