Hughes Aircraft Company

Gm Global Technolgoy Operations, Inc.

Delco Electronics Corporation

Elena Ramos

George W Smith

Anna M Lackner

James L Kohler

John D Margerum

Charles R Allison

Nuno A Vaz

J David Margerum

Willis H Smith, Jr

Khoon C Lim

Nuno Yaz

Anna M Lacker

A method of forming a polymer dispersed liquid crystal (PDLC) film is disclosed which consists of forming a solution of LC dissolved in a monomer, photopolymerizing the solution to form a film having a dispersion of LC bubbles therein, establishing a correlation between the LC bubble size and selected characteristics of the film, selecting a LC bubble size corresponding to desired film characteristics, and controlling the conditions of photopolymerization to achieve said LC bubble size. The LC bubble size is controlled by means of the UV exposure intensity, exposure temperature, exposure wavelength, LC concentration and/or concentration of polymerization initiator. Correlations are noted between LC bubble size and the resulting film's threshold and operating voltages for optical transmission, contrast ratio, absolute transmissivity and electro-optical response times. Special types of films, including in situ gratings and holograms, are obtained by periodically varying the conditions of polymerization over the film to produce a corresponding periodic spatial variation in the LC bubble size; different processes used to achieve this result are noted. Films with LC bubbles in a new size regime that significantly decreases the operating voltage threshold, and with gradients in the bubble size, are also disclosed.

Polymer dispersed liquid crystal film devices

A polymer dispersed liquid crystal (PDLC) film, along with various fabrication methods that enable partial prealignment of the film's LC bubbles, are described. The film is formed with a matrix of liquid crystal bubbles. Individual liquid crystals within the bubbles are partially, but substantially less than fully, aligned in a given direction. Partial alignment is attained by the controlled application of an electric or magnetic field, or a mechanical flow, during photopolymerization. The resulting films retain the positive qualities of prior PDLCs, and in addition exhibit generally lower threshold and operating voltages, and can be used as tunable birefringent films in the infrared region.

Film with partial pre-alignment of polymer dispersed liquid crystals for

Polymer dispersed liquid crystal film devices, and method of forming the

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Elena Ramos