Basf Se Corporation

Fabian Seeler

Kerstin Schierle-Arndt

Wolfgang Rohde

Torben Adermann

Otto Machhammer

Stephan Maurer

Florian Garlichs

Georg Degen

Bernard Hendrik Reesink

Sabine Weiguny

Michael Lutz

Regina Vogelsang

Jürgen Kaczun

Jürgen Wortmann

Günther Huber

Juergen Kaczun

Guenther Huber

Juergen Wortmann

Martin Gärtner

Thomas Michael Ryll

Birgit Gerke

Michael Zeilinger

Markus Schwind

Felix Major

Matthias Voges

Claus Schäfer

Jerome Francois

Martin Gaertner

Gareth Smith

Claus Schaefer

Disclosed herein is a process for the recovery of one or more transition metals and lithium from waste lithium ion batteries or parts thereof. The process includes the steps of (a) providing a particulate material containing a transition metal compound and/or transition metal; (b) treating the material provided in step (a) with a polar solvent and optionally an alkaline earth hydroxide, (c) separating the solids from the liquid, optionally followed by a solid-solid separation step; and (d) treating the solids containing the transition metal in a way to dissolve at least part of the Ni and/or Co. The process provides good separation of lithium in high purity and of transition metal useful for the production of battery cathode active materials.

Process for the recovery of lithium and other metals from waste lithium ion batteries

Process for the recovery of transition metal from spent lithium ion batteries containing nickel, wherein said process comprises the steps of (a) heating a lithium containing transition metal oxide material to a temperature in the range of from 400 to 1200° C., (b) treating said heat-treated material with water, (c) treating the solid residue from step (b) with an acid selected from sulfuric acid, hydrochloric acid, nitric acid, methanesulfonic acid, oxalic acid and citric acid, (d) adjusting the pH value to 2.5 to 8, (e) removing compounds of Al, Cu, Fe, Zn or combinations of at least two of the foregoing from the solution or slurry obtained in step (d).

Process for the recovery of lithium and transition metal using heat

The invention relates to a device for storing heat, comprising a heat storage medium which absorbs heat in order to store heat and releases heat in order to use the stored heat, and a container for holding the heat storage medium, the container being closed by a gastight cover, and the device comprising volume compensation means in order to compensate for a volume increase of the heat storage medium () due to a temperature rise and a volume decrease due to a temperature reduction. The invention furthermore relates to a method for storing heat, in which heat is transferred to a heat storage medium in order to store heat or heat is discharged from the heat storage medium to the heat carrier in order to use the heat, the heat storage medium being held in a container which is closed by a gastight cover, wherein a volume expansion of the heat storage medium () is compensated for by a volume increase of the container () or by heat storage medium () flowing out of the container () into a buffer container (), and a volume decrease of the heat storage medium () is compensated for by a volume decrease of the container () or by heat storage medium () flowing out of the buffer container () into the container ().

Device and method for storing heat

Use of a composition (A) having a pH of at least 8 at 25&#xb0; C. containing at least 50 wt.-% of water or a water containing solvent mixture, at least 0.1 mol/m3 of at least one water soluble silicate, optionally at least one molybdate, optionally at least one phosphonate, optionally at least one azole, optionally at least one additional freezing point depressing salt, optionally at least one phosphate, and optionally at least one nitrate, as heat carrier medium for magnetocaloric materials of formula (I) (AB)CDE(I) where: A is Mn or Co, B is Fe, Cr or Ni, C is Ge, As or Si, D is different from C and is selected from P, B, Se, Ge, Ga, Si, Sn, N, As and Sb, E may be same or different from C and D and is selected from P, B, Se, Ge, Ga, Si, Sn, N, As and Sb.

[object Object]

In a method for producing form bodies for heat exchangers, comprising a thermomagnetic material, said form bodies having channels for passage of a fluid heat exchange medium, a powder of the thermomagnetic material is introduced into a binder, the resulting molding material is applied to a carrier by printing methods, and the binder and if appropriate a carrier are removed subsequently and the resulting green body is sintered.

Printing method for producing thermomagnetic form bodies for heat exchangers

What is described is the use of alcohols, alcoholamines, diols, polyols or mixtures thereof in heat carrier media or as heat carrier media which are in contact with magnetocaloric materials.

Heat carrier medium for magnetocaloric materials

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Dossenheim, Germany

Fabian Seeler