The Dow Chemical Company

Dow Global Technolgoies LLC

Dow Chemical Technologies LLC

Eric K Lee

Douglas E Beyer

Steven R Jenkins

Mladen Ladika

Hyun K Jeon

Nichole E Nickel

James P Maher

Stephen J Skapik, Iii

Carlos E Hinton

Martin F Debney

Donald J Gromacki

Robert A Gunther

The invention includes a copolymer of vinylidene chloride with at least one monounsaturated comonomer and at least one branching monomer in an amount sufficient to increase molecular weight over that of a polymer prepared using the same process and same monomers in the same relative amounts except without the branching monomer, but preferably the branching monomer is present in a quantity not sufficient to result in measurable crosslinking as determined by solubility in tetrahydrofuran at up to 83&#xb0; C. The invention includes a process for making the polymer and processes for forming the copolymer or compositions thereof as well as articles comprising the copolymer and compositions thereof. The copolymer exhibits improved bubble stability and is particularly useful for processes in which the copolymer is at least partially oriented in formation such as blow molding, formation of monofilament fiber and film blowing.

Bubble stability

The invention includes a composition comprising from 40 to 98 weight percent of at least one GPPS, from 0 to 98 weight percent of at least one HIPS, from 0.5 to 10 weight percent at least one styrene block copolymer, from 0.5 to 10 weight percent of at least one polypropylene wherein the combination of GPPS, HIPS, polypropylene and styrene block copolymer make up at least about 90 percent of the composition as well as a film made of the composition, an envelope window patch comprising the film, an envelope comprising the window patch, and a process for making the film.

Window envelopes with scratch resistant window film patches

A vinylidene chloride polymer composition comprising a vinylidene chloride polymer and a concentrate comprising a blend of a high viscosity, high molecular weight silicone polymer and a carrier polymer, e.g. high density polyethylene, the concentrate being present in an amount sufficient to improve the extrudability of the vinylidene chloride polymer. The vinylidene chloride composition can be fabricated into flexible and rigid containers, both in monolayer and multilayer structures for use in the preservation of food, drink medicine and other perishables.

Extrudable vinylidene chloride polymer compositions

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Midland, MI, United States of America

Eric K Lee