Engelhard Corporation

Eugene Palka

Deepak S Thakur

Brian D Roberts

Eugene Nebesh

Thomas J Sullivan

Mark Edward Gall

Thomas I Sullivan

Disclosed are catalysts in powdered form comprising a major amount of the oxides of a first metal selected from copper or zinc, a second metal selected from chromium, molybdenum, tungsten and vanadium, and optionally, a minor amount of the oxide of a promoter metal selected from the group consisting of manganese, barium, zinc, nickel, cobalt, cadmium, iron and any combination thereof provided that the promoter metal is not zinc if the first metal is zinc, wherein the average particle diameter of the powder is from about 6 to about 20 microns; and the particle surface area is from about 20 to about 70 m.sup.2 /g. Also disclosed is a process for preparing such catalysts and a process for hydrogenating aldehydes, ketones, carboxylic acids and carboxylic acid esters with catalysts of the type described.

Hydrogenation catalyst, process for preparing and process of using said

This hydrogenation catalyst comprises a major amount of the oxides of a first metal selected from copper or zinc, a second metal selected from chromium, molybdenum, tungsten and vanadium, and optionally, a minor amount of the oxide of a promoter metal selected from the group consisting of manganese, barium, zinc, nickel, cobalt, cadmium, iron and any combination thereof provided that the promotor metal is not zinc if the first metal is zinc. The average particle diameter of the powder is from about 6 to about 20 microns; and the particle surface area is from about 20 to about 70 m.sup.2 /g. The process for preparing this catalyst comprises the steps of

Process for preparing catalyst with copper or zinc and with chromium,

A pigment of irregular-shaped particles is described which comprises crystallites of the empirical formula A.sub.x B.sub.y C.sub.z wherein A and B are different; A is cobalt, nickel, copper, zinc, cadmium, iron, manganese or any combination thereof; B is aluminum, chromium, molybdenum, iron, vanadium, manganese or any combination thereof; C is oxygen, selenium, tellurium or sulfur; x is 1, 2 or 3; y is 2 or 3; and z is greater than 3; the crystallites have an average size of from about 75 to about 600 Angstroms; and the surface area of the pigment particles is greater than zero up to about 20 m.sup.2 /g. In one embodiment, when the pigment contains a mixture of copper oxide, iron oxide, manganese oxide and no chromium, the pigment contains no more than 10% of manganese, and when the pigment contains copper oxide, chromium oxide, and manganese oxide, the pigment contains up to about 5% of manganese oxide, the mole ratio of chromium to copper is no greater than about 1.3 to 1.

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Parma, OH, United States of America

Eugene Palka