Saudi Arabian Oil Company

King Fahd University of Petroleum and Minerals

Emad Naji Al-Shafei

Ki-Hyouk Choi

Ali S Al-Nasir

Ali Nader Al-Jishi

Zain Hassan Yamani

Oki Muraza

Mohammad F Al-Jishi

Mohammed Z Al-Bahar

M Rashid Khan

Mohammad A Alabdullah

Esam Zaki Hamad

Lianhui Ding

Bandar Hussain Alsolami

Ashok Kumar Punetha

Ali Alsomali

Bandar K Alotaibi

Mohammed Zuhair Albahar

Mohamed A Ahmed

Massad S Alanzi

Mohamed Al-Bahar

Anas Karrar Jamil

Manal Al-Eid

Mohammad Al-Abdullah

Mohammad Fuad Aljishi

Guanghui Zhu

Peter J Jones

Ali Alnasir

Rashid M Khan

Idris Akolade Bakare

Jaffar Mohammad Al-Dubaisi

Ali N Aljishi

Henry I Halpern

Mohammed F Aljishi

Mohammed A Alkhunaizi

Ali Salim Al-Qahtani

James J Funk

Robert E Ballay

Ali M Alsomali

A method for upgrading a naphtha feed includes passing the naphtha feed to an adsorption unit to produce at least a paraffin stream and an isoparaffin stream, wherein the isoparaffin stream comprises isoparaffins and aromatics. Passing the isoparaffin stream to an isoparaffin aromatization catalytic unit that contacts the isoparaffin stream with at least one aromatization catalyst produces aromatics from the isoparaffins thereby yielding an aromatization effluent. The at least one aromatization catalyst may comprise ZSM-5 zeolite. Benzene, toluene, and/or xylene (BTX) may be separated from the aromatization effluent by separating the aromatics effluent into a gas stream and a liquid stream in a gas/liquid separator, wherein the liquid stream contains BTX. Passing the liquid stream to a BTX-separation unit may produce a BTX stream and a recycle stream, wherein the BTX stream contains benzene, toluene, and/or xylene.

Processes for aromatization of naphtha isoparaffins

A process for upgrading a hydrocarbon feed to produce light olefins, includes contacting the hydrocarbon feed with steam in the presence of a cracking catalyst in a steam catalytic cracking reactor at reaction conditions sufficient to cause at least a portion of the hydrocarbons in the hydrocarbon feed to undergo one or more cracking reactions to produce a steam catalytic cracking effluent comprising ethylene, propylene, or both, wherein the process is capable of being transitioned between an ethylene-selective mode and a propylene-selective mode; determining whether to produce ethylene or propylene; when producing ethylene, then operating the process in ethylene-selective mode comprises producing more ethylene than propylene; or when producing propylene, then operating the process in propylene-selective mode comprises producing more propylene than ethylene.

Process configurations for enhancing light olefin selectivity by steam catalytic cracking of heavy feedstock

A process for producing olefins from the hydrocarbon feed includes introducing the hydrocarbon feed into a Solvent Deasphalting Unit (SDA) to remove asphaltene from the hydrocarbon feed producing a deasphalted oil stream, wherein the SDA comprises a solvent that reacts with the hydrocarbon feed, and the deasphalted oil stream comprises from 0.01 weight percent (wt. %) to 18 wt. % asphaltenes; introducing the deasphalted oil stream into a steam catalytic cracking system; steam catalytically cracking the deasphalted oil stream in the steam catalytic cracking system in the presence of steam and a nano zeolite cracking catalyst to produce a steam catalytic cracking effluent; and separating the olefins from the steam catalytic cracking effluent.

Systems and processes for producing olefins from crude oil

According to one or more embodiments, non-agglomerated, nano-sized ZSM-22 zeolites may be synthesized by methods comprising operating a mechanical rotation drum unit at a first temperature of from 40&#xb0; C. to 60&#xb0; C. and a first speed of from 200 rpm to 1000 rpm for a first time period of from 1.3 hours to 2.7 hours; operating the mechanical rotation drum unit at a second speed of from 30 rpm to 90 rpm for a second time period of from 0.05 hours to 0.4 hours; heating the mechanical rotation drum unit at a ramping temperature of from 8&#xb0; C./minute to 12&#xb0; C./minute to a second temperature of from 115&#xb0; C. to 185&#xb0; C. at the second speed; operating the mechanical rotation drum unit at the second temperature and the second speed for a third time period of from 30 hours to 90 hours; and cooling the mechanical rotation drum unit at a fourth speed of 0 rpm.

Systems and methods for the synthesizing ZSM-22 zeolites

An integrated process for conversion of a hydrocarbon stream comprising light naphtha to enhanced value products. The process includes passing the hydrocarbon stream through a first reactor, the first reactor being a catalytic bed reactor with a dual-function catalyst to simultaneously reform light naphtha to BTEX and crack light naphtha to ethane, propane, and butanes. Further, the process includes passing an effluent of the first reactor to a gas-liquid separating unit to generate a liquid stream and a gas stream, and passing the gas stream to a gas separator unit to remove hydrogen gas and methane and generate an enhanced gas stream. The process further includes passing the enhanced gas stream through a second reactor, the second reactor being a pyrolysis unit operated at steam cracking conditions to convert ethane, propane, and butanes in the enhanced gas stream to light. An associated system for performing the process is also provided wherein the integrated process does not include passage of a process stream to a separate and independent hydrocracking unit to crack light alkanes in the hydrocarbon stream to smaller alkanes.

Conversion of light naphtha to enhanced value products in an integrated two-zone reactor process

Methods and systems for production of consistently-sized BEA zeolite nano-crystals, the method including mixing an emulsion, the emulsion comprising a surfactant and an organic solvent; heating the emulsion; mixing a zeolite solution, the zeolite solution comprising a silicon-containing compound and an aluminum-containing compound; heating the zeolite solution; adding the emulsion to the zeolite solution drop-wise over time to create an zeolite emulsion solution mixture; heating the zeolite emulsion solution mixture; and precipitating the consistently-sized BEA zeolite nano-crystals.

Systems and methods for preparing nano-sized crystals of BEA zeolite

Methods and systems for production of consistently-sized BEA zeolite nano-crystals incorporating at least one metal oxide, the method including removing an organic template from a BEA zeolite comprising an organic template via calcination; desilicating the BEA zeolite following the step of removing the organic template; incorporating at least one metal oxide into the structure of the BEA zeolite after the step of desilicating; protonating the BEA zeolite after the step of incorporating the at least one metal oxide; and calcining the BEA zeolite after the step of protonating to form a modified BEA zeolite product.

Systems and methods for preparing nano-sized crystals of BEA zeolite with metal oxide for hydrocarbon conversions

Embodiments of the disclosure provide a method for producing light olefins from a hydrocarbon feed. The hydrocarbon feed and a water feed are introduced to a reactor to produce an effluent stream. The reactor is operated at a temperature and pressure such that cracking reactions occur in the reactor. The reactor includes a catalyst bed including a nanoscale zeolite catalyst having a crystal size ranging between 10 nm and 300 nm. The effluent stream includes the light olefins. The effluent stream is introduced to a first separator to produce a gas phase fraction and a liquid phase fraction. The gas phase fraction includes the light olefins. The liquid phase fraction is introduced to a second separator to produce a liquid hydrocarbon stream and a spent water stream.

Catalyst and process for catalytic steam cracking of heavy distillate

Systems and methods for production of externally-pore-blocked, internally-pore-opened modified zeolite crystals, the method including mixing zeolite crystals with an organic pore blocking agent; heating the zeolite crystals mixed with the organic pore blocking agent to block internal pores of the zeolite crystals and produce internally-pore-blocked zeolite crystals; mixing the internally-pore-blocked zeolite crystals with an external pore blocking agent; and calcining the internally-pore-blocked zeolite crystals mixed with the external pore blocking agent, to re-open internal pores via decomposition of the organic pore blocking agent and to block external pores via formation of a silica layer over external pores of the zeolite crystals, forming the externally-pore-blocked, internally-pore-opened modified zeolite crystals.

Systems and methods for zeolite catalyst pore blocking modifications for hydrocarbon conversion reactions

Systems and methods for upgrading a heavy oil feed to a light product comprising distillate fractions and olefins, the method including combining a heavy oil feed with a naphtha-based cracking additive to produce a mixed heavy oil feed; heating the mixed heavy oil feed with a nano-zeolite catalyst to effect catalytic upgrading of the mixed heavy oil feed to produce lighter distillate fractions and olefins in an upgraded product; and separating the lighter distillate fractions from the olefins.

Systems and methods for catalytic upgrading of vacuum residue to distillate fractions and olefins

Systems and methods for upgrading a heavy oil feed to a light product comprising distillate fractions and olefins, the method including combining a heavy oil feed with a naphtha-based cracking additive to produce a mixed heavy oil feed; heating the mixed heavy oil feed with a nano-zeolite catalyst in the presence of steam to effect catalytic upgrading of the mixed heavy oil feed to produce lighter distillate fractions and olefins in an upgraded product, the upgraded product including at least about 30 wt. % olefins; and separating the lighter distillate fractions from the olefins.

Systems and methods for catalytic upgrading of vacuum residue to distillate fractions and olefins with steam

The present invention provides selective extraction of sulfoxides, or sulfoxides in combination with sulfones, from hydrocarbon mixtures containing these compounds. A significant advantage of the invention is that oxidation products resulting from oxidative desulfurization of hydrocarbon feedstocks are selectively extracted with minimum co-extraction of non-oxidized products such as valuable hydrocarbon fuel components.

Selective liquid-liquid extraction of oxidative desulfurization reaction products

Systems and methods for production of consistently-sized ZSM-22 zeolite catalyst crystals, a method including preparing an aluminate solution; preparing a silica solution; mixing the aluminate solution and the silica solution to form a zeolite-forming solution; heating the zeolite solution with microwave irradiation in a first, a second, a third, and a fourth distinct isothermal stage to produce the consistently-sized ZSM-22 zeolite catalyst crystals within a pre-selected crystal size range using a non-ionic surfactant.

Systems and methods for synthesis of ZSM-22 zeolite

A dynamic demulsification system to facilitate the removal of water from oil for use in a gas-oil separation plant (GOSP) which has a dehydrator vessel in fluid communication with a desalter vessel which in turn is in fluid communication with a water/oil separator vessel includes the following system components:

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Dhahran, Saudi Arabia

Emad Naji Al-Shafei