Commissariat a L'energie Atomique

Edmond Zellner

Jacques Duhayon

Jean-Pierre Goumondy

Andre Leseur

Maurice Tarnero

Maurice Anav

Michel Jean Jacques

Christiane Brugere

Jean-Marie Morel

Pierre Michel

The method of processing alkaline solutions containing radioactive iodine consists in dissolving irradiated fuels in a nitric acid solution. The vapors constituted essentially by nitrogen oxides, iodine and water formed during dissolution are passed into a condenser and then into a first absorption column in which the recombined nitric acid is formed. The recombined acid is returned to the dissolver while the gases discharged from the first absorption column are passed into a second absorption column in counterflow to an alkaline solution which is loaded with iodine and with nitrous ions. The alkaline solution discharged from the second absorption column is passed into a reaction vessel containing a mixture of nitric acid and sulphamic acid which destroys the nitrous products and releases the iodine.

Method for processing alkaline solutions containing radioactive iodine

After dissolving irradiated nuclear fuel in a nitric acid medium, the vapor produced by this dissolution and consisting of water, nitrogen oxides and iodine is passed into a condenser, then into a column for the absorption of the nitrous vapor in which is formed recombined nitric acid containing iodine and nitrous ions, the iodine contained in the recombined acid being then separated-out. The nitrous ions present in the recombined acid have a favorable influence on the important first stage of that separation.

Method of extraction, trapping and storage of radioactive iodine

The method of recovery of hydrogen chloride in gaseous form from an organic solvent loaded with hydrochloric acid in a dilute aqueous solution consists in carrying out prior to distillation a dehydration of the loaded organic solvent in a dehydration extractor in which the solvent is circulated countercurrent to an aqueous solution having a high chloride concentration.

Method for recovery of hydrogen chloride from dilute solutions

Growing community of inventors

Gif-sur-Yvette, France

Edmond Zellner