Celgard Inc.

Eric Robert White

Kang Karen Xiao

Robert A Nark

Xiaomin Zhang

Kristoffer K Stokes

Stefan Reinartz

Eric Joseph Penegar

Masaaki Okada

Takahiko Kondo

Changqing Wang Adams

Katharine R Chemelewski

Brian R Stepp

Zhengming Zhang

Insik Jeon

Paul D Vido

Allen M Donn

Yao Lu

Hisaki Ikebata

Described herein is a multilayer microporous film or membrane that may exhibit improved properties, including improved dielectric break down and strength, compared to prior monolayer or tri-layer microporous membranes of the same thickness. The preferred multilayer microporous membrane comprises microlayers and one or more lamination barriers. Also disclosed is a battery separator or battery comprising one or more of the multilayer microporous films or membranes. The inventive battery and battery separator is preferably safer and more robust than batteries and battery separators using prior monolayer and tri-layer microporous membranes. Also, described herein is a method for making the multilayer microporous separators, membranes or films described herein.

Microlayer membranes, improved battery separators, and related methods

A new or improved microporous monolayer, bilayer, trilayer, or multilayer membrane, separator membrane, separator, or coated separator is disclosed. The membrane is preferably made up of at least one resin or polymer and at least one additive. The additive may comprise at least one material that improves adhesion of the microporous membrane to a coating, including a polyaramid-containing coating and a PCS coating, or to a different material such as a metallic surface, including an electrode surface. Improvements in adhesion are based on comparisons to similar microporous membranes without the at least one additive. In some preferred embodiments, the at least one additive may comprise, consist of, or consist essentially of a functionalized polymer or the combination of a functionalized polymer and an elastomer. In some embodiments, the functional group of the functionalized polymer may be maleic anhydride (MAH). Also disclosed is a battery separator or coated separator comprising the new or improved microporous membrane. The battery separator may comprise the microporous membrane coated with a polyaramid-containing coating. Also disclosed is a new or improved separator, composite, battery, secondary lithium ion battery, and/or vehicle or device comprising the separator, composite, or battery.

Battery separators, coated battery separators, batteries, and related methods

A multilayer microporous membrane which includes microlayers and one or more lamination barriers is disclosed. Also disclosed is a battery separator or battery comprising one or more of the multilayer microporous films or membranes. Also, described herein is a method for making multilayer microporous separators, membranes or films.

In accordance with at least selected embodiments, a battery separator or separator membrane comprises one or more co-extruded multi-microlayer membranes optionally laminated or adhered to another polymer membrane. The separators described herein may provide improved strength, for example, improved puncture strength, particularly at a certain thickness, and may exhibit improved shutdown and/or a reduced propensity to split.

Microlayer membranes, improved battery separators, and methods of manufacture and use

Disclosed herein are novel or improved microporous battery separator membranes, separators, batteries including such separators, methods of making such membranes, separators, and/or batteries, and/or methods of using such membranes, separators and/or batteries. Further disclosed are laminated multilayer polyolefin membranes with exterior layers comprising one or more polyethylenes, which exterior layers are designed to provide an exterior surface that has a low pin removal force. Further disclosed are battery separator membranes having increased electrolyte absorption capacity at the separator/electrode interface region, which may improve cycling. Further disclosed are battery separator membranes having improved adhesion to any number of coatings. Also described are battery separator membranes having a tunable thermal shutdown where the onset temperature of thermal shutdown may be raised or lowered and the rate of thermal shutdown may be changed or increased. Also disclosed are multilayer battery separator membranes having enhanced web handling performance during manufacturing processes and coating operations.

Laminated multilayer membranes, separators, batteries, and methods

Described herein is a multilayer microporous film or membrane that may exhibit improved properties, including improved dielectric break down and strength, compared to prior monolayer or tri-layer microporous membranes of the same thickness. The preferred multilayer microporous membrane comprises microlayers and one or more lamination interfaces or barriers. Also disclosed is a battery separator or battery comprising one or more of the multilayer microporous films or membranes. The inventive battery and battery separator is preferably safer and more robust than batteries and battery separators using prior monolayer and tri-layer microporous membranes. Also, described herein is a method for making the multilayer microporous separators, membranes or films described herein.

Microlayer membranes, battery separators, batteries, and related methods

Described herein, are battery separators, comprising the following: a microporous polymeric film; and an optional coating layer on at least one side of the microporous polymeric film, wherein at least one of the microporous polymeric film and the optional coating comprises an additive. The additive is selected from the group consisting of a lubricating agent, a plasticizing agent, a nucleating agent, a shrinkage reducing agent, a surfactant, an SEI improving agent, a cathode protection agent, a flame retardant additive, LiPFsalt stabilizer, an overcharge protector, an aluminum corrosion inhibitor, a lithium deposition agent or improver, or a solvation enhancer, an aluminum corrosion inhibitor, a wetting agent, and a viscosity improver. Also, described herein are batteries, including lithium-ion batteries, comprising one or more of the described separators. Methods for making the battery separators are also described.

Additives for improved battery performance, improved additive-containing membranes, improved battery separators, improved batteries, and related methods

Growing community of inventors

Fort Mill, SC, United States of America

Eric Robert White