Exxonmobil Chemical Patents Inc.

Dirk Frans Rouckhout

Walter Harvey Waddell

Donald Sheley Tracey

Donald S Tracey

Mun Fu Tse

Maria Dolores Ellul

Jianya Cheng

Porter Clarke Shannon

David Yen-Lung Chung

James Peter Stokes

Robert Norman Webb

Peter William Manders

Basil D Favis

Dennis Kumor

Robert Christopher Napier

Arthur Joseph Sullivan

Prashant Arun Bhadane

Jianya J Cheng

Arthur J Sullivan

Prashant A Bhadane

A dynamically vulcanized alloy containing an elastomer and a thermoplastic resin is prepared by a process wherein supercritical fluid is injected into the thermoplastic elastomeric material as the material is mixed in an extruder. The material is mixed under conditions such that the thermoplastic elastomeric material is dynamically vulcanized wherein the elastomer forms a discontinuous dispersed of small particles in a continuous phase of the thermoplastic resin. The DVA material may then be directly formed into film or sheets by the use of at least one set of rolls located adjacent to the extruder outlet.

Dynamically vulcanized thermoplastic elastomer film

The invention provides for processes to produce elastomeric compositions, the processes including contacting at least one elastomer with a processing aid, wherein the processing aid comprises at least one functionalized polymer having at least one anhydride group. The invention also provides for articles such as innerliners for tires produced from the aforementioned elastomeric compositions.

Processing aids for elastomeric compositions

The present invention provides an elastomeric composition processable in a curable, filled rubber formulation. The composition comprises a halogenated interpolymer of a Cto Cisoolefin and from 3 to 20 weight percent alkylstyrene and comprising from 0.2 to 2 mole percent haloalkylstyrene, a Mooney viscosity less than 37, a number average molecular weight less than 270,000, a weight average molecular weight less than 470,000, a z-average molecular weight less than 700,000, and a branching index (g') from 0.4 to 1.1. Also disclosed are a method of making a cured, filled rubber article, comprising compounding the elastomeric composition with filler and curative, processing the compounded composition to form a shape of the article, and curing the composition to obtain the article in the formed shape, as well as a tire comprising an innerliner made by the method.

Processable filled, curable halogenated isoolefin elastomers

The present invention provides an elastomeric composition processable in a curable, filled rubber formulation. The composition comprises a halogenated interpolymer of a Cto Cisoolefin and from 3 to 20 weight percent alkylstyrene and comprising from 0.2 to 2 mole percent haloalkylstyrene, a Mooney viscosity less than 27, a number average molecular weight less than 270,000, a weight average molecular weight less than 470,000, a z-average molecular weight less than 700,000, and a branching index (g') from 0.4 to 1.1. Also disclosed are a method of making a cured, filled rubber article, comprising compounding the elastomeric composition with filler and curative, processing the compounded composition to form a shape of the article, and curing the composition to obtain the article in the formed shape, as well as a tire comprising an innerliner made by the method.

According to the invention, a processing aid is used to improve processing in a green (uncured) rubber composition, such as in downstream in-plant processing of an innerliner compound, and maintaining, or more preferably, reducing the air permeability of the cured composition, e.g., innerliner compound. In embodiments, another of the advantages of the present invention is that the processing aid according to the invention can be used in very low levels relative to the other processing aids and oils.

Air barrier composition for innerliners

According to the invention, a processing aid is used to improve processing in a green (uncured) rubber composition, such as in downstream in-plant processing of an innertube compound, and maintaining, or more preferably, reducing the air permeability of the cured composition, e.g., innertube compound. In embodiments, another of the advantages of the present invention is that the processing aid according to the invention can be used in addition to or as a replacement for the other processing aids and oils.

Air barrier composition for innertubes

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Grotesteenweg, Belgium

Dirk Frans Rouckhout