Dow Global Technolgoies LLC

Dow Quimica De Colombia S.a.

Douglas S Ginger

Mehmet Demirors

Philip P Fontaine

David T Gillespie

Mustafa Bilgen

Jian Jim Wang

Nicolas Cardoso Mazzola

Didem Oner-Deliormanli

Sanjib Biswas

Teresa Plumley Karjala

Linfeng Chen

Mridula Babli Kapur

Pradeep Jain

Lori L Kardos

Sylvie Y Desjardins

Ayush A Bafna

Gagan Saini

Rahul Sharma

Michael D Turner

Jose Eduardo Ruiz

John A Naumovitz

Joshua B Gaubert

Vivek Kalihari

Hien Q Do

Peter Hermann Roland Sandkuehler

Marc A Springs

Anthony J Castelluccio

David Lopez

Colleen M Tice

Justice Alaboson

Jorge Mario Rodriguez Camelo

Francis O Olajide, Jr

Terry A Pearce

Amaia Bastero

Jian Wang

Jain Pradeep

Marlos Guintini De Oliveira

Albert Carbonell

Julie W Mckenna

Mridula Kupar

Jr Francis O Olajide

Terry Pearce

Dibyaranjan Mekap

Colleen Tice

Sylvie Desjardins

David López

Jacquelyn A DeGroot

Embodiments of the present disclosure are directed to multilayer films. Embodiments of the multilayer films may include a first layer comprising a polyethylene composition having a density of 0.924 g/cmto 0.936 g/cmand a melt index (I) of 0.25 g/10 minutes to 2.0 g/10 minutes, a second layer comprising a first polyolefin, a third layer comprising a second polyolefin. The first layer may be positioned between the second layer and the third layer. The first polyolefin and the second polyolefin may be the same or different.

Multilayer films having at least three layers and methods of producing the same

Embodiments of the present disclosure are directed to multilayer films. Embodiments of the multilayer films may include a first layer comprising a first polyolefin, a second layer comprising a second polyolefin, a third layer comprising a third polyolefin, fourth layer comprising a fourth polyolefin, and a fifth layer comprising a fifth polyolefin. The second layer may be positioned between the first layer and the third layer; the third layer may be positioned between the second layer and the fourth layer; and the fourth layer may be positioned between the third layer and the fifth layer. Two or more of the first polyolefin, second polyolefin, third polyolefin, and fourth polyolefin may be the same or different. The third polyolefin may be a polyethylene composition having a density of 0.924 g/cmto 0.936 g/cmand a melt index (I) of 0.25 g/10 minutes to 2.0 g/10 minutes.

Multilayer films that include at least five layers and methods of producing the same

An ethylene/alpha-olefin copolymer composition having a density from 0.935 to 0.955 g/cc; a ratio of weight average molecular weight to number average molecular weight, Mw/Mn, of from 3 to 10; a z-average molecular weight, Mz, from 200 kg/mol to 500 kg/mol; and a PENT value of greater than 500 hours at 80&#xb0; C. and 2.4 MPa; wherein when the composition is formed into a monolayer pipe the pipe has a pipe hydrostatic strength of greater than 100 hours at 20&#xb0; C. and 12.0 MPa. Also provided is a pipe or pipe fitting comprising the ethylene/alpha-olefin copolymer composition.

Ethylene/alpha-olefin copolymer composition, and articles comprising the same

The invention provides a composition comprising a first composition, comprising at least one ethylene-based polymer, and wherein the first composition comprises a MWCDI value greater than 0.9, and a melt index ratio I10/I2 that meets the following equation: I10/I2&#x2265;7.0&#x2212;1.2&#xd7;log (I2). The invention also provides a process to form a composition comprising at least two ethylene-based polymers, said process comprising the following: polymerizing ethylene, and optionally at least one comonomer, in solution, in the presence of a catalyst system comprising a metal-ligand complex of Structure I, as described herein, to form a first ethylene-based polymer; and polymerizing ethylene, and optionally at least one comonomer, in the presence of a catalyst system comprising a Ziegler/Natta catalyst, to form a second ethylene-based polymer.

Ethylene-based polymer composition for films with improved toughness

The instant invention provides a polyolefin composition suitable for sealant applications, sealant compositions, method of producing the same, and films and multilayer structures made therefrom. The polyolefin composition suitable for sealant applications according to the present invention comprises: an ethylene/&#x3b1;-olefin interpolymer composition having a Comonomer Distribution Constant (CDC) in the range of from 40 to 110, vinyl unsaturation of less than 0.1 vinyls per one thousand carbon atoms present in the backbone of the ethylene-based polymer composition; a zero shear viscosity ratio (ZSVR) in the range of from 1.01 to 2.0; a density in the range of from 0.908 to 0.922 g/cm, a melt index (Iat 190&#xb0; C./2.16 kg) in the range of from 0.5 to 5.0 g/10 minutes, a molecular weight distribution (defined as the weight average molecular weight divided by the number average molecular weight, M/M) in the range of from 2.0 to 4.0, and tan delta at 0.1 radian/second, determined at 190&#xb0; C., in the range of from 5 to 50.

Sealant composition

The instant invention provides an ethylene/alpha-olefin interpolymer composition suitable for blown film applications, and blown films made therefrom. The ethylene/alpha-olefin interpolymer composition suitable for blown film applications according to the present invention comprises greater than 80 percent by weight of units derived from ethylene and 20 percent or less by weight of units derived from one or more alpha olefin co-monomers, wherein said ethylene/alpha-olefin interpolymer has a density in the range of from 0.910 to 0.918 g/cm, a melt index Iin the range of from 0.5 to 1.1 g/10 minutes, a melt flow ratio I/Iin the range of from 8 to 10, a melt strength in the range of from 3 to 6 cN, a highest temperature fraction in the range of from 11 to 14 percent determined by CEF, a highest peak temperature fraction by CEF in range of from 96 to 100&#xb0; C., and a lowest temperature fraction from CEF in the range of from 2 to 5 percent, and a DSC heat curve having three melting peaks with a highest temperature melting peak in the range of from 120 to 124&#xb0; C., a crystallinity in the range of from 40 to 50 percent.

Ethylene/alpha-olefin interpolymer composition

The instant invention provides a polyolefin composition suitable for packaging applications, films, multilayer structures and packaging devices made therefrom. The polyolefin composition according to the present invention comprises: an ethylene/&#x3b1;-olefin interpolymer composition comprising (a) from 50 to 75 percent by weight of a first ethylene/&#x3b1;-olefin copolymer fraction having a density in the range of 0.894 to 0.908 g/cm, a melt index (I) in the range of from 0.2 to 1 g/10 minutes, and (b) from 25 to 50 percent by weight of a second ethylene/&#x3b1;-olefin copolymer fraction, and wherein said ethylene/&#x3b1;-olefin interpolymer composition has a density in the range of 0.910 to 0.924 g/cm, a melt index (I) in the range of from 0.5 to 2 g/10 minutes, a zero shear viscosity ratio (ZSVR) in the range of from 1.15 to 2.5, a molecular weight distribution, expressed as the ratio of the weight average molecular weight to number average molecular weight (M/M) in the range of from 2.0 to 4.0, and tan delta at 0.1 radian/second and 190&#xb0; C. in the range of from 6 to 43.

Polyolefin composition

The instant invention provides a polyolefin composition suitable for injection molding applications, and method of making such injection molded articles. The polyolefin composition suitable for injection molding applications comprises: an ethylene/&#x3b1;-olefin interpolymer composition comprising: (a) from 25 to 50 percent by weight of a first ethylene/&#x3b1;-olefin copolymer fraction having a density in the range of from 0.924 to 0.937 g/cm, a melt index (I) in the range of from 0.03 to 0.3 g/10 min, (b) from 50 to 75 percent by weight of a second ethylene homopolymer fraction having a density in the range of from greater than 0.960 g/cm, a melt index (I) in the range of from 100 to 180 g/10 minutes, wherein said ethylene/&#x3b1;-olefin interpolymer composition has a density in the range of from 0.950 to 0.958 g/cm, a melt index (I) in the range of from 1.0 g/10 min to 3.5 g/10 min, a zero shear viscosity ratio (ZSVR) in the range of from 1.01 to 2.5, a molecular weight distribution (M/M) in the range of from 2.0 to 4.0, and tan delta at 0.1 radian/second and 190&#xb0; C. in the range of from 9 to 50.

An interpolymer of ethylene and at least one alpha-olefin is claimed, wherein the ethylene interpolymer is characterized as having an average Mand a valley temperature between the interpolymer and high crystalline fraction, T, such that the average Mfor a fraction above Tfrom ATREF divided by average Mof the whole polymer from ATREF (M/M) is less then about 1.95 and wherein the interpolymer has a CDBI of less than 60%. The interpolymer of ethylene and at least one alpha-olefin can also be characterized as having a high density (HD) fraction and an overall density such that % HD fraction&#x3c;&#x2212;2733.3+2988.7x+144111.5 (x&#x2212;0.92325)where x is the density in grams/cubic centimeter. Fabricated articles comprising the novel interpolymers are also disclosed.

Heterogeneous ethylene alpha-olefin interpolymers

Growing community of inventors

Houston, TX, United States of America

Douglas S Ginger