Lg Energy Solution, Ltd.

Lg Chem, Ltd

Dong Hwi Kim

Wang Mo Jung

Dong Hun Lee

Sung Bin Park

Ji Hye Kim

Jung Min Han

Hyung Man Cho

Dae Jin Lee

Gi Beom Han

Hyeong Il Kim

Seul Ki Chae

Sang Wook Lee

Ji Hoon Ryu

Jin Tae Hwang

Tae Hee Kim

YoJin Kim

Nanji Yun

Hyunkyung Do

Tae Gu Yoo

Hyuck Hur

So Ra Baek

Young Uk Park

Eun Sol Lho

Hak Yoon Kim

A positive electrode and a lithium secondary including the same is disclosed herein. In some embodiments, the positive electrode includes a positive electrode current collector, a first positive electrode active material layer and a second positive electrode active material layer sequentially stacked on the positive electrode current collector, wherein the first positive electrode active material layer and the second positive electrode active material layer include a bimodal positive active material, the first positive electrode active material layer includes small-diameter particles in the form of single particles, and the second positive electrode active material layer includes small-diameter particles in the form of secondary particles. The positive electrode has improved capacity, efficiency, lifespan, output properties, and thermal stability.

Positive electrode and lithium secondary battery including the same

The present invention relates to an electrode of a double-layer structure including a different type of particulate active material having a different average particle diameter, and a secondary battery including the same, and according to the present invention, the mechanical strength and stability of the electrode increases, and the secondary battery to which they are applied exhibits excellent discharge capacity.

Secondary battery electrode including mixture layer of double layer structure containing active materials of different particle diameters, and method for manufacturing the same

A positive electrode material for a lithium secondary battery includes a first positive electrode active material and a second positive electrode active material, both of which are lithium composite transition metal oxides containing transition metals. The first positive electrode active material has a larger average particle size (D) than the second positive electrode active material, wherein a ratio (Li/Me)of the mole number of lithium with respect to the total mole number of transition metals of the first positive electrode active material is more than 1 to 1.5 or less, and a ratio (Li/Me)of the mole number of lithium (Li) with respect to the total mole number of transition metals of the second positive electrode active material is 0.9 to 1. The second positive electrode active material has a crystallite size of 180 nm or more.

Positive electrode material for lithium secondary battery, and positive electrode for lithium secondary battery and lithium secondary battery including the same

A method of preparing a positive electrode active material for a secondary battery includes preparing a lithium composite transition metal oxide which includes nickel, cobalt, and manganese and contains 60 mol % or more of the nickel among all metals except lithium, adding a moisture absorbent and the lithium composite transition metal oxide into an atomic layer deposition (ALD) reactor, and adding a coating metal precursor into the atomic layer deposition (ALD) reactor and forming a metal oxide coating layer on surfaces of particles of the lithium composite transition metal oxide by atomic layer deposition (ALD).

Method of preparing positive electrode active material for secondary battery

The present disclosure relates to an anode for a lithium secondary battery and a lithium secondary battery including the same, wherein the anode includes a first anode active material layer formed on at least one surface of the anode current collector, wherein the first anode active material layer contains a mixture of natural graphite and artificial graphite as the anode active material and a first binder; a second anode active material layer formed on the first anode active material layer, wherein the second anode active material layer contains a mixture of artificial graphite and a silicon-based compound as the anode active material and a second binder; and wherein a weight ratio of the first binder and the second binder is 1 to 2:1.

Multi-layered anode containing silicon-based compound and lithium secondary battery including the same

The present disclosure relates to an anode for a lithium secondary battery and a lithium secondary battery including the same, wherein the anode includes an anode current collector; a first anode active material layer formed on at least one surface of the anode current collector and containing a mixture of natural graphite and artificial graphite in a weight ratio of 13&#x2dc;34:66&#x2dc;87 and a first binder as the anode active material; and a second anode active material layer formed on the first anode active material layer and containing a mixture of artificial graphite and a silicon-based compound in a weight ratio of 91&#x2dc;99:1&#x2dc;9 and a second binder as the anode active material.

A positive electrode material including a first positive electrode active material represented by Formula 1 and a second positive electrode active material represented by Formula 2, a positive electrode including the same, and a lithium secondary battery including the positive electrode are provided. The positive electrode material has a bimodal particle size distribution including large diameter particles and small diameter particles, and the difference in average particle diameter (D) between the large diameter particles and the small diameter particles is 3 &#x3bc;m or greater.

Positive electrode material for lithium secondary battery, positive electrode including same, and lithium secondary battery

A positive electrode active material precursor is provided, which includes a transition metal hydroxide particle represented by Formula 1 and a cobalt oxide particle and a manganese oxide particle attached to the surface of the transition metal hydroxide particle. A preparation method thereof, a positive electrode active material prepared using the same, a positive electrode including the positive electrode active material, and a secondary battery including the positive electrode are also provided.

Positive electrode active material precursor, preparation method thereof, positive electrode active material prepared using same, positive electrode, and secondary battery

A positive electrode material for a secondary battery, including a first positive electrode active material and a second positive electrode active material, wherein the first positive electrode active material and the second positive electrode active material consist of a lithium composite transition metal oxide including at least two or more transition metals selected from the group consisting of nickel (Ni), cobalt (Co) and manganese (Mn) are provided. The average particle size (D) of the first positive electrode active material is two or more times larger than that of the second positive electrode active material, and the first positive electrode active material has a concentration gradient in which at least one of Ni, Co or Mn contained in the lithium composite transition metal oxide has a concentration difference of 1.5 mol % or more between the center and the surface of a particle of the lithium composite transition metal oxide.

Positive electrode material for secondary battery and lithium secondary battery including the same

A positive electrode active material for a secondary battery includes a first positive electrode active material and a second positive electrode active material, wherein an average particle diameter (D) of the first positive electrode active material is twice or more than an average particle diameter (D) of the second positive electrode active material, and the second positive electrode active material has a crystallite size of 200 nm or more.

Positive electrode active material for secondary battery, method of preparing the same, and lithium secondary battery including the positive electrode active material

A method of preparing a positive electrode active material for a secondary battery includes preparing a positive electrode active material precursor including nickel (Ni), cobalt (Co), and at least one selected from the group consisting of manganese (Mn) and aluminum (Al); and forming a lithium composite transition metal oxide by mixing the positive electrode active material precursor and a lithium source and performing calcination, wherein the positive electrode active material precursor includes nickel (Ni) in an amount of 60 mol % or more out of the entire metal element, and a molar ratio (Li/M) of lithium (Li) of the lithium source to the entire metal element (M) of the positive electrode active material precursor is greater than 1.1.

The present invention relates to a method for recovering a positive electrode active material from a lithium secondary battery including: 1) separating a positive electrode into a collector and a positive electrode part; 2) removing an organic substance by firing the separated positive electrode part; 3) washing the fired resultant and removing remaining fluorine (F); 4) adding a lithium-containing material into the washed resultant and firing to recover a lithium transition metal oxide.

Method for recovering positive electrode active material from lithium secondary battery

The present invention relates to a positive electrode active material for a secondary battery, which comprises a core including a lithium composite metal oxide, and a surface treatment layer located on a surface of the core and including an amorphous oxide, wherein the amorphous oxide including silicon (Si), nitrogen (N) and at least one metal element selected from the group consisting of a Group 1A element, a Group 2A element, and a Group 3B element, and a method for preparing the same.

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Daejeon, South Korea

Dong Hwi Kim