Th. Goldschmidt Ag

Eckehard Schamberg

Gotz Koerner

Jurgen Fock

Harald Rau

Christian Weitemeyer

Ulrich Holtschmidt

Manfred Priesch

Herwig Fritsch

Dieter Hellwig

Herbert Quilitsch

Herbert Giesing

Eberhard Esselborn

Roland Sucker

Hans-Jurgen Patzke

Otto Klocker

Werner Schafer

Arnold Laqua

G/o/ Tz Koerner

Manfred Grasse

Vaclay Kropac

Fritz Spieker

Jakob Wassermeyer

Wolfgang Hoffmann

A composition is disclosed which is useful for the water-repellent impregnation of porous mineral building materials. The composition is based on organosilicon compounds which contain alkoxy groups and comprises an emulsion which contains 2.5 to 25% by weight of an alkoxysilane of the formula

Preparation for the water-repellent impregnation of porous mineral

Method for impregnating mineral building materials, with aqueous solutions of silanols and/or siloxanols is disclosed. The solution is obtained by continuous hydrolysis of alkoxysilanes and/or alkoxysiloxanes, of the general formula ##EQU1## wherein R.sup.1 =alkyl with 1 to 8 carbon atoms, at least 90% of the R.sup.1 groups in the average molecule being alkyl groups with 1 to 4 carbon atoms,

Method for impregnating mineral building materials

A continuous process for the preparation of alkoxypolysiloxane in which silane or a silane mixture and a mixture of hydrogen chloride-containing alcohol and water is fed continuously into the lower region of preferably cylindrical stirred reactor, the reaction product formed together with excess hydrogen chloride-containing alcohol is drawn off continuously after residence time of 30 to 180 minutes at the upper end of the reactor and the undissolved, gaseous portion of hydrogen chloride is carried off at the head of the reactor, the temperature of the reaction mixture or the reaction product, as it flows through the reactor, being raised from a range of -17.degree. to +30.degree. C. to range of +30.degree. to +80.degree. C., the temperature gradient having to be at least 10.degree. C., and the excess alcohol and dissolved hydrogen chloride being removed outside of the reactor in a known manner from the reaction product formed, and the hydrogen chloride-containing alcohol obtained while working up to reaction product being recycled to the reactor. The invention furthermore relates to an apparatus which is particularly suitable for implementing the process.

Process and apparatus for continuously synthesizing alkoxypolysiloxanes

Heat-curable vehicles and a process for their preparation which can be diluted with water after neutralization, by the partial reaction of a low molecular weight alkoxysiloxane with a low molecular weight polyol having carboxyl groups and at least two hydroxyl groups. The vehicle dissolves in water, optionally in the presence of slight amounts of auxiliary solvents, highly concentrated solutions being obtained with a solids content of 80 weight percent or higher, yet a relatively low viscosity.

Process for the synthesis of a water-dilutable, heat-curable

A composition for making building materials water-repellent, before or after they are shaped, the composition containing organoalkoxysiloxanes of the formula ##STR1## in which R.sup.1 is an alkyl or aryl radical, R.sup.2 is an alkyl radical with 1 to 4 carbon atoms, a=0.8 to 1.5, and b is not greater than 2. The composition contains

Preparation for making inorganic building materials water-repellent

The invention relates to a process for heat-curable silicone resins and their synthesis by reacting a low molecular weight alkoxysilane with a low molecular weight polyol with 2 to 6 hydroxyl groups in the molecule. The reaction products have a very low viscosity, which is suitable for processing when about 20% of solvent, based on the non-volatile resin, are added.

Process for the synthesis of heat-curable silicone resins

A method for preparing thermosettable urea-formaldehyde resins having a urea to formaldehyde molar ratio of 1:1 to 1:1.5 wherein urea and formaldehyde are first reacted in an aqueous solution at a molar ratio of 1:1.5 to 1:4 in the pH range between 7.5 to 10, and then condensing the reactants in a pH range from 4 to 6 to a precipitation number of 1:1.5 to 1:10, thereafter adjusting the pH to 7 to 10 and adding the remaining urea to obtain a molar ratio of 1:1 to 1:1.5 and continuing the reaction until a precipitation number of 1:0.5 to 1:3 is obtained. The products obtained have a uniform molecular weight and good penetration properties when used to impregnate supporting webs for coating wood-based panels.

Process for the preparation of thermosettable urea-formaldehyde resins

This invention relates to an improvement in a substrate web coated with a thermosetting coating resin and optionally impregnated with an aminoplast resin, in particular a web of paper, for the surface finishing of woodwork panels or laminates, the improvement that the coating resin is a modified polyester resin, composed of (a) 60 to 95% by weight of a hardenable polyester resin, (b) 1 to 15% by weight of a cross-linking agent for the polyester resin, (c) 5 to 40% by weight of a thermoplastic containing predominantly linear, high-molecular weight, reactive groups, (d) 1 to 15% by weight of a monomer with at least one polymerizable double bond and at least one group which reacts with the reactive group of the thermoplastic, and (e) a hardening catalyst, and optionally dyes, pigments and/or fillers. The invention also relates to a process for preparing a synthetic resin coated substrate web.

Substrate web coated with a thermosetting coating resin

A method for the preparation of hardenable urea-formaldehyde resins for use in impregnating and coating carrier webs wherein urea and formaldehyde are first reacted in the presence of an aminosulfonic acid and ammonia, additional aminosulfonic acid is added and the mixture is further reacted to adjust the viscosity of the solution and then additional ammonia and urea are added to the reaction mixture and the mixture is further reacted to adjust the viscosity thereof, and wherein a polymer formed from the monomers of the formula ##STR1## in which R.sup.1 =H or CH.sub.3,

Process for the preparation of solutions of urea-formaldehyde resins for

This invention relates to a thermosetting, substrate-free, storage-resistant synthetic resin foil which is hard, scratch- and abrasion-proof in the hardened state, comprising: (a) about 60 to 95% by weight of a hardenable polyester resin, (b) about 1 to 15% by weight of a cross-linking agent for the polyester resin, (c) about 5 to 40% by weight of a thermoplastic containing predominantly linear, high-molecular weight reactive groups, (d) about 1 to 15% by weight of a monomer with at least one polymerizable double bond and at least one group reactable with the reactive group of the thermoplastic under the conditions of reaction, (e) and at least one hardening catalyst, and optionally dyestuffs, pigments and/or fillers. The invention also relates to a process for preparing the novel foil of the invention.

Substrate-less, thermosetting synthetic resin foil

This invention relates to a copolymerizate foil suitable for surface finishing, and which may be thermosetting, composed of: (A) an elastomeric copolymerizate with a glass transition temperature no higher than +10.degree. C., obtained by copolymerizing

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Essen, Germany

Eckehard Schamberg