Gulf Research & Development Company

Gulf Oil Corporation

Edward W Smith

John A Paraskos

Clarence R Murphy

Jin K Kim

Improved ethylene polymer fibrils are provided which are characterized in having:

Ethylene polymer fibrils

A process for the selective recovery of tar sand bitumen from tar sands using a two-solvent system comprising a halogenated aliphatic solvent in combination with a second solvent selected from an oxygenated compound. The process provides for an inexpensive method for selectively removing substantially metal-free tar sand bitumen from tar sands. The bitumen so recovered renders the same amenable to catalytic desulfurization and upgrading processes.

Process for selective recovery of relatively metals-free bitumen from

A process for preparing olefin polymer fibrils is disclosed. A high molecular weight ethylene polymer is dissolved in methylene chloride in a first zone that is heated to develop a superatmospheric pressure. The polymer solution is fed to a second zone which is maintained at atmospheric pressure. The polymer solution is discharged into vigorously stirred isopropanol to form fibrils. Polymer solvent is distilled from the resulting slurry. The fibrils are refined in the isopropanol slurry. The polymer solvent and the isopropanol are recycled to the process.

Method for manufacture of olefin polymer fibrils

A process for separating tar and solid particles from coal liquefaction products using a highly selective halogenated aliphatic solvent which removes essentially all of the tar and solid particles from the coal liquefaction products wherein a minimum amount of energy is used. This is accomplished by contacting said coal liquefaction products with the halogenated aliphatic solvent to form two phases, one containing said tar and solid particles and the other containing said solvent and the remainder of said coal liquefaction products.

Process for separating tar and solids from coal liquefaction products

A process for increasing the fuel yield of coal liquefaction products by extracting the asphaltenes, resins and aromatic compounds from said coal liquefaction products. This is accomplished by contacting said coal liquefaction products with a halogenated aliphatic solvent to form two phases, one containing tar and the other containing said solvent and the remainder of said coal liquefaction products, separating said phases from each other and treating said tar phase with a second solvent to recover asphaltenes, resins and/or aromatics in said tar phase. The resulting asphaltenes, resins and/or aromatics are suitable for upgrading to produce additional synthetic fuel.

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Houston, TX, United States of America

Edward W Smith