California Nickel Corporation

E Harris Lowenhaupt

John E Litz

Dennis L Howe

Dennis L Hoe

According to the present invention, processes are provided for recovery of nickel, cobalt and like metal values from laterite ores wherein the ores are separated into high and low magnesium containing fractions, the low magnesium fraction is leached with sulfuric acid at elevated temperatures and pressure to solubilize the metal values. The pregnant liquor resulting from the high pressure which also contains solubilized Fe, Al and acid is then contacted with a low magnesium fraction of the ore in a low pressure leach under conditions such that at least some of the acid is neutralized and substantially all of the solubilized Fe and Al is removed as hematite and alunite precipitate. In one embodiment, the pregnant liquor from the high pressure leach and the high magnesium fraction are contacted at atmospheric pressure and a temperature of about 80.degree. C. prior to low pressure leaching. In other embodiments, various process streams are separated by size and otherwise, and recycled to within the processes. In another embodiment, all leached values, including magnesium and sulfuric acid, are recovered, resulting in a dischargeless process which is environmentally and economically acceptable. Elimination of prior art iron and aluminum contaminants by the low pressure leach provides a simplified method of recovery of all elements in the leachate.

Method of recovering nickel from laterite ores

According to the present invention, Ni- and Co-rich, low Mg fines may be advantageously separated from the coarse fractions of lateritic ores by atmospheric or low pressure leaching. In particular, the process of the present invention comprises contacting a lateritic ore or ore fraction at temperatures from about 20.degree. C. to about 200.degree. C. and pressures from about atmospheric to about 200 psig with an aqueous acid solution to form a leach liquor, a leach residue and a fines fraction. The fines fraction which can be separated from the residue with the leach liquor by conventional means such as cycloning is found to be richer in Ni and Co and lower than the remainder of the residue.

Method of liberating nickel- and cobalt-enriched fines from laterite

According to the present invention, improved dissolution of nickel and cobalt and thus improved recovery of those desired metal values is achieved by modifying the ore recovery processes wherein sulfuric acid leaching at elevated temperatures is used to dissolve the nickel and cobalt. In particular, according to the present invention, processes are provided wherein the sulfuric acid and ore are contacted at substantially ambient temperature prior to subsequent heating to attain the elevated temperatures of the sulfuric acid leach. Practice of the present invention has been found to result in improved metal value recovery.

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Gasquet, CA, United States of America

E Harris Lowenhaupt