Degussa Aktiengesellschaft

Deutsche Gold- Und Silber-scheideanstalt Vormals Roessler

Other

Degussa - Huls Ag

Degussa Gmbh

Degusaa Aktiengesellschaft (degussa Ag)

Edgar Koberstein

Bernd Engler

Rainer Domesle

Herbert Voelker

Reinhold Brand

Hans-Dieter Pletka

Herbert M Volker

Alfred Bozon

Eduard Lakatos

Egbert Lox

Peter K Kleinschmit

Jorg Hensel

Wolfgang Honnen

Peter Kleine-Moellhoff

Michael Baacke

Klaus Deller

Johannes Ohmer

Peter Schubert

Klaus Ostgathe

Stephan Blumrich

Akos Kiss

Rudolf Schwarz

Thomas Lehmann

Werner Hartmann

Mustafa Siray

Felix Schmidt

Klaus-Peter Muller

Ferdinand Theissen

Michael Berger

Martin H Volker

Juergen Martens

Wolfgang Honen

Hans-Guenter Koban

Martin Foerster

Reinhold Beand

Peter Kleine-Mollhoff

Klaus Muller

H Bernd Engler

A coating dispersion is shown for the production of catalysis-promoting coatings on an inert, structure-reinforcing element. The solids of the dispersion are present in various particle fractions and lead to a relatively rough coating surface with improved exchange between the exhaust gas and the catalyst surface. This results in improved heat-up behavior of the catalyst.

Coating dispersion for exhaust gas catalysts

An open-cell, monolithic catalyst for the purification of diesel-engine exhaust gas with a coating of finely divided inorganic oxides containing vanadium and platinum group metal as active components. The active components of the oxidic coating are added as water-soluble precursors which are then converted by means of tempering, preferably in an atmosphere of hydrogen, into the active component.

Method for using a catalyst to purify exhaust gases from a diesel engine

A catalyst for the selective reduction of nitrous oxide with ammonia contains, in addition to titanium oxide as component (A), at least one oxide of W, Si, B, Al, P, Zr, Ba, Y, La, Ce and at least one oxide of Y, Nb, Mo, Fe, Cu as component (B), whereby the atomic ratio between the elements of components (A) and (B) amounts to 1:0.001 up to 1. The catalyst can be obtained by kneading reactive titanium oxide with a high specific surface of predominantly anatase with the substances of component (B) or their preliminary stages, adding processing agents, winding up with a homogeneous kneaded mass, extruding the latter, drying the extrudate and calcining in air at 300.degree.-800.degree. C.

Catalyst for selective reduction of nitrous oxides with ammonia

A solid catalyst for the oxidation of sulfur dioxide in gas currents containing oxygen, which catalyst includes vanadium oxide and alkali metal oxides, alkali metal sulfates or mixtures thereof, as an active substance, silicon, aluminum, or mixtures thereof, in oxide form, for surface area enlargement, and titanium dioxide in anatase form, rutile form, or mixtures thereof, as a carrier material and a ceramic binder. The metals in these finely sintered components which impart discrete functions are present in certain atomic ratios. The fine sintering takes place according to a production method especially by means of differentiated conditions of drying, calcining and sintering. One use for the invention is the desulfurization of waste gases from combustion processes and industrial plants.

Catalyst for the oxidation of sulfur dioxide and method for the

A catalyst for the selective reduction of nitrous oxide with ammonia contains, in addition to titanium oxide as component (A), at least one oxide of W, Si, B, Al, P, Zr, Ba, Y, La, Ce and at least one oxide of V, Nb, Mo, Fe, Cu as component (B), whereby the atomic ratio between the elements of components (A) and (B) amounts to 1:0.001 up to 1. The catalyst can be obtained by kneading reactive titanium oxide with a high specific surface of predominantly anatase with the substances of component (B) or their preliminary stages, adding processing agents, winding up with a homogeneous kneaded mass, extruding the latter, drying the extrudate and calcining in air at 300.degree.-800.degree. C.

Process for producing a catalyst for selective reduction of nitrous

A catalyst for purifying the exhaust gases of internal combustion engines with improved light-off behavior and improved durability with reduced specific noble-metal content is disclosed which uses active aluminum oxide provided with customary promoters as carrier and platinum and/or palladium and rhodium in customary amounts as noble metals. In addition, it contains one or more base metals in amounts up to 5 times the mass of the total noble metal which are brought into the immediate vicinity of the rhodium by means of a special manufacturing technique.

Catalyst for purifying the exhaust gases of internal combustion engines

Catalyst for purification of exhaust gases of diesel engines and method

A device for the continuous measurement of the ammonia concentration in gases in the ppm range includes a columnar absorption vessel (1) with a hemispherical bottom (4). The bottom of the column includes an overflow (3) and an outlet (5). The gas introduction pipe (7,8) empties above the bottom (4) and below a sieve bottom (6) arranged in the column (1). A packing material (10) rests on the sieve bottom (6), which packing (10) essentially fills the absorption column (1). A cooling part (11) extends from the absorption column (1). The cooling part (11) includes a cooling zone (15) and a gas collection space (16) above it with a closable connection piece (13). A pipe (14), which may include a serrated crown on each end, runs from the gas collecting space (16) downward in a cooled manner to the packing 10. The liquid absorption agent is introduced through a lateral connection piece (18) into the gas collection space (16). For the measurement of ammonia concentration, a certain volume flow of the gas to be measured is washed in a countercurrent flow with the absorption agent, and the NH.sub.3 content is determined in a part of the ammonia containing absorption agent. The volume flow rate of the absorption agent and of the gas from which NH.sub.3 has been removed is measured (the latter being dried), and the ammonia concentration is thereby calculated.

Device and method for the continuous measurement of the ammonia

A one-piece catalyst for purifying exhaust gases, particularly from internal combustion engines and gas turbines operated above the stoichiometric ratio. The one-piece honeycomb ceramic or metal carrier has a reduction catalyst on its leading-edge portion and an oxidation catalyst on its trailing-edge portion.

Catalyst for purifying exhaust gases from internal combustion engines

Titanium dioxide compacts are produced by intensively mixing pyrogenically produced titanium dioxide in the presence of deionized water with a wetting agent and/or with a base and/or optionally with a binder and/or optionally with an auxiliary deformation agent and/or optionally with a pore former, extruding the mass thus obtained at pressures between 5 and 100 bars to form shaped articles, drying the shaped articles at temperatures between 50.degree. and 120.degree. C. and subsequently calcining the shaped articles in the ambient air at temperatures of 400.degree. to 700.degree. C. for 1 to 5 hours.

Titanium dioxide compacts, method of their production and a catalyst

A zeolite catalyst and a method for reduction of nitrogen oxides present in waste gas streams is described. The method includes mixing the waste gas containing nitrogen oxides with ammonia. At an elevated temperature, this mixture is passed over a zeolite catalyst. Preferably, the zeolite catalyst is in a monolithic or honeycomb form. The zeolite catalyst includes one or more of the following subgroup metals: copper, iron, molybdeum and cerium. The zeolite catalysts made in accordance with this invention show better conversion of nitrogen oxides and longer life than known catalysts.

Method for the reduction of nitrogen oxides from waste gases using a

A catalyst is described made of active aluminum oxide with additives of CeO.sub.2, ZrO.sub.2, and Fe.sub.2 O.sub.3 and/or NiO as carrier and an active phase, applied thereon and consisting of platinum, palladium and/or rhodium, and a base metal, which is obtainable by impregnation of the additive-containing carrier with solutions of salts of the metals for the active phase, wherein the base metal of the active phase is cerium, by drying, and by heating to 250.degree. to 650.degree. C. The catalyst can be used for the oxidation and/or reduction of exhaust gases from internal combustion engines.

An oxidizing and/or reducing exhaust gas purification catalyst with a reduced tendency to emit H.sub.2 S contains active Al.sub.2 O.sub.3 as carrier which is charged with CeO.sub.2 and optionally ZrO.sub.2 as well as Pt, Pd and/or Rh and, in addition, 0.1 to 40% by weight ZnO relative to Al.sub.2 O.sub.3.

Catalyst for the purification of exhaust gases of internal combustion

A monolithic or honeycomb-catalyst, in particular for purifying the exhaust gases of internal-combustion engines, composed of an inert ceramic or metallic support traversed by parallel flow channels, a layer disposed thereon and composed of catalysis-promoting metal oxide and a catalytically active component supported by the metal oxide, wherein the concentration of the catalysis-promoting metal oxide increases from the periphery to the central axis of the support. Alternatively, the catalysis-promoting metal oxide is essentially equally distributed between central axis and periphery of the support, but concentration of catalytically active component increases from the central axis to the periphery of the support.

Monolithic or honeycomb-type catalyst

Growing community of inventors

Alzenau, Germany

Edgar Koberstein