Harvard College

Elijah Shirman

Joanna Aizenberg

Tanya Shirman

Theresa M Kay

Katherine Reece Phillips

Michael Aizenberg

Nicolas Vogel

Ian Burgess

Grant England

Calvin Russell

Sören Brandt

Ida Pavlichenko

Austin Tripp

Timothy Sheung Bun Wong

A method for analyzing a volatile liquid mixture is described. The method includes providing a sensor, and placing the sensor within a chamber. The mixture is stored in the chamber for a duration sufficient to achieve a series of dynamic non-equilibrium mass-transfer processes: (1) spreading and wetting of the analyte on at least a portion of the bottom-inside surface of the chamber from the source of the injection, (2) evaporation of at least a portion of the analyte liquid into a vaporized analyte, (3) convection and/or diffusion of the vaporized analyte through the chamber to the sensor, and (4) sorption of the vaporized analyte on the sensor. The sensor detects, over time, a plurality of non-equilibrium spectral responses, each corresponding to at least one compositional change in the analyte liquid. The method further includes machine learning algorithms to measure or predict the compositional change and/or presence of contaminants.

Volatile liquid analysis

Disclosed herein is an inverse photonic structure comprising a first component comprising air holes or colloidal particles; and a metal oxide matrix comprising metal oxide nanocrystals, wherein the metal oxide nanocrystals comprise at least one of: a transition metal, titania, zirconia, alumina, iron oxide, zinc oxide, tin oxide, beryllia, a noble metal oxide, platinum group metal oxides, hafnia, molybdenum oxide, tungsten oxide, rhenium oxide, tantalum oxide, niobium oxide, vanadium oxide, chromium oxide, scandium oxide, yttria, lanthanum oxide, ceria, a rare earth oxide, thorium oxide, uranium oxide, other rare earth oxides, or a combination thereof, wherein the inverse photonics structure is crack-free for at least 10,000 repeat units of the first component.

Formation of high quality titania, alumina and other metal oxide templated materials through coassembly

Aspects of the present application provides for enhanced catalytic materials, which can feature multiple functional and/or catalytic species, and methods of their formation. The materials can include catalytic nanoparticles (NPs) partially embedded within a supporting matrix. Treatment of the material, e.g., thermal, optical, microwave, plasma, and/or chemical treatment, can lead to the formation of functionally, e.g., catalytic or co-catalytic, relevant chemical and structural/morphological species or features at the NP-matrix, NP-pore, and matrix-pore interfaces. The treated material is characterized by enhanced properties, e.g., greater mechanical stability.

Enhanced catalytic materials with partially embedded catalytic nanoparticles

A co-assembly method for synthesizing inverse photonic structures is described. The method includes combining an onium compound with a sol-gel precursor to form metal oxide (MO) nanocrystals, where each MO nanocrystal has crystalline and amorphous content. The MO nanocrystals are combined with templating particles to form a suspension. A solvent is evaporated from the suspension to form an intermediate or compound product, which then undergoes calcination to produce an inverse structure.

A method of making a multi-layered film includes depositing thin film layers onto a first side of a double-sided transparent substrate. The thin film layers are transparent, and two adjacent layers of said plurality of thin film layers have different refractive indices. One or more absorbers are deposited at an interface formed between two of the thin film layers that are adjacent to one another, or formed by the first side of the substrate and one of the thin film layers. The absorbers absorb selected wavelengths of incident light and reflect part of the incident light after inducing a phase shift. The location of the interface is selected to provide desired wavelengths of absorbed and reflected light. The multi-layered film has a first appearance when viewed from the first side of the substrate and a second appearance when viewed from the second side of the substrate.

Growing community of inventors

Arlington, MA, United States of America

Elijah Shirman