American Air Liquide, Inc.

Other

L'air Liquide, Soci&#xe9;t&#xe9; Anonyme Pour L'etude Et L'exploitation Des Proc&#xe9;d&#xe9;s Georges Claude

L'air Liquide, Societe Anonyme a Directoire Et Conseil De Surveillance Pour L'etude Et L'exploitation Des Procedes Georges Claude

Erwin Penfornis

Ovidiu Marin

Scott Macadam

Fabienne Chatel-Pelage

Olivier Charon

William A Von Drasek

Bertrand Leroux

Remi Pierre Tsiava

Xavier Paubel

Guillaume De Smedt

Pascal Duperray

M Usman Ghani

Rajani K Varagani

Maguelonne Hammel

Michael Grant

The invention relates to a process for manufacturing clinker from a raw mix, implementing the following: preheating of the raw mix by combustion flue gases; precalcination of the raw mix; and calcination of the precalcined raw mix in a rotary kiln, in which process the precalcination and the calcination in the rotary kiln produce combustion flue gases that contain CO, in which the combustion flue gases created by the precalcination undergo a CO-removal treatment without said flue gases mixing with the combustion flue gases created by the calcination in the rotary kiln.

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The invention relates to a method for calcination of a material in which said material is heated by contact with a heat source essentially generated by means of a flame produced with at least one flow of fuel and primary air and a flow of secondary air, the flame comprising a first combustion zone with a temperature below 1500&#xb0; C. and a second combustion zone with a temperature above 1500&#xb0; C., where at least one flow of at least one inert gas is injected into the flame at the beginning of the second combustion zone and/or at least one flow of oxygen or a gas enriched in oxygen is injected into the second combustion zone.

Method for calcination of a material with low nochi emissions

A steam-generating combustion system includes an oxygen enriched gas provided as at least part of an oxidant stream. A combustion chamber receives and combusts a fuel in the oxidant stream and generate steam. The combustion chamber generates flue gas having a flue gas volume which is smaller than a volume of flue gas generated by the combustion chamber when operated with air as the oxidant stream. A flue gas pollutant control system receives the flue gas from the combustion chamber and reduces at least one of particulate matter, SO, NO, and mercury. The reduction in flue gas volume allows the implementation of much smaller pollutant control equipment, since the size of the pollutant control units is mainly based on the volume or mass flow rate of flue gas to be treated. Moreover, the system including oxygen-enriched gas in the oxidant will lead to concentrated levels of the pollutants in the flue gas. The high concentrations of pollutants will enhance their absorption in the different pollutant control systems, improving removal efficiency for all species.

Steam-generating combustion system and method for emission control using oxygen enhancement

An improved process for burning solid fuel particles in a combustion chamber and creating a flue gas is disclosed. The method comprises creating a fuel gas stream by mixing the solid fuel particles with a conveying gas, transporting the fuel gas stream through a fuel duct terminating at the combustion chamber at a fuel exit plane and injecting an oxygen stream through an injection device into said fuel gas at an oxygen injection location selected to create a mixing zone to mix the oxygen stream and the fuel gas stream immediately prior to or coincident with combustion of the fuel. Operating parameters of the process can be varied to optimally reduce NOemissions.

Process and apparatus for oxygen enrichment in fuel conveying gases

An air separation unit separates air into an oxygen-rich and oxygen-deficient gas. Fuel gas and the oxygen-rich gas are preheated at heat exchangers through which hot flue gas flows. Combustion of the preheated fuel and oxygen-rich gases result in the hot flue gas. The hot flue gas is cooled at the heat exchangers and flows through a waste heat boiler. Water and/or steam flowing through the waste heat boiler absorbs energy from the cooled flue gas thereby producing heated steam. The heated steam flows through a turbine to produce power. The power is transferred to the air separation unit, thus reducing a power requirement of the air separation unit needed to separate the air.

Integrated heat recovery systems and methods for increasing the efficiency of an oxygen-fired furnace

A method and apparatus for monitoring the flue gases of a furnace combustion process is disclosed. A by-pass circuit that communicates a sample of flue gases to be monitored from a furnace, through a measurement chamber and back to the furnace or furnace exhaust duct is provided. The by-pass circuit has a gas sampling probe with a fume inlet opening, the probe being positioned for withdrawing the sample to be monitored and transmitting it through the by-pass circuit. A measurement device is positioned in the measurement chamber and comprises an in situ optical device which provides real-time measurement of targeted flue gas species concentrations.

Method and apparatus for real-time monitoring of furnace flue gases

Steam generation apparatus and methods are presented that are dedicated to oxygen-enriched air combustion of a fuel, wherein the oxygen concentration of the oxygen-enriched air may range from just above 21 percent to 100 percent. One apparatus comprises an oxygen-enriched air preheater through which oxygen-enriched air flows and exchanges heat indirectly with flue gas, creating a preheated oxygen-enriched air stream. The apparatus further comprises a boiler having a radiant section and a convection section, and other heat transfer units adapted to handle reduced flue gas flow rate and higher temperature flue gases than comparable air/fuel combustion boilers, thus allowing a smaller heat transfer surface area, a more compact design and a higher efficiency.

Steam generation apparatus and methods

An improved process for burning a fuel to produce a flue gas is disclosed. The fuel is burned in a main combustion zone in the presence of a main combustion oxidant to produce combustion products. The combustion products are mixed in a post-combustion zone positioned downstream from the main combustion zone. The post-combustion zone is provided with a recirculation zone positioned proximate to the main combustion zone and an injection zone positioned downstream from the recirculation zone. An post-combustion oxidant is injected into the combustion products in the injection zone. At least one of (a) the residence time of the combustion products in the post-combustion zone, (b) the temperature range of the combustion products contained within the injection zone and (c) the oxygen content of the oxidant is controlled to optimize the level of CO and NOin the flue gas.

Method and apparatus for optimized CO post-combustion in low NOx combustion processes

This invention proposes innovative techniques of NOx reduction in boiler operation through an adaptation of staged combustion in combustion boilers. In preferred processes, air is fed into an air separation unit, and a nitrogen-enriched stream is combined with air to produce a nitrogen-enriched first stage air stream, and at least a portion of an oxygen-enriched stream is mixed with air to produce an oxygen-enriched second stage air stream. A reduction in NOx and increase in efficiency is promoted by the inventive processes and systems.

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Oak Park, IL, United States of America

Erwin Penfornis