Borealis Technology Oy

Neste Oyj

Borealis A/s

Esa Korhonen

Pauli Leskinen

Ali Harlin

Fred Bergmann

Jouni Kivel&auml;

Kauno Alastalo

Bo Malm

Torvald Vestberg

Henrik Andtsjö

Ward Mennes

Mikko Matilainen

Klaus Nyfors

Erno Elovainio

Olli Tuominen

Samuli Zitting

Amir K Karbasi

Antti Kurkijärvi

Marianna Vuorikari

Hannu Lehtinen

Max Nyström

Karin H Knudsen

Kai Hagane

Henrik Andtsj&ouml;

Michiel Bergstra

Marianne Vuorikari

Ensio Hietanen

Amir Kiumars Karbasi

The present disclosure relates to methods for processing plastic waste pyrolysis gas, such as methods wherein clogging of the systems used in the method is avoided or at least alleviated.

Method for processing plastic waste pyrolysis gas

The invention is directed to a process for the treatment of plastic material comprising a) providing a liquid; b) contacting the plastic material with the liquid; c) keeping the plastic material in the liquid at Tb&#x2212;25&#xb0; C. to Tb of the liquid, wherein Tb is the boiling point of the liquid at the applied pressure; and d) removing the plastic material from the liquid. Furthermore, the invention is directed to the use of a liquid for the treatment of plastic material and to a plant for treating plastic material with a liquid.

Removing volatile compounds from polymer pellets

A process for producing polyolefins, which includes polymerizing at least one olefin monomer, separating at least a part of the reaction mixture, dividing the separated reaction mixture into a polymer-lean fraction and a polymer-rich fraction, and subjecting at least a part of the polymer-lean fraction to a purification step prior to recycling back to the polymerization of at least one olefin monomer. The obtained polyolefins particularly have a low content of volatile low molecular weight compounds, a low content of low-molecular weight polyolefin waxes and a low content of residues derived from the catalyst employed.

Process to reduce polyolefins with extra low impurity content

The present invention concerns a process and an apparatus for continuous polymerisation of olefin monomers. In particular, the present invention concerns a process and an apparatus for continuous polymerisation olefin monomers like ethylene and other monomers, wherein an olefin monomer is polymerised in slurry phase in an inert hydrocarbon diluent in at least one loop reactor. According to the invention, a polymer slurry is continuously withdrawn from the loop reactor and concentrated. The concentrated slurry is conducted to a flash unit in order to remove the remaining fluid phase, and gas obtained is compressed in a flash gas compressor before it is being fed to a distillation section. By means of the present invention it is possible reduce the size of the flash gas compressor and the capacity of the distillation sections. This significantly reduces investment cost for a continuously operated polymerization apparatus.

Process and apparatus for producing olefin polymers

Olefins are polymerised in the presence of a solid catalyst component and optionally a cocatalyst. The solid catalyst component is introduced into the polymerisation reactor by suspending the solid component into oil having a viscosity of from 20 to 1500 mPa s. Optionally, the suspension comprises a drag reduction agent dissolved in the oil. The suspension is metered into the polymerisation reactor by using a valveless piston pump.

Process for polymerising olefins in the presence of an olefin polymerisation catalyst

The present invention concerns a process and an apparatus for continuous polymerisation of olefin monomers in a cascade of polymerisation reactors. According to the process, an olefin monomer is polymerised first in slurry phase in an inert hydrocarbon diluent in at least one loop reactor and then, subsequently, in gas phase in at least one gas phase reactor. According to the invention, a polymer slurry is continuously withdrawn from the loop reactor and optionally concentrated. The concentrated slurry is conducted to a high pressure flash unit in order to remove the remaining fluid phase, and fed to the gas phase reactor. With the process described in this invention, it is possible to produce bimodal polyethylene with good properties. The operation of the process is stable because of the truly continuous operation.

The present invention concerns a method and an apparatus of introducing polymer slurry obtained from a slurry reactor into a gas phase reactor containing a fluidized bed (C, D). According to the present invention, the content of the slurry reactor (R1) is conducted directly to the fluidized bed reactor (R2) as a multiphase stream comprising polymer, active catalyst and reaction medium using at least one feed line ( ), and the stream is fed below a first fluidized zone (C) of the gas phase reactor via inlet pipe protruding into the fluidized bed in order to increase the once-through conversion of the process. By means of the invention, the amount of unreacted monomers which needs to be recirculated is minimized and investment and operation costs of the recovery section are greatly reduced.

Method and apparatus for preparing polymers

Described herein is a process and an apparatus for polymerizing propylene. The process comprises carrying out the polymerization in at least one slurry reactor and at least one gas phase reactor without recycling unreacted monomers to the slurry reactor. A polymerization product containing unreacted monomers is recovered from the slurry reactor and volatile components are separated from the product in a separation unit. The polymerization product is recovered from the separation unit and conducted to a first gas phase reactor; and at least a part of the volatile components a recovered from the separation unit and conducted them to a gas phase reactor. At least 10% of the polymer product is produced in the gas phase reactor(s). The invention provides propylene homopolymers and alloys of propylene homopolymers and copolymers having good impact and creep properties.

Process for preparing polypropylene alloys

An apparatus for the polymerization of olefin monomers comprising means for forming a fluid stream containing catalyst, means for continuously feeding the fluid stream into an elongated polymerization reactor having at least two successive chambers separated by dividing plates having a diameter slightly smaller than that of the polymerization rector, means for feeding monomers, and an optional catalyst and donor into the polymerization reactor under temperature conditions to polymerize the olefin while maintaining a mixed flow in the chambers to polymerize the monomers and optional comonomer in the fluid, and means for removing the resultant polymer slurry from the polymerization reactor.

Apparatus for the polymerization of olefin monomers

Described herein is a process and an apparatus for preparing propylene homopolymers and copolymers, which comprises polymerizing propylene optionally with comonomers in the presence of a catalyst at elevated temperature and pressure in at least one slurry reactor and at least one gas phase reactor, the polymerization product of at least one slurry reactor, containing unreacted monomers, being conducted to a first gas phase reactor essentially without recycling of the unreacted monomers to the slurry reactor. The invention provides for fast start-ups because the gas phase bed material is available directly from the loop reactor.

Process for preparing propylene homopolymers and copolymers

A process for polymerization of olefin monomers by forming a fluid stream containing catalyst, continuously feeding the fluid stream into an elongated polymerization reactor having at least two successive chambers separated by dividing plates having a diameter slightly smaller than that of the polymerization rector, feeding monomers, and an optional catalyst and donor into the polymerization reactor under temperature conditions to polymerize the olefin while maintaining a mixed flow in the chambers to polymerize the monomers and optional comonomer in the fluid, and removing the resultant polymer slurry from the polymerization reactor.

Growing community of inventors

Porvoo, Finland

Esa Korhonen