Ningde Amperex Technology Limited

Other

Fei Wu

Kefei Wang

Qiao Zeng

Liangzhen Xiao

Ting Guan

Shan Zhu

Juan Jin

Jibin Geng

Lijun Lou

Shouwen Chen

Xiangqi Qiu

Dongbo Cai

Bowen Zhang

Jinli Wang

Junhui Li

An electrolyte including a dinitrile compound, a trinitrile compound, and propyl propionate. Based on the total weight of the electrolyte, the weight percentage of the dinitrile compound is X, the weight percentage of the trinitrile compound is Y, and the weight percentage of the propyl propionate is Z, wherein, about 3 wt %≤(X+Y)≤about 11 wt %, about 1≤(X/Y)≤about 6, and about 0.01<(Y/Z)≤about 0.3; the trinitrile compound includes at least one selected from the group of 1,3,5-pentanetricarbonitrile; 1,2,3-propanetrinitrile, 1,3,6-hexanetricarbonitrile; 1,2,6-hexanetricarbonitrile, 1,2,3-tris(2-cyanoethoxy)propane; 1,2,4-tris(2-cyanoethoxy)butane, 1,1,1-tris(cyanoethoxymethylene)ethane, 1,1,1-tris(cyanoethoxymethylene)propane, 3-methyl-1,3,5-tris(cyanoethoxy)pentane, 1,2,7-tris(cyanoethoxy)heptane, 1,2,6-tris(cyanoethoxy)hexane, and 1,2,5-tris(cyanoethoxy)pentane.

Electrolyte and electrochemical device

An electrolyte including a dinitrile compound, a trinitrile compound, and propyl propionate. Based on the total weight of the electrolyte, the weight percentage of the dinitrile compound is X, the weight percentage of the trinitrile compound is Y, and the weight percentage of the propyl propionate is Z, wherein, about 2 wt %<(X+Y)≤about 11 wt %, about 0.1≤(X/Y)≤about 4, about 30 wt %≤Z≤about 50 wt %, about 2 wt %<X≤about 6 wt %, and about 0.01<(Y/Z)≤about 0.3; wherein the trinitrile compound comprises at least one selected from the group consisting of 1,3,5-pentanetricarbonitrile; 1,2,3-propanetrinitrile, 1,3,6-hexanetricarbonitrile; 1,2,6-hexanetricarbonitrile, 1,2,3-tris(2-cyanoethoxy)propane; 1,2,4-tris(2-cyanoethoxy)butane, 1,1,1-tris(cyanoethoxymethylene)ethane, 1,1,1-tris(cyanoethoxymethylene)propane, 3-methyl-1,3,5-tris(cyanoethoxy)pentane, 1,2,7-tris(cyanoethoxy)heptane, 1,2,6-tris(cyanoethoxy)hexane, and 1,2,5-tris(cyanoethoxy)pentane.

An electrolyte including a dinitrile compound, a trinitrile compound, and propyl propionate. Based on the total weight of the electrolyte, the weight percentage of the dinitrile compound is X, the weight percentage of the trinitrile compound is Y, and the weight percentage of the propyl propionate is Z, wherein, about 2 wt %≤(X+Y)≤about 11 wt %, about 1≤(X/Y)≤about 6, about 40 wt %≤Z≤about 50 wt %, and about 0.01<(Y/Z)≤about 0.3; wherein the trinitrile compound comprises at least one selected from the group consisting of 1,3,5-pentanetricarbonitrile; 1,2,3-propanetrinitrile, 1,3,6-hexanetricarbonitrile; 1,2,6-hexanetricarbonitrile, 1,2,3-tris(2-cyanoethoxy)propane; 1,2,4-tris(2-cyanoethoxy)butane, 1,1,1-tris(cyanoethoxymethylene)ethane, 1,1,1-tris(cyanoethoxymethylene)propane, 3-methyl-1,3,5-tris(cyanoethoxy)pentane, 1,2,7-tris(cyanoethoxy)heptane, 1,2,6-tris(cyanoethoxy)hexane, and 1,2,5-tris(cyanoethoxy)pentane.

An electrolyte including a dinitrile compound, a trinitrile compound, and propyl propionate. Based on the total weight of the electrolyte, the weight percentage of the dinitrile compound is X, the weight percentage of the trinitrile compound is Y, and the weight percentage of the propyl propionate is Z, wherein about 2.2 wt %≤(X+Y)≤about 8 wt %, about 0.1≤(X/Y)≤about 6, 1 wt %<Y<5 wt %, about 30 wt %≤Z≤about 50 wt %, and about 0.02<(Y/Z)≤about 0.3.

An electrolyte including a dinitrile compound, a trinitrile compound, and propyl propionate. Based on the total weight of the electrolyte, the weight percentage of the dinitrile compound is X, the weight percentage of the trinitrile compound is Y, and the weight percentage of the propyl propionate is Z, wherein, about 2 wt %≤(X+Y)≤about 8 wt %, about 0.1≤(X/Y)≤about 6, about 30 wt %≤Z≤about 50 wt %, and about 0.01≤(Y/Z)≤about 0.3; wherein the dinitrile compound is one or more compounds selected from adiponitrile, 1,4-dicyano-2-butene, and ethylene glycol bis(2-cyanoethyl) ether; and the trinitrile compound is one or more compounds selected from 1,3,5-pentanetricarbonitrile; 1,2,3-propanetrinitrile; 1,3,6-hexanetricarbonitrile; 1,2,6-hexanetricarbonitrile; 1,2,3-tris(2-cyanoethoxy)propane; 1,2,4-tris(2-cyanoethoxy)butane; 1,1,1-tris(cyanoethoxymethylene)ethane; 1,1,1-tris(cyanoethoxymethylene)propane; 3-methyl-1,3,5-tris(cyanoethoxy)pentane; 1,2,7-tris(cyanoethoxy)heptane; 1,2,6-tris(cyanoethoxy)hexane; 1,2,5-tris(cyanoethoxy)pentane; and any combination thereof.

An electrolyte including a dinitrile compound, a trinitrile compound, and propyl propionate. Based on the total weight of the electrolyte, the weight percentage of the dinitrile compound is X, the weight percentage of the trinitrile compound is Y, and the weight percentage of the propyl propionate is Z, wherein, about 2 wt %<(X+Y)≤about 8 wt %, about 0.1≤(X/Y)≤about 6, about 2 wt %<X≤about 6 wt %, about 30 wt %≤Z≤about 50 wt %, and about 0.01≤(Y/Z)≤about 0.3; wherein the dinitrile compound is one or more compounds selected from butanedinitrile, adiponitrile, 1,4-dicyano-2-butene, and ethylene glycol bis(2-cyanoethyl) ether; and the trinitrile compound is one or more compounds selected from 1,3,5-pentanetricarbonitrile; 1,2,3-propanetrinitrile; 1,3,6-hexanetricarbonitrile; 1,2,6-hexanetricarbonitrile; 1,2,3-tris(2-cyanoethoxy)propane; 1,2,4-tris(2-cyanoethoxy)butane; 1,1,1-tris(cyanoethoxymethylene)ethane; 1,1,1-tris(cyanoethoxymethylene)propane; 3-methyl-1,3,5-tris(cyanoethoxy)pentane; 1,2,7-tris(cyanoethoxy)heptane; 1,2,6-tris(cyanoethoxy)hexane; 1,2,5-tris(cyanoethoxy)pentane; and any combination thereof.

A method for charging a battery includes charging the battery with a charging current at a constant current during an mth charge and discharge cycle; a first state of charge SOCof the battery when the constant current charging phase in any one charge and discharge cycle ends is the same as a standard state of charge SOC, SOC≤SOC≤SOC+k. SOCis a state of charge or a preset value of the battery at the end of the constant current charging phase during an nth charge and discharge cycle, SOCis a state of charge or a preset value of the battery at the end of the constant current charging phase during an (m−1)th charge and discharge cycle, SOC≤SOC≤SOC+k, 0≤k≤10%, and SOC+k≤100%.

Electronic device and method for charging battery

A method of charging a battery, including: in an mcharge and discharge cycle, constant-current charging a battery to a first cut-off voltage Uat a charging current, where m is any two or more integers of 1, 2, 3, . . . , x, and Uhas different values in at least two charge and discharge cycles. The method shortens fully charged time of a battery and further ensure that phenomena of lithium precipitation and overcharge do not occur on the battery, thereby prolonging a service life of the battery.

Charging method, electronic apparatus, and storage medium

An electrolyte including a dinitrile compound, a trinitrile compound, and propyl propionate. Based on the total weight of the electrolyte, the weight percentage of the dinitrile compound is X, the weight percentage of the trinitrile compound is Y, and the weight percentage of the propyl propionate is Z, wherein, about 2.2 wt %≤(X+Y)≤about 8 wt %, about 0.1≤(X/Y)≤about 2.3, about 5 wt %≤Z≤about 50 wt %, 1 wt %<Y<5 wt %, and about 0.02≤(Y/Z)≤about 0.3; wherein the dinitrile compound is one or more compounds selected from butanedinitrile, adiponitrile, 1,4-dicyano-2-butene, and ethylene glycol bis(2-cyanoethyl) ether; and the trinitrile compound is one or more compounds selected from 1,3,6-hexanetricarbonitrile, 1,2,6-hexanetricarbonitrile and 1,2,3-tris(2-cyanoethoxy)propane.

An electrolyte including a dinitrile compound, a trinitrile compound, and propyl propionate. Based on the total weight of the electrolyte, the weight percentage of the dinitrile compound is X, the weight percentage of the trinitrile compound is Y, and the weight percentage of the propyl propionate is Z, wherein, about 2.2 wt %≤(X+Y)≤about 8 wt %, about 0.1≤(X/Y)≤about 2.3, about 5 wt %≤Z≤about 50 wt %, 1 wt %<Y<5 wt %, and about 0.02<(Y/Z)≤about 0.3; wherein the trinitrile compound comprises at least one selected from the group consisting of 1,3,5-pentanetricarbonitrile; 1,2,3-propanetrinitrile, 1,3,6-hexanetricarbonitrile; 1,2,6-hexanetricarbonitrile, 1,2,3-tris(2-cyanoethoxy)propane; 1,2,4-tris(2-cyanoethoxy)butane, 1,1,1-tris(cyanoethoxymethylene)ethane, 1,1,1-tris(cyanoethoxymethylene)propane, 3-methyl-1,3,5-tris(cyanoethoxy)pentane, 1,2,7-tris(cyanoethoxy)heptane, 1,2,6-tris(cyanoethoxy)hexane, and 1,2,5-tris(cyanoethoxy)pentane.

An electrolyte including a dinitrile compound, a trinitrile compound, and propyl propionate. Based on the total weight of the electrolyte, the weight percentage of the dinitrile compound is X, the weight percentage of the trinitrile compound is Y, and the weight percentage of the propyl propionate is Z, wherein about 2.2 wt %≤(X+Y)≤about 8 wt %, about 0.1≤(X/Y)≤about 6, 1 wt %≤Y<5 wt %, about 5 wt %≤Z≤about 50 wt %, and about 0.02<(Y/Z)≤about 0.3. The electrolyte further includes at least one selected from the group consisting of a cyclic carbonate ester having a carbon-carbon double bond, a fluorinated chain carbonate ester, a fluorinated cyclic carbonate ester, and a compound having a sulfur-oxygen double bond.

An electrochemical device, including an electrode and an electrolyte. The electrolyte including a dinitrile compound, a trinitrile compound, and propyl propionate. Based on the total weight of the electrolyte, the weight percentage of the dinitrile compound is X, the weight percentage of the trinitrile compound is Y, and the weight percentage of the propyl propionate is Z. Wherein about 2 wt %&#x2264;(X+Y)&#x2264; about 11 wt %, about 0.1&#x2264;(X/Y)&#x2264; about 8. The electrode including a coating, which including a single-sided sub-coating and a double-sided coating, the electrode with the single-sided sub-coating has an electrode compaction density D1, and the electrode with the double-sided coating has an electrode compaction density D2, where about 0.8&#x2264;D1/D2&#x2264; about 1.2. The electrolyte and D1/D2 of the electrodes has a significant effect on the cycle performance of the electrochemical device.

An electrolyte including a dinitrile compound, a trinitrile compound, and propyl propionate. Based on the total weight of the electrolyte, the weight percentage of the dinitrile compound is X, the weight percentage of the trinitrile compound is Y, and the weight percentage of the propyl propionate is Z; where about 2 wt %&#x2264;(X+Y)&#x2264;about 11 wt %, about 0.1&#x2264;(X/Y)&#x2264;about 8, and about 0.01&#x2264;(Y/Z)&#x2264;about 0.3. The dinitrile compound comprises a compound of Formula (5): N&#x2014;R&#x2014;(O&#x2014;R)&#x2014;O&#x2014;R&#x2014;CN (5). The electrolyte is capable of effectively inhibiting the increase in DC internal resistance of an electrochemical device so that the electrochemical device has excellent cycle and storage performance.

An electrolyte including a dinitrile compound, a trinitrile compound, and propyl propionate. Based on the total weight of the electrolyte, the weight percentage of the dinitrile compound is X, the weight percentage of the trinitrile compound is Y, and the weight percentage of the propyl propionate is Z, wherein, about 2.2 wt %&#x2264;(X+Y)&#x2264;about 8 wt %, about 0.1&#x2264;(X/Y)&#x2264;about 2.3, about 5 wt %&#x2264;Z&#x2264;about 50 wt %, 1 wt %&#x3c;Y&#x3c;5 wt %, and about 0.02&#x2264;(Y/Z)&#x2264;about 0.3; wherein wherein the dinitrile compound is one or more compounds selected from the group consisting of butanedinitrile, adiponitrile, and 1,4-dicyano-2-butene; and the trinitrile compound is one or more compounds selected from the group consisting of 1,3,6-hexanetricarbonitrile, 1,2,6-hexanetricarbonitrile and 1,2,3-tris(2-cyanoethoxy)propane.

A method for charging a battery, and electronic device using the method, includes charging the battery with a first charge current Iat constant current in a mth charge-discharge cycle of the battery, wherein the battery has a first cut-off voltage Vwhen the constant current charging stage of the battery is cut off in the mth charge-discharge cycle. The first charge current Iis calculated according to a formula I=I+k&#xd7;I, where, 0&#x3c;k&#x2264;1, Iis the charging current of the constant current charging stage of the battery or another battery identical to the battery in the nth charge-discharge cycle, or Ican be a preset value, n is an integer and is greater than or equal to 0, and m is an integer greater than n, the value of k is not the same in at least two charge-discharge cycles of the battery.

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Ningde, China

Fei Wu