Petrochina Company Limited

Boe Technology Group Co., Ltd.

Ordos Yuansheng Optoelectronics Co., Ltd.

Dong Ji

Haitao Zhang

Di Li

Xionghou Gao

Hongchang Duan

Chenxi Zhang

Zhengguo Tan

Yi Wang

Yanqing Ma

Yanbo Sun

ZhengGuo Tan

Yi Su

Nan Zhang

Jie Liu

Da Li Liu

Feng Luo

Guoliang Liu

Zhicheng Tang

Xiaodong Fang

Jialin Huang

Guoqiang Zhao

Provided are a flowrate measurement device and a flowrate measurement method. The flowrate measurement device includes an attachment portion configured to attach the flowrate measurement device to an object to be measured, and a measurement portion. The measurement portion includes a first ultrasonic transmitter, a second ultrasonic transmitter and a plurality of signal receivers between the first ultrasonic transmitter and the second ultrasonic transmitter. The plurality of signal receivers are spaced apart from each other. The first ultrasonic transmitter, the second ultrasonic transmitter and the plurality of the signal receivers are all disposed on the attachment portion, such that both the first ultrasonic transmitter and the second ultrasonic transmitter are capable of emitting an ultrasonic wave signal to the object to be measured. The signal receivers are capable of receiving an ultrasonic wave signal reflected from the object to be measured.

Ultrasonic flowrate measurement device having an attachment portion with receivers for determining size of a pipe

A method for producing double-component modified molecular sieve comprises adding molecular sieve to an aqueous solution containing phosphorus to form a mixture, allowing the mixture to react at pH of 1-10, temperature of 70-200&#xb0; C. and pressure of 0.2-1.2 MPa for 10-200 min, and then filtering, drying and baking the resultant to obtain phosphorus-modified molecular sieve, and then adding the phosphorus-modified molecular sieve to an aqueous solution containing silver ions, allowing the phosphorus-modified molecular sieve to react with silver ions at 0-100&#xb0; C. in dark condition for 30-150 min, and then filtering, drying and baking. The obtained double-component modified molecular sieve contains 88-99 wt % molecular sieve with a ratio of silica to alumina between 15 and 60, 0.5-10 wt % phosphorus (based on oxides) and 0.01-2 wt % silver (based on oxides), all based on dry matter. A catalyst produced from the double-component modified molecular sieve has improved hydrothermal stability and microactivity.

Double-component modified molecular sieve with improved hydrothermal stability and production method thereof

The present invention relates to a heavy oil catalytic cracking catalyst and preparation method thereof. The catalyst comprises 2 to 50% by weight of an ultra-stable rare earth type Y molecular sieve, 0.5 to 30% by weight of one or more other molecular sieves, 0.5 to 70% by weight of clay, 1.0 to 65% by weight of high-temperature-resistant inorganic oxides, and 0.01 to 12.5% by weight of rare earth oxide. The ultra-stable rare earth type Y molecular sieve is obtained as follows: the raw material, NaY molecular sieve, is subjected to a rare earth exchange and a dispersing pre-exchange, and the molecular sieve slurry is filtered, washed and subjected to a first calcination to produce a 'one-exchange one-calcination' rare earth sodium Y molecular sieve, wherein the order of the rare earth exchange and the dispersing pre-exchange is not limited; and the 'one-exchange one-calcination' rare earth sodium Y molecular sieve is further subjected to ammonium salt exchange for sodium reduction and a second calcination. The catalyst provided in the present invention is characteristic in its high heavy-oil-conversion capacity, a high total liquid yield and a high light oil yield.

Heavy oil catalytic cracking catalyst and preparation method therefor

The present invention provides an ultra-stable rare earth type Y molecular sieve and the preparation method thereof, which method is carried out by subjecting a NaY molecular sieve as the raw material to a rare earth exchange and a dispersing pre-exchange, then to an ultra-stabilization calcination treatment. The molecular sieve comprises 1 to 20% by weight of rare earth oxide, not more than 1.2% by weight of sodium oxide, has a crystallinity of 51 to 69%, and a lattice parameter of 2.451 nm to 2.469 nm. In contrast to the prior art, in the molecular sieve prepared by this method, rare earth ions are located in sodalite cages, which is demonstrated by the fact that no rare earth ion is lost during the reverse exchange process. Moreover, the molecular sieve prepared by such a method has a molecular particle size D(v,0.5) of not more than 3.0 &#x3bc;m and a D(v,0.9) of not more than 20 &#x3bc;m. Cracking catalysts using the molecular sieve as an active component is characterized by a high heavy-oil-conversion capacity and a high yield of valuable target products.

Ultra-stable rare earth Y-type molecular sieve and preparation method therefor

Modified molecular sieve characterized by improved sodium-resisting contamination activity and preparation method thereof are provided. The method comprises: adding molecular sieve in phosphorus-containing organic solution, and reacting for 10-200 minutes at temperature of 70-200&#xb0; C. and pressure of 0.2-1.2 MPa, and then filtering, drying and calcining. The said modified molecular sieve contains 90-99 wt. % molecular sieve as dry basis and 1-10 wt. % phosphorus as oxide. The said method can improve the capability of sodium-resisting contamination effectively, and its technology is simple and fits the existing catalyst production apparatus and process. The said modified molecular sieve has high sodium-resisting contamination activity, and the model catalyst by sodium contamination has high activity retention.

Modified molecular sieve characterized by improved sodium-contamination-resisting activity and preparation method thereof

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Beijing, China

Dong Ji