Betzdearborn, Inc.

Betz Laboratories, Inc.

Ge Betz, Inc.

Edward J Connors

Fu Chen

Michelle L Cotter

Paul R Hart

J Michael Brown

Water soluable, aqueous salt solution dispersible polymers and aqueous salt solutions containing dispersed polymers are produced by polymerization of ethylenically unsaturated soluble monomers in an aqueous salt solution in the presence of at least one carbohydrate. The polymers and aqueous salt solutions containing the dispersed polymers are useful for paper making, water clarification and emulsion breaking.

Aqueous dispersion polymers

Oil-in-water (reverse) and water-in-oil (obverse) emulsions in crude oil production and processing systems are resolved by addition of a treatment solution comprising a copolymer of acryloxyethyltrimethyl ammonium chloride (AETAC) and acrylamide. The mole percent of AETAC is above about 20% and the molecular weight (grams per mole) of the copolymer is above about 2 million. The treatment solution is effective in matrix which include high percentages of oil and at high temperatures.

Method of resolving oil and water emulsions

A process for preparing a water-soluble polymer dispersion is herein provided which is characterized by polymerizing from about 10 to 50 mole percent of a monomer having a formula (II); from about 1 to 50 mole percent of N-alkylacrylamide, N, N-dialkylacrylamide or mixtures thereof; having a formula (III) from about 1 to 70 mole percent acrylamide; and optionally up to about 4 mole percent of a monomer having a formula (I) having a benzyl functionality. The polymerization is carried out in the presence of an aqueous solution of a polyvalent anionic salt which contains (1) a water soluble cationic polymer which is insoluble in the aqueous salt solution and (2) a water soluble cationic polymer which is soluble in the aqueous salt solution.

Process for the preparation of aqueous dispersion polymers

A process for preparing a water-soluble polymer dispersion is herein provided which is characterized by polymerizing from about 10 to 50 mole percent of a monomer having a formula (II); from about 1 to 50 mole percent of N-alkylacrylamide, N,N-dialkylacrylamide or mixtures thereof; having a formula (III) from about 1 to 70 mole percent acrylamide; and optionally up to about 4 mole percent of a monomer having a formula (I) having a benzyl functionality. The polymerization is carried out in the presence of an aqueous solution of a polyvalent anionic salt which contains (1) a water soluble cationic polymer which is insoluble in the aqueous salt solution and (2) a water soluble cationic polymer which is soluble in the aqueous salt solution.

Process for the preparations of aqueous dispersion polymers

The present disclosure is directed to water-in-oil emulsion polymers which are used to flocculate matter suspended in aqueous systems. The disclosure and invention are particularly relevent to emulsion polymers which are self-inverting.

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Conshohocken, PA, United States of America

Edward J Connors