Amax Incorporated

Edward I Wiewiorowski

Ranko P Crnojevich

Peter H Yu

Luther R Tinnin

Dale K Huggins

Eddie C Chou

Andrew B Case

Ben W Wiegers

Donald H Wilkinson

A method is provided for treating sludge containing substantial amounts of chromium, aluminum and iron and residuals of other elements. The method comprises forming a slurry of the sludge in water at a temperature ranging from ambient to 150.degree. F. with the specific gravity of the slurry ranging from about 1.05 to 1.25, and adding a mineral acid to the slurry to provide a pH ranging from about 0.1-3 to dissolve selectively the aluminum and the chromium and leave a solids residue containing gangue material comprising an oxidized iron compound, calcium sulfate, calcium fluoride, calcium silicate among other solids. The pH of the solution is controlled at range of about 2 to 3.5 to precipitate undesirable elements, including iron, without substantially adversely affecting the dissolved chromium and aluminum. The chromium/aluminum-containing solution is separated from the solids therein to provide a substantially purified solution of chromium/-aluminum, and the pH of the solution raised to a range of about 12 to 13.8 to precipitate chromium as chromium hydroxide and provide a pregnant aluminate solution. The chromium hydroxide-containing solution is then subjected to solid/liquid separation to extract chromium hydroxide therefrom and providea pregnant aluminate solution which is thereafter treated to recover alumina therefrom.

Reclaiming of aluminum-chromium waste materials from etching operations

Metal values and alumina are recovered from spent, usually oily, catalysts by oxygen pressure leaching with sodium hydroxide and/or sodium aluminate to dissolve molybdenum, vanadium and/or tungsten and provide a solid, filterable residue containing alumina and cobalt and/or nickel, the residue is digested with sodium hydroxide to give a sodium aluminate solution and a residue enriched in nickel and/or cobalt, alumina is recovered from the sodium aluminate solution as a solid and the remaining supernatant solution is recycled to the oxygen pressure leaching step wherein the alumina content of the aluminate solution is precipitated and a bleed for metals in the aluminate solution is provided.

Cyclic process for recovering metal values and alumina from spent

Spent hydrodesulfurization catalysts containing alumina, at least one metal from the group consisting of molybdenum, tungsten and vanadium and at least one metal from the group consisting of nickel and cobalt, sulfur, and, usually, residual oil are oxygen pressure leached at a temperature of at least about 400.degree. F. with a base from the group consisting of sodium hydroxide and sodium aluminte in at least stoichimetric amount to yield a solution having a pH between about 7 and 9 containing dissolved molybdenum, vanadium and any tungsten which may be recovered and a readily filterable residue containing aluminum, nickel and cobalt which may be worked up to recover the valuable constituents, with overall processing being accomplished in an environmentally acceptable manner.

Selective extraction of molybdenum and vanadium from spent catalysts by

A process is provided for removing hexavalent selenium from an acidic sulfate solution containing at least one metal ion from the group consisting of nickel, cobalt and copper at ambient pressure and at a temperature not exceeding the boiling point of the solution. The solution is treated with an agent from the group consisting of a compound which will produce nascent hydrogen in the solution and finely divided metal from the group consisting of nickel, cobalt and copper resulting from in situ precipitation of the metal in the acid sulfate solution. Thus, following treatment with the compound, the hexavalent selenium is reduced to a form separable from the solution by solid-liquid separation.

Removal of hexavalent selenium from nickel, cobalt or copper sulfate

Selenium is precipitated from solutions containing at least one metal selected from the group consisting of nickel, cobalt, copper, iron, zinc, manganese, magnesium, chromium and cadmium by adding chromous sulfate to the solution to precipitate selenium therefrom.

Production of metals with low selenium contents

Selenium is precipitated from solutions or slurries containing nonferrous metals, particularly nickel by contacting the solution or slurries with a semimetallic chromous precipitant of the nonferrous metal, particularly nickel, which has a nonferrous metal to chromium ratio between about 10:1 and about 200:1 and which has a metallic content between about 50% and about 90%. The semimetallic chromous precipitant of the nonferrous metal is prepared by hydrogen reducing a solution of the nonferrous metal or slurries containing chromous salts in amount to provide the aforementioned nickel to chromium ratios.

Production of nonferrous metals with low selenium contents

A method is provided for the recovery of cobalt from nickel solutions, wherein cobalt is separated from said solution as a precipitate containing cobaltic hydroxide precipitate and also containing nickel, the method comprising dissolving the precipitate for the subsequent recovery of cobalt therefrom by reducing trivalent metal in said precipitate to the divalent state. This is achieved by forming an aqueous slurry of said precipitate acidified with sulfuric acid to a pH ranging from about 0.1 to 2, subjecting the precipitate of said aqueous slurry to electrolytic reduction at the cathode of an electrolytic cell having an insoluble anode, said precipitate being isolated from said anode during said electrolytic reduction and continuing the electrolytic reduction of said precipitate from the trivalent to the divalent state and effect the dissolution thereof.

Cathodic dissolution of cobaltic hydroxide

A method is provided for effecting the dissolution of a cobaltic hydroxide-containing precipitate which may also contain nickel, wherein an aqueous slurry of the precipitate containing trivalent metal is acidified to a pH of from about 0.1 to 2, and the aqueous slurry then treated with an organic reductant to effect substantial reduction of the trivalent metal to the divalent state and hence the dissolution of said precipitate.

Dissolution of cobaltic hydroxide with organic reductant

A method is provided for decreasing the silicon content of relatively pure nickel and/or cobalt powder, wherein silicon is present as an impurity substantially in the oxidic state. The method comprises mixing the metal powder in an aqueous solution of an alkali metal hydroxide, e.g. sodium hydroxide, with the temperature of the solution ranging from ambient to below boiling and maintaining the powder in contact with the solution until the silicon content of the powder has been reduced to the desired level.

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New Orleans, LA, United States of America

Edward I Wiewiorowski