Other

Ngk Insulators, Inc.

Tokoku University

Kabushiki Kaisha Makabe Giken

Tohoku University

Eiichi Makabe

Akihisa Inoue

Masahide Onuki

Naokuni Muramatsu

Hisamichi Kimura

Tao Zhang

Xin Min Wang

Junsuke Kiuchi

Hiroshi Suzuki

Tatsue Arakawa

There is provided a metallic glass component with its surface layer having both durability of a film and chromatic color properties, and a method for forming the surface layer. Surface active treatment is performed wherein the surface of the metallic glass component is reacted with a mixed aqueous solution of nitric acid and hydrofluoric acid to remove an oxide film and to provide an anchor bond shape on the surface of a metallic glass component, and electroplating or electroless plating is then performed, to form a plating film on the surface of the metallic glass component. It is thereby possible to form a surface layer of a metallic glass which has both durability and a chromatic color.

Method of surface treatment for metal glass part, and metal glass part with its surface treated by the method

A golf club which has a clubface of desired shape comprising an alloy metal is provided. The golf club has excellent strength properties as well as excellent ball hitting properties. The clubface is free from casting defects such as cold shuts, and preferably, free from the crystalline phase formed from crystal nuclei through nonuniform nucleation since the club face is produced in a simple, highly reproducible, one-step process by selectively cooling the molten metal at a temperature above the melting point at a rate higher than the critical cooling rate, and the product comprises a single amorphous phase. The metallic glass face used in the golf club is produced by filling a metal material in a hearth; melting said metal material by using a high-energy heat source which is capable of melting said the metal material; pressing said the molten metal at a temperature above the melting point of said the metal material to deform the molten metal into the desired shape by at least one of compressive stress and shear stress at a temperature above the melting point, while avoiding the surfaces of the molten metal cooled to a temperature below the melting point of said the metal material from meeting with each other during the pressing; and cooling said the molten metal at a cooling rate higher than the critical cooling rate of the metal material simultaneously with or after said the deformation to produce the metallic glass face of desired form.

Golf club manufacturing method

A process and an apparatus for producing metallic glass which are capable of producing a bulk amorphous alloy of desired shape, in particular, a bulk amorphous alloy of desired final shape are provided. In the present invention, the molten metal at a temperature above the melting point is selectively cooled at a rate higher than the critical cooling rate, and the product comprises single amorphous phase which is free from the crystalline phase formed by the development of crystal nuclei through nonuniform nucleation. The present invention is capable of producing the bulk amorphous alloy which is free from casting defects such as cold shuts and which has excellent strength properties in a simple process at a high reproducibility. Accordingly, a bulk metallic glass of desired shape is produced by filling a metal material in a hearth; melting the metal material by using a high-energy heat source which is capable of melting the metal material; pressing the molten metal at a temperature above the melting point of the metal material to deform the molten metal into the desired shape by at least one of compressive stress and shear stress at a temperature above the melting point, while avoiding the surfaces of the molten metal cooled to a temperature below the melting point of the metal material from meeting with each other during the pressing; and cooling the molten metal at a cooling rate higher than the critical cooling rate of the metal material simultaneously with or after the deformation to produce the bulk metallic glass of desired form.

Process and apparatus for producing metallic glass

This invention provides a glassy metal-suction casting method capable of readily and conveniently producing a large-sized amorphous material with excellent properties as an amorphous material. Such an object of the invention is attained by filling a metal material in a mold cooled with water; melting said metal material by using a high-energy heat source which is capable of rapidly melting said metal material; and introducing the resulting molten metal instantaneously into a vertically extending water-cooled mold provided below said mold by using a difference in gas pressure or gravity to move the metal melt at a high speed and attain a high quenching rate to thereby enable the production of a glassy metal ingot of a large size.

Production methods of metallic glasses by a suction casting method

Growing community of inventors

Miyagi, Japan

Eiichi Makabe