Mitsubishi Gas Chemical Company, Inc.

Emiko Yokose

Kimitaka Nakao

Fumiya Zaima

Toshio Hidaka

Masato Inari

Hiroshi Machida

Hiroshi Watanabe

Kouta Kagimoto

Takayoshi Itoh

Jyun Wakabayashi

The present invention provides an oxygen-absorbing resin composition having a satisfactory oxygen absorption performance and suppressing the occurrence of odor after oxygen absorption, even in an aspect substantially containing no photoinitiator, and an oxygen-absorbing multilayer body using the oxygen-absorbing resin composition. An oxygen-absorbing resin composition initiating oxygen absorption by irradiation with an energy ray, the composition including an easily oxidizable thermoplastic resin and a transition metal catalyst, and wherein the easily oxidizable thermoplastic resin includes a polybutadiene (X) and a resin (Y) having carbon-carbon double bonds and the constitutional unit of the following general formula (1): (wherein Rto Reach represent &#x2014;H, &#x2014;CH, &#x2014;CHR, &#x2014;CHR, &#x2014;CR, &#x2014;OR, &#x2014;COOR, &#x2014;SiR, &#x2014;O&#x2014;SiR, &#x2014;COCl or a halogen atom, and may be the same as each other or different from each other, and R represents a linear or cyclic alkyl, alkenyl, halogenated alkyl, halogenated alkenyl or aryl group.)

Oxygen-absorbing resin composition and oxygen-absorbing multilayer body using the same

The present invention provides a deoxidizing multilayered body, which sufficiently suppresses the production of odorous organic components produced by oxidation, and which absorbs oxygen at a fast rate. The present invention relates to the deoxidizing multilayered body that is constituted by laminating at least an isolation layer (A) that contains a thermoplastic resin, an oxygen absorption layer (B) which is made of an oxygen absorbent resin composition (b) that contains an oxidizable thermoplastic resin and a transition metal catalyst, an odor absorption layer (C) which is made of an odor absorbent resin composition (c) that contains a thermoplastic resin and an odor absorbent, and an oxygen barrier layer (D) which contains an oxygen barrier substance, in this order.

Deoxidizing multilayered body

The present invention provides a deoxidizing multilayered body, which sufficiently suppresses the production of odorous organic components produced with oxidation, and which absorbs oxygen at a fast rate. The present invention is the deoxidizing multilayered body that is constituted by laminating at least an isolation layer (A) that contains a thermoplastic resin, an odor absorption layer (B), which is made from an odor absorbent resin composition (b) that contains an oxidizable thermoplastic resin, a transition metal catalyst, and an odor absorbent, an oxygen absorption layer (C), which is made from an oxygen absorbent resin composition (c) that contains an oxidizable thermoplastic resin and a transition metal catalyst, and an oxygen barrier layer (D), which contains an oxygen barrier substance, in this order.

Dialkylnaphthalene is oxidized to naphthalenedicarboxylic acid in a lower aliphatic carboxylic acid solvent in the presence of a catalyst comprising a cobalt compound, a manganese compound and a bromine compound having an atomic ratio of manganese to cobalt of 0.03 to 0.5. The catalyst is supplied to the oxidation reaction zone so that the total amount of cobalt and manganese is 0.025 to 0.1 gram atom based on 1 gram mol of the dialkylnaphthalene. An oxidation product slurry is subjected to solid-liquid separation when the concentration of the naphthalenedicarboxylic acid in the slurry is 8 to 30% by weight. The process prevents the by-production of benzotricarboxylic acid such as trimellitic acid, thereby drastically reducing the incorporation of heavy metal complexes with trimellitic acid into naphthalenedicarboxylic acid crystals. The process optionally includes the addition of a polymer flocculant, this forming crystal aggregates with a large particle size and facilitating the separation of the crystals from the mother liquor.

Method of producing naphthalenedicarboxylic acid

Dimethylamine is prepared from a reaction of methanol with ammonia or monomethylamine or a disproportionation reaction of monomethylamine, in the presence of a catalyst of silica-modified crystalline silicoaluminophosphate molecular sieve or silica-modified SAPO.

Growing community of inventors

Tokyo, Japan

Emiko Yokose