Uop Lcc

Universal Oil Products Company

Donald J Korous

Richard W Neuzil

Joseph A Kocal

An improved process for the production of alkylated aromatic compounds by paraffin dehydrogenation and aromatic alkylation is disclosed. Aromatic by-products normally formed in paraffin dehydrogenation are selectively removed using at least one aromatics removal zone. Removal of these aromatic by-products significantly reduces the deactivation rate of solid alkylation catalysts. The improved process produces a detergent alkylate product that is significantly more linear than that produced by the prior art process.

Alkylaromatic process with removal of aromatic by-products

A process for the separation of the para-isomer from a hydrocarbon feed mixture comprising at least two bi-alkyl substituted monocyclic aromatic isomers, including the para-isomer, said isomers having from 8 to about 18 carbon atoms per molecule, which process employs an adsorbent comprising a X or a Y zeolite containing selected cations at exchangeable cationic sites to preferentially adsorb the para-isomer. The para-isomer thereafter is removed from the adsorbent by contacting it with a desorbent material and is recovered as a product stream. In a preferred embodiment the process uses a simulated-moving-bed counter-current flow system.

Separation of bi-alkyl substituted monocyclic aromatic isomers

A process for the separation of a para-isomer from a hydrocarbon feed stock containing alkyl-aromatic hydrocarbons having more than eight carbon atoms per molecule which employs a crystalline aluminosilicate adsorbent containing a particular cation or cations to selectively adsorb either a para-, meta-, or ortho- isomer from the feed stock. A feed stock contacts an adsorbent which allows one or more isomers from the feed stock to be selectively adsorbed by the adsorbent. The selectively adsorbed component is thereafter recovered from the adsorbent in a more pure form as compared to the other isomers in the feed stock. The process can be performed in both the liquid or vapor phase.

Hydrocarbon separation

A process for the separation of the para-isomer from a hydrocarbon feed mixture comprising at least two bi-alkyl substituted monocyclic aromatic isomers, including the para-isomer, said isomers having from 8 to about 18 carbon atoms per molecule which process employs an adsorbent comprising a type Y zeolite essentially completely exchanged with a single cation selected from the group consisting of potassium, cesium, and rubidium. The feed mixture is passed through a bed of the adsorbent wherein the para-isomer is preferentially adsorbed within the adsorbent and thereafter recovered from the adsorbent.

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Bensenville, IL, United States of America

Donald J Korous