Arizona State University

Skysong Innovations

Dong-Kyun Seo

Shaojiang Chen

Dinesh Medpelli

Danielle Ladd

Alex Volosin

Lukas Sorge

Farid Akhtar

Milad Mesgar

Candace K Chan

Elham Fini

Kamil Elias Kaloush

Daniel Mieritz

Ran Zhao

Ki-Wan Jeon

Jungmin Seo

Alireza Samieadel

An electrolytic cell includes a liquid metal cathode, an anode, and a molten salt electrolyte in contact with the liquid metal cathode and the anode. The molten salt electrolyte includes carbonate ions, and the electrolytic cell is configured to reduce the carbonate ions at the surface of the cathode or in the vicinity of the cathode to yield a carbon material and oxide ions. Producing a carbon material in the electrolytic cell includes providing carbonate ions to the electrolytic cell, reducing the carbonate ions at the liquid metal cathode to yield the carbon material, and removing the carbon material from the electrolytic cell.

Liquid metal cathodes for electrolysis of metal carbonates in molten salts

A modified bitumen includes bitumen and a bitumen modifier. The bitumen modifier includes composite particles. The composite particles include aluminosilicate nanostructures defining nanopores and micropores and paraffin wax adhered to surfaces of the aluminosilicate nanostructures. Modifying bitumen includes combining bitumen and the bitumen modifier.

Nanostructured aluminosilicate wax carrier for asphalt

A carbon dioxide adsorbent including a hierarchical zeolite. The hierarchical zeolite defines micropores having a pore width between about 0.4 nm and about 2 nm, and at least one of: mesopores having a pore width between about 2 nm and about 50 nm; and macropores having a pore width greater than about 50 nm.

Carbon dioxide adsorbents

Nanostructured aluminosilicates including aluminosilicate nanorods are formed by heating a geopolymer resin containing up to about 90 mol % water in a closed container at a temperature between about 70&#xb0; C. and about 200&#xb0; C. for a length of time up to about one week to yield a first material including the aluminosilicate nanorods. The aluminosilicate nanorods have an average width of the between about 5 nm and about 30 or between about 5 nm and about 60 nm or between about 5 nm and about 100 nm, and a majority of the aluminosilicate nanorods have an aspect ratio between about 2 and about 100.

Aluminosilicate nanorods

Nanostructured aluminosilicates including aluminosilicate nanorods are formed by heating a geopolymer resin containing up to about 90 mol % water in a closed container at a temperature between about 70&#xb0; C. and about 200&#xb0; C. for a length of time up to about one week to yield a first material including the aluminosilicate nanorods. The aluminosilicate nanorods have an average width of between about 5 nm and about 30 or between about 5 nm and about 60 nm or between about 5 nm and about 100 nm, and a majority of the aluminosilicate nanorods have an aspect ratio between about 2 and about 100.

Forming a metal oxide by treating an acidic solution containing a metal to yield a precursor in the form of a semi-liquid, semi-solid or solid, and treating the precursor to yield a product including the metal oxide. An organic or inorganic component may be combined with the precursor to yield a second semi-liquid, semi-solid or solid. The product may be treated to yield a new material. In some cases, the metal oxide has an empirical formula HMA-A, where M represents a transition metal or any combination of transition metals in Groups 3-12; Ais a first oxyanion; Ais a second oxyanion; 0&#x2264;x&#x2264;3; 0&#x2264;y&#x2264;3; 0&#x2264;z&#x2264;3; and y+z&#x3e;0.

Metal oxides from acidic solutions

A product formed from a first material including a geopolymer resin material, a geopolymer material, or a combination thereof by contacting the first material with a fluid and removing at least some of the fluid to yield a product. The first material may be formed by heating and/or aging an initial geopolymer resin material to yield the first material before contacting the first material with the fluid. In some cases, contacting the first material with the fluid breaks up or disintegrates the first material (e.g., in response to contact with the fluid and in the absence of external mechanical stress), thereby forming particles having an external dimension in a range between 1 nm and 2 cm.

Geopolymer resin materials, geopolymer materials, and materials produced thereby

Forming multifunctional materials and composites thereof includes contacting a first material having a plurality of oxygen-containing functional groups with a chalcogenide compound, and initiating a chemical reaction between the first material and the chalcogenide compound, thereby replacing oxygen in some of the oxygen-containing functional groups with chalcogen from the chalcogen-containing compound to yield a second material having chalcogen-containing functional groups and oxygen-containing functional groups. The first material is a carbonaceous material or a macromolecular material. A product including the second material is collected and may be processed further to yield a modified product or a composite.

Multifunctional materials and composites

Porous materials are fabricated using interpenetrating inorganic-organic composite gels. A mixture or precursor solution including an inorganic gel precursor, an organic polymer gel precursor, and a solvent is treated to form an inorganic wet gel including the organic polymer gel precursor and the solvent. The inorganic wet gel is then treated to form a composite wet gel including an organic polymer network in the body of the inorganic wet gel, producing an interpenetrating inorganic-organic composite gel. The composite wet gel is dried to form a composite material including the organic polymer network and an inorganic network component. The composite material can be treated further to form a porous composite material, a porous polymer or polymer composite, a porous metal oxide, and other porous materials.

Fabricating porous materials using intrepenetrating inorganic-organic composite gels

Methods, apparatuses, and systems for fabricating porous materials using thixotropic gels. A shear force is applied to a thixotropic material causing the material to flow. Multiple components are added to the thixotropic material while applying the shear force causing the multiple components to be distributed in the material. The shear force is removed such that the static properties of the thixotropic material in the absence of the shear force retain a distribution of the multiple components in the thixotropic material to form a composite gel material that includes liquid within a network of inter-connected solid particles that include the distributed plurality of components. The liquid in the composite gel material is removed to form a porous composite material.

Fabricating porous materials using thixotropic gels

A product formed from a first material including a geopolymer resin material, a geopolymer resin, or a combination thereof by contacting the first material with a fluid and removing at least some of the fluid to yield a product. The first material may be formed by heating and/or aging an initial geopolymer resin material to yield the first material before contacting the first material with the fluid. In some cases, contacting the first material with the fluid breaks up or disintegrates the first material (e.g., in response to contact with the fluid and in the absence of external mechanical stress), thereby forming particles having an external dimension in a range between 1 nm and 2 cm.

Preparing porous materials includes forming a mixture including a geopolymer resin and a liquid between which a nanoscale (1-1000 nm), microscale (1-1000 m), and/or milliscale (1-10 mm) phase separation occurs. The mixture is solidified (e.g., at an ambient temperature or a relatively low temperature), and a portion (e.g., a majority or a significant majority) of the liquid is removed from the solidified mixture. The liquid can include organic liquids from agricultural, geological, industrial, or household sources. The porous materials have accessible pores with a range of pore sizes including nanoscale pore sizes, microscale pore sizes, milliscale pore sizes, or a combination thereof. The porous material may be treated further to form another material, such as a composite.

Porous geopolymer materials

Preparing porous particles includes forming a gel including a first liquid and an oxygen-containing compound of a metal, semi-metal, metalloid, or semi-conductor, including an oxide, hydroxide, alkoxide, oxohydroxide, oxoalkoxide, oxo salt, or oxo salt hydrate of the metal, semi-metal, metalloid, or semi-conductor; contacting the gel with a combustible liquid to form a combustible gel; and initiating combustion of the combustible gel to form a substance including porous metal, semi-metal, metalloid, or semi-conductor oxide particles. The combustible liquid can include a volatile solvent. The porous particles have open pores with a range of nanoscale pore sizes. The porous particles may be treated further to form, for example, a composite.

Growing community of inventors

Chandler, AZ, United States of America

Dong-Kyun Seo