Bromine Compounds Limited

Imi Tami Institute for Research and Development Ltd.

Eli Barnea

Joseph Mizrahi

Baruch Grinbaum

Leni Kogan

Gideon Harel

Rafael Semiat

Samuel Wahrmann

A process for the production of calcium bromide from feed brines, particularly from Dead Sea End Brine (EB), is described. The process comprises extracting the feed brine in countercurrent with a composite organic solvent; optionally, purifying the extract to increase the ratio Br:Cl by contacting it with a part of the product; and washing the purified extract with water to yield the product, that is an aqueous solution of CaBr. The composite solvent comprises an anionic extractant, such as an amine or a mixture of amines; a cationic extractant, such as a carboxylic phosphoric or sulphonic acid or a mixtures of said acids; and diluent/modifier, which is an organic solvent. An apparatus for the production of calcium bromide is also described, which comprises: an extraction battery; optionally, a purification battery; and a washing battery, wherein at least one of the batteries comprises a plurality of stages.

Process for the production of calcium bromide by liquid-liquid extraction

A liquid-liquid mixer wherein each impeller is associated with one recirculation chamber or two such chambers, having substantially the same diameter as the impeller. Each such recirculation chamber has the effect of increasing significantly the number of dispersion-recoalescence cycles for a given residence time and in consequence it is possible to employ an impeller of a selectively large diameter -- 50-90% of the diameter of the vessel portion in which it is located -- and to operate at relatively low speeds of revolution.

Liquid-liquid mixer

Growing community of inventors

Haifa, Israel

Eli Barnea