E.i. Dupont De Nemours and Company

Hercules Corporation

Performance Materials Na, Inc.

Kuraray America, Inc.

Elliott Echt

Peter Arnold Morken

Richard Allen Hayes

G Michael Collins

Scott Christopher Jackson

Charles L Burdick

George D Robinson

William W Maslanka

David H Dumas

Anthony J Allen

Edward J Engle, Iii

Ronald D Lees

Jeffrey C Peters

Disclosed are methods to form coatings on a substrate, the coatings comprising a blend of a poly(vinyl alcohol) composition comprising a poly(vinyl alcohol) characterized by (i) a hydrolysis level of from about 85 to about 93 mol % and a 4 weight % aqueous viscosity of 15 centipoise (cp) or less; or (ii) a hydrolysis level of about 95 mol % to 100%; and an ionomer comprising a parent acid copolymer that comprises ethylene and about 18 to about 30 weight % of acrylic acid or methacrylic acid, the acid copolymer having a melt flow rate from about 200 to about 1000 g/10 min., wherein about 50% to about 70% of the carboxylic acid groups of the copolymer are neutralized to carboxylic acid salts comprising potassium cations, sodium cations or combinations thereof. Multilayer structures comprising the blend composition on a substrate are also disclosed.

Ionomer-poly(vinylalcohol) coated substrates

Disclosed are methods to form coatings on a substrate, the coatings comprising a blend of a poly(vinyl alcohol) composition comprising a poly(vinyl alcohol) characterized by a hydrolysis level of from about 85 to about 93 mole % and a 4 weight % aqueous viscosity at 20&#xb0; C. of about 16 to about 75 centipoise; and an ionomer comprising a parent acid copolymer that comprises ethylene and about 18 to about 30 weight % of acrylic acid or methacrylic acid, the acid copolymer having a melt flow rate from about 200 to about 1000 g/10 min., wherein about 50% to about 70% of the carboxylic acid groups of the copolymer are neutralized to carboxylic acid salts comprising potassium cations, sodium cations or combinations thereof. Multilayer structures comprising the blend composition on a substrate are also disclosed.

Methods for preparing highly viscous ionomer-poly(vinylalcohol) coatings

Ionomer-poly(vinylalcohol) coatings

Disclosed is a method for forming an aqueous dispersion of an ionomer composition comprising mixing a solid ionomer composition with water heated to a temperature from about 80 to about 90&#xb0; C., the solid ionomer composition comprising an ethylene acid copolymer comprising about 18 to about 30 weight % of copolymerized units of acrylic acid or methacrylic acid, based on the total weight of the parent acid copolymer, the acid copolymer having a melt flow rate from about 200 to about 1000 g/10 min., wherein about 50% to about 70% of the total carboxylic acid groups of the copolymer are neutralized to carboxylic acid salts comprising sodium cations.

Method to form an aqueous dispersion of an ionomer

The present invention provides a method for recovering oil from a subterranean reservoir using waterflooding, wherein the flooding fluid used in the waterflooding process comprises water and one or more ionic polyvinyl alcohol copolymers. The use of one or more ionic polyvinyl alcohol copolymers is expected to increase the recovery of oil by improving both the oil/water mobility ratio and the sweep efficiency in reservoirs with a high degree of heterogeneity.

Method for enhanced recovery of oil from oil reservoirs

The present invention is a composition useful for coating the surface of paper wherein the coating composition is an aqueous solution comprising less than 40 wt % water and consisting essentially of a polyvinyl alcohol copolymer that is at least about 95% hydrolyzed, and a process for preparing the same.

Copolymers of vinyl alcohol and itaconic acid for use in paper coatings

Method of coating paper with copolymers of vinyl alcohol and itaconic acid

The present invention is a composition useful for coating the surface of paper wherein the coating composition is an aqueous solution comprising less than 40 wt % water and consisting essentially of a polyvinyl alcohol copolymer that is at least about 95 % hydrolyzed, and a process for preparing the same.

Water-soluble film from copolymers of vinyl alcohol and itaconic acid, and paper coating articles therefrom

The invention relates to resin systems useful for imparting dry-strength to paper without substantially increasing the paper's wet-strength wherein the resin system comprises a cationic component and an anionic component. The invention also relates to the process for incorporating these resin systems into paper and the paper produced containing the resin systems.

Dry-strength system

A method is provided for using an aqueous suspension of at least 15% of poly(ethylene oxide)(PEO) as a flocculent. PEO is dispersed in an aqueous solution of at least one salt selected from the group consisting of sodium or potassium formate, sodium or potassium hydroxide, sodium or potassium citrate, sodium or potassium acetate, sodium chloride or mixtures thereof to form a poly(ethylene oxide) suspension having at least 15% of poly(ethylene oxide) by total weigh. This suspension is dissolved in an aqueous system; and said dissolved aqueous system is added in conjunction with a solution of a coagulant or synthetic flocculents selected from the group consisting of alum, polyaluminum chloride, sodium aluminates, polyamines, polyacrylamides, copolymers of acrylamide with cationic or anionic monomers, or polyethylene imine, to an aqueous slurry containing finely divided materials, whereby said dissolved aqueous dispersion enhances the separation of the finely divided materials from the liquid in the aqueous slurry.

Aqueous suspensions of poly(ethylene oxide) useful as a flocculent

A method is provided for using an aqueous suspension of at least 15% of poly(ethylene oxide) (PEO) as a retention aid in the manufacturing of paper. PEO is dispersed in an aqueous solution of at least one salt selected from the group consisting of sodium or potassium formate, sodium or potassium hydroxide, sodium or potassium citrate, sodium or potassium acetate, sodium chloride or mixtures thereof to form a poly(ethylene oxide) suspension having at least 15% of poly(ethylene oxide) by total weigh. This suspension is dissolved in said dispersion in an aqueous system containing ferric ions or free chlorine; and said dissolved aqueous system is added to a pulp slurry for making paper just prior to forming the pulp into a wet web, whereby said aqueous suspension prevents the loss of fiber fines during the paper formation stage and resists viscosity loss due to ferric ions or free chlorine in the aqueous system.

Aqueous suspensions of poly(ethylene oxide) useful as retention aids in

A paper-making furnish, comprising poly(paravinyl phenol), also known as poly(hydroxy styrene), in admixture with polyethylene oxide, and a process for retaining fine particles in paper-making comprising adding poly(paravinyl phenol) and polyethylene oxide to a paper-making furnish, are disclosed.

Phenolic compound/polyethylene oxide retention system

A stabilized synthetic polyolefin pulp-cellulose blend is prepared by adding 0.1-1.0% by weight of an antioxidant (a hindered phenolic and/or phosphite antioxidant) to a solution of a polyolefin and solvent wherein the antioxidant is homogenously dispersed therein, forming the polyolefin into a polyolefin pulp, and then mixing the polyolefin pulp with from about 55 to about 90% by weight of a wood pulp to produce the blend. This blend with improved higher ignition temperature is used in the absorbent products industry as an absorbent core, when the blend is heated sufficiently to melt the polyolefin.

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Wilmington, DE, United States of America

Elliott Echt