Thueringisches Institut Fuer Textil-Und Kunststoff-Forschung E.v.

Thueringisches Institut F{umlaut Over ())}{Umlaut Over (})}R Textil-Und Kunstsoff-Forschung E.v.

Eberhard Taeger

Klaus Heinemann

Wolfgang Mueller

Erich Meusel

The invention relates to a method for producing novel reactive organic compounds containing poly-DOPO and having a higher phosphorus content than known comparable DOPO (9,10-dihydro-9-oxa-10-phospha-phenenthrene-10-oxide) adducts, and to the use thereof for flameproofing thermoplastic polymers, such as polyesters and polyamides. The same flameproofing effect is achieved with smaller additive quantities than previously, thus reducing the influence of the physical, especially textile-physical properties of the polymers. The adducts containing poly-DOPO are formed by reacting DOPO with acetylenes carrying reactive groups, in the presence of a catalyst.

Method for producing organic compounds containing poly-DOPO, and the use of the same

This invention relates to a method for producing and processing polyester block copolymers, in particular, polyester side-chain grafted, rigid side-chain and/or semi-rigid side-chain polymers. According to the invention, the monomeric units of rigid side-chain and/or semi-rigid side-chain polymers are, preferably in the melt, polycondensated together with monofunctionalized and/or difunctionalized, cyclic dicarboxylic acid anhydrides to form polymers having anhydride terminal and/or side groups. The formed polyester anhydrides are reacted with the hydroxyl groups and/or with the ester groups of meltable linear polyesters in order to form side-chain grafted, rigid side-chain and/or semi-rigid side-chained polymers and, together with meltable polyesters, they form molecularly reinforced blends. These blends can be shaped into filaments or fibers having a high orientation of the reinforcing polymer or they serve as compatibility mediators in blends consisting of a polyester matrix and of rigid side-chain and/or semi-rigid side-chain polymers. The filaments are used, in particular, in technical fields or in the carpet industry.

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Munich, Georgia

Eberhard Taeger