Union Carbide Corporation

Ck Witco Corporation

Polyplexx, LLC

Union Carbide Chemicals & Plastics Technology Corporation

Union Carbide Chemicals and Plastics Company, Inc.

Edmond J Derderian

Richard M Gerkin

Paul E Austin

Robert A Kayser

John N Argyropoulos

Brian Terry Keen

Kenneth A Nielsen

James A Condron

Keith D Cavender

Alan E Wang

Eugene L Jarrett

Timothy G Bumgardner

The present invention teaches a new process to produce novel, hard, optically clear, impact-resistant polyurethane polymers that are characterized by excellent thermo mechanical properties and chemical resistance, and the polymers made as a result of such a process. The polyurethanes are made by reacting in a one step process

Transparent polyurethanes

The present invention teaches a new process to produce novel, hard, optically clear, impact-resistant polyurethane polymers that are characterized by excellent thermo mechanical properties and chemical resistance, and the polymers made as a result of such a process. The polyurethanes are made by reacting a) a prepolymer made by reacting a polyisocyanate with a primary amine-terminated polyether with an amine functionality of about 2 and a molecular weight of &#x3e;1000, and in which the free &#x2014;NCO content of the resulting prepolymer is &#x3e;18% by weight; with b) (i) a polyol having an average hydroxyl functionality greater than or equal to 2 and an average hydroxyl equivalent weight of from about 300 to about 1,000, and (ii) a curing agent that has isocyanate reactive groups, a functionality of 2 to 3 and a molecular weight of &#x3c;400. More preferably the prepolymer is made by reacting a cycloaliphatic polyisocyanate with a primary amine-terminated polyether diamine of 2000 to about 2500 molecular weight, the polyol is either a polyester polyol triol with a molecular weight of between about 540 and 900, or a polyether glycol with a molecular weight of between about 650 and 2000, or a polyester polyol diol with a molecular weight of up to 2,000, and the curing agent is either dianhydrohexitol, an aromatic diamine, an aromatic ring containing diol or a cyclohexanedimethanol.

Impact-resistant polyurethane

An improved process is provided for the preparation of siloxane-oxyalkylene and siloxane-alkyl copolymer compositions via a hydrosilation reaction in the presence of high boiling point natural vegetable oils as the reaction solvent. The reaction solvent need not be removed from the block copolymer product, and indeed is beneficial to remain with the copolymer particularly when the copolymer is used as a surfactant for polyurethane foam formulations. Soybean oil and linseed oil are the preferred high boiling natural oil solvents when the copolymer product is to be used in the preparation of the surfactants for polyurethane foams. High resiliency polyurethane foam prepared with these natural oils present in the surfactant preparation afforded improved compression sets, wet compression sets and humid aged compression sets. Additionally, the use of the surfactants made with natural oils as a reaction solvent or consequently surfactants post diluted with natural oils when employed in the preparation of polyurethane foam afforded foams with greatly reduced amounts of &ldquo;glass fogging&rdquo;.

Hydrosilation in high boiling natural oils

An improved process is provided for the preparation of siloxane-oxyalkylene and siloxane-alkyl copolymer compositions via a hydrosilation reaction in the presence of high boiling point natural vegetable oils as the reaction solvent. The reaction solvent need not be removed from the block copolymer product, and indeed is beneficial to remain with the copolymer particularly when the copolymer is used as a surfactant for polyurethane foam formulations. Soybean oil and linseed oil are the preferred high boiling natural oil solvents when the copolymer product is to be used in the preparation of the surfactants for polyurethane foams. High resiliency polyurethane foam prepared with these natural oils present in the surfactant preparation afforded improved compression sets, wet compression sets and humid aged compression sets. Additionally, the use of the surfactants made with natural oils as a reaction solvent or consequently surfactants post diluted with natural oils when employed in the preparation of polyurethane foam afforded foams with greatly reduced amounts of 'glass fogging'.

Hydrosilation in high boiling natural vegetable oils

A process for delivering a predetermined ratio of a compressible fluid and a non-compressible fluid which comprises the measurement of only the flowrate of the compressible fluid, the activation of an air-driven positive displacement pump at appropriate times, the pumping of a non-compressible fluid with the air-driven pump, mixing the supercritical fluid and non-compressible fluid and depositing the mixture onto a substrate.

Supercritical ratio control system utilizing a sonic flow venturi and an

A process for producing and refining trisubstituted glycol monoesters, e.g., 2,2,4-trimethyl-1,3-pentanediol monoester. The improvement resides in immediately distilling the crude condensation product mixture as it leaves the reactor before it has cooled or had any contact with added water.

Production of trisubstituted hydroxyalkyl alkanoates from aldehydes

A process which comprises (i) the generation of release surfaces by application to predetermined areas of a solid surface of a solution, suspension or dispersion of a release agent and a supercritical fluid that vaporizes from the release agent, (ii) the deposition of a mass onto the release surface containing the release agent, and (iii) the separation of the mass or a product derived from the mass from such surface covered by the release agent. Novel apparatus for carrying out the process are described.

Mold release coating process and apparatus using a supercritical fluid

A phase-stable aqueous gasoline/ethanol fuel composition containing an additional alcohol selected from the group consisting of n-butanol, 2-butanol, iso-butanol, 2-methyl-1-butanol, 3-methyl-1-butanol, n-pentanol, and mixtures thereof, as well as a method for producing said fuel composition.

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Charleston, WV, United States of America

Edmond J Derderian