Suntech, Inc.

Sun Ventures, Inc.

Other

The United States of America As Represented by the United States

Edward J Janoski

Abraham Daniel Schneider

Richard E Ware

Elmer J Hollstein

Edward G Scheibel

Robert E Moore

Richard E Mitchell

Tetrahydrotricyclopentadienes are isomerized to a low pour point, high energy missile fuel. Aluminum trichloride is the catalyst and an inert chlorinated hydrocarbon solvent is present. The mole ratio of AlClto the diene is in the range between from about 0.005 to about 1.0. The isomerization temperature is in the range from between about &#x2212;20&#xb0; C. to about 25&#xb0; C.

Isomerization of tetrahyd rotricyclopentadienes to missile fuel

A process for removing halide ions from a hydrocarbon feedstream containing halogenated hydrocarbons wherein the contaminated feedstock is contacted with a solution of a suitable oxidizing acid containing a lanthanide oxide, the acid being present in a concentration of at least about 50 weight percent for a time sufficient to remove substantially all of the halide ion from the hydrocarbon feedstock.

Method for removing chlorine compounds from hydrocarbon mixtures

Oxygen compounds are removed, e.g., by extraction, from a coal liquid prior to its hydrogenation. As a result, compared to hydrogenation of such a non-treated coal liquid, the rate of nitrogen removal is increased.

Process to upgrade coal liquids by extraction prior to

Tetrahydrodimethyldicyclopentadiene is catalytically isomerized to a liquid isomeric mixture having a suitable low temperature viscosity making it suitable as a missile fuel. The catalyst comprises an acidic alumina. Hydrogen is also present and in an amount sufficient to maintain the isomerization activity of the alumina. The elevated temperature is sufficient to cause isomerization.

Process for isomerization of tetrahydrodimethyldicyclopentadiene

Oxygen compounds are removed, e.g., by solvent extraction, from a shale oil prior to its hydrogenation. As a result, the amount of hydrogen consumed during subsequent hydrogenation to achieve a given level of nitrogen for the shale oil is less than that which would occur if the oxygen compounds were not removed from the shale oil. Removal of the nitrogen is necessary to avoid adverse effects on subsequent shale oil processing steps such as catalytic cracking.

Process to upgrade shale oil

Dimethyldicyclopentadiene is continuously hydrogenated to tetrahydrodimethyldicyclopentadiene and then the latter is continuously isomerized to a missile fuel. Both the hydrogenation and the isomerization steps use a nickel on silica-alumina catalyst. The temperature of the hydrogenation is in the range of about 70.degree.-260.degree. C., and the temperature of the isomerization is in the range of about 200.degree.-280.degree. C. The space velocity of the hydrogenation is about 0.1 to about 2.0 volumes of the diene charged per volume of catalyst per hour and the space velocity of the isomerization is about 0.1 to about 3.0 volumes of the hydrocarbon charged per volume of catalyst per hour. The pressure range for hydrogenation is between about 200 psig to about 3000 psig and for isomerization between from about 10 psig to about 1500 psig. Hydrogen is present during the isomerization.

Continuous process for conversion of dimethyldicyclopentadiene to

Endo-tetrahydrodicyclopentadiene is isomerized to its exo-isomer in the presence of aluminum trichloride at a temperature in the range between from about -.degree. C to about 90.degree. C. The mole ratio of AlCl.sub.3 to the tetrahydrodiene is in the range between from about 0.001 to about 0.75. An inert solvent may also be used. The very facile isomerization is essentially quantitative. The exoisomer has utility as a relatively high BTU/gallon, viscosity-lowering difluent for a missile fuel.

Isomerization of endo-tetrahydrodicyclopentadiene to a missile fuel

Mixed tetrahydropolycyclopentadienes are isomerized in the presence of anhydrous aluminum trichloride to form an additive suitable for use with a high energy missile fuel. The amount of aluminum trichloride present is such that the weight ratio of trichloride to the tetrahydropolydiene is in the range between from about 0.005 to about 0.75. Also the isomerization involves an inert solvent and is at a temperature between from about -20.degree. C to about 25.degree. C. Also anhydrous hydrogen chloride is present to facilitate the isomerization.

Isomerization of tetrahydropolycyclopentadienes to a missile fuel

Ionic alcoholysis of Binor-S, a C.sub.14 heptacyclic, saturated hydrocarbon, in the presence of a primary alcohol and hydrogen, yields a low melting point product containing novel alkyl ethers of Binor-S. Alcoholysis occurs at about 50.degree.-300.degree. C. and at about 100-10,000 p.s.i.g. in the presence of Raney nickel, palladium-on-carbon or palladium-on-alumina catalyst promoted by a hydrogen halide or its equivalent. Resulting product has utility as a high energy fuel.

Alkyl ethers of Binor-S

Novel, highly fluorinated hydrocarbons derived from the fluorination of alkyladamantanes, may be produced by known means, as for example by the process comprising contacting an alkyladamantane hydrocarbon, in vapor phase, with a fluoride of a transition metal (e.g., CoF.sub.3, MnF.sub.3, AgF.sub.2) at 200.degree.-400.degree. C. The preferred adamantane hydrocarbons contain in the range of 11-30 (more preferred 12 to 14) carbon atoms and contain methyl and/or ethyl groups.

Process of manufacture of flourinated alkyladamantanes

Ionic hydrogenolysis of Binor-S, a C.sub.14 heptacyclic saturated hydrocarbon, yields a low melting point product containing predominantly hexacyclics and lesser amounts of pentacyclics. Hydrogenolysis occurs at about 50.degree.-200.degree. C and at about 100-10,000 p.s.i.g. in the presence of a palladium-on-carbon catalyst, palladium-on-alumina or Raney nickel and is promoted by a hydrogen halide or its equivalent. Resulting product has utility as a high energy fuel.

Growing community of inventors

Havertown, PA, United States of America

Edward J Janoski