Pilkington Brothers P.l.c.

Edward Hargreaves

Joseph E Lewis

Andrew F Simpson

Infra red reflecting fluorine-containing tin oxide coatings are applied to glass using a solid chlorine-containing volatile inorganic tin (IV) compound optionally containing fluorine. The inorganic tin (IV) compound is suspended in carrier gas. When that compound is fluorine free, the suspension is directed on to the hot glass surface in the presence of a separate source of fluorine which may be an organic tin compound. When the inorganic tin (IV) compound contains fluorine, the suspension is directed on to the hot glass surface in the presence of an organic tin compound which may contain fluorine. Examples of the inorganic tin (IV) compounds which may be used are ammonium hexahalostannates of the formula (NH.sub.4).sub.2 SnHal.sub.6 wherein Hal represents halogen, being either chlorine, or a minor atomic proportion of fluorine and the balance chlorine.

Production of infrared reflecting coatings on glass

Apparatus for coating glass by pyrolysis of a powder at the glass surface to form a coating on that surface, and in which a flow of a suspension of a powder in a carrier gas is applied to a moving hot glass surface across the width of that surface, comprising means for supporting and advancing hot glass beneath an applicator comprising a chamber terminating in a slot extending across the supporting means close to the path of the glass surface to be coated, which chamber diverges downwardly from a central inlet for the downward flow of the suspension of the powder.

Apparatus for and method of coating glass

Solid tin (IV) compounds, free from carbon-tin bonds, and containing both chlorine and fluorine are used to apply infra red reflecting fluorine containing tin oxide coatings to glass. Examples of the tin compounds that may be used are ammonium hexahalostannates of the formula (NH.sub.4).sub.2 SnHal.sub.6 wherein Hal represents halogen, and a minor atomic proportion of the halogen present is fluorine and the balance is chlorine. The tin compounds are dispersed in finely divided form in a carrier gas, and the suspension of the tin compound in the carrier gas is directed on to a hot glass surface to be coated.

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Prescot, United Kingdom

Edward Hargreaves