Agfa-gevaert

Agfa Gevaert Nv

Afga-gevaert

Dirk Bollen

Ingrid E Geuens

Yvan K Gilliams

Andre Bellens

Johan August Loccufier

Ivan Hoogmartens

Bartholomeus Cyriel Horsten

Xavier André

Sabine Emmers

Nicolas Vriamont

Yvan Hoogmartens

Jaroslav Katona

A metallic nanoparticle dispersion includes metallic nanoparticles, a liquid carrier and an optional binder, and a silane compound according to Formula I: 

Metallic nanoparticle dispersion

A metallic nanoparticle dispersion includes metallic nanoparticles, a liquid carrier, and a dispersion-stabilizing compound according to Formulae I, II, III or IV, wherein Q represents the necessary atoms to form a substituted or unsubstituted a five or six membered heteroaromatic ring; M is selected from the group consisting of a proton, a monovalent cationic group and an acyl group; R1 and R2 are independently selected from the group consisting of a hydrogen, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkynyl group, a substituted or unsubstituted alkaryl group, a substituted or unsubstituted aralkyl group, a substituted or unsubstituted aryl or heteroaryl group, a hydroxyl group, a thioether, an ether, an ester, an amide, an amine, a halogen, a ketone and an aldehyde, R1 and R2 may represent the necessary atoms to form a five to seven membered ring; R3 to R5 are independently selected from the group consisting of a hydrogen, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkynyl group, a substituted or unsubstituted alkaryl group, a substituted or unsubstituted aralkyl group, a substituted or unsubstituted aryl or heteroaryl group, a hydroxyl group, a thiol, a thioether, a sulfone, a sulfoxide, an ether, an ester, an amide, an amine, a halogen, a ketone, an aldehyde, a nitrile and a nitro group; and R4 and R5 may represent the necessary atoms to form a five to seven membered ring.

A metallic nanoparticle dispersion includes metallic nanoparticles and less than 50 &#x3bc;mol/g metal of an inorganic acid or a compound capable of generating such an acid during curing of a metallic layer or pattern formed from the dispersion. The presence of such small amounts an inorganic acid increases the conductivity of metallic layers or patterns formed from the metallic nanoparticle dispersions at moderate curing conditions.

A metallic nanoparticle dispersion includes metallic nanoparticles and a compound according to Formula I, wherein X represents the necessary atoms to form a substituted or unsubstituted ring. The presence of small amounts of the compound according to Formula I increases the conductivity of metallic layers or patterns formed from the metallic nanoparticle dispersions at moderate curing conditions.

A metallic nanoparticle dispersion includes a dispersion medium characterized in that the dispersion medium includes a solvent according to Formula I, 

A method to prepare a metallic nanoparticle dispersion includes the steps of forming a metallic precursor dispersion or solution by adding a metallic precursor to a dispersion medium including: wherein

Method to prepare a metallic nanoparticle dispersion

The present invention relates to a dispersion comprising metallic, metal oxide or metal precursor nanoparticles and a polymeric dispersant, the dispersant comprising an anchor group with affinity for the metallic, metal oxide or metal precursor nanoparticles that is chemically bonded to a polymeric backbone characterized in that the dispersant has a 95 wt. % decomposition at a temperature below 300&#xb0; C. as measured by Thermal Gravimetric Analysis. It further relates to metallic fluids or inks prepared from the dispersion and to the preparation of the dispersion and the metallic fluid or inks.

Dispersion comprising metallic, metal oxide or metal precursor nanoparticles

A dispersion includes metallic, metal oxide, or metal precursor nanoparticles; a thermally cleavable polymeric dispersant; an optional dispersion medium; and a thermally cleavable agent. Pastes, coated layers, and patterns may contain the dispersion. A method for producing the specific thermally cleavable dispersant and for producing the metallic nanoparticle dispersions. The dispersions allow the reduction or avoidance of organic residue in coated layers and patterns on substrates, the use substrates of low thermal resistance, and faster processing times.

Dispersion comprising metallic, metal oxide or metal precursor nanoparticles, a polymeric dispersant and a sintering additive

Dispersion comprising metallic, metal oxide or metal precursor nanoparticles, a polymeric dispersant and a thermally cleavable agent

A green-sensitized black-and-white silver halide negative working photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer containing tabular silver halide grains, further comprising in said emulsion layer or in a layer adjacent thereto, a heteroatomic sulfinic acid compound, a disulfide compound or a combination thereof, wherein each of said compounds has a solubilizing group having a pK-value of 10 or less.

Radiographic silver halide photographic material having a good developing speed, an excellent image tone and low residual color after processing

A recording material comprising a support and a thermosensitive element containing one or more of silver behenate, silver palmitate, and silver stearate, an organic reducing agent therefor in thermal working relationship therewith and a binder, wherein the silver behenate, palmitate, or stearate is not associated with mercury and/or lead ions, production processes for particles of substantially light-insensitive organic silver salt primarily comprising silver behenate, silver palmitate, or stearate, with described X-ray characteristics in the substantial absence of organic solvent.

Recording materials with improved shelf-life, image tone and/or stability upon thermal development

Method of preparing silver halide emulsion containing homogeneous and thin tabular crystals

A recording material comprising a support and a thermosensitive element containing silver behenate, an organic reducing agent therefor in thermal working relationship therewith and a binder, wherein the silver behenate is not associated with mercury and/or lead ions and when the recording material is irradiated with a copper K.alpha..sub.1 X-ray source the ratio, normalized to a quantity of silver in the recording material of 1 g per m.sup.2 thereof, of the sum of the peak heights of the X-ray diffraction lines attributable to silver behenate at Bragg angles, 2.THETA., of 6.01.degree., 7.56.degree., 9.12.degree., 10.66.degree., 12.12.degree. and 13.62.degree. to the sum of the peak heights of the X-ray diffraction lines at Bragg angles, 2.THETA., of 25.60.degree., 35.16.degree. and 43.40.degree. of NIST standard 1976, rhombohedral Al.sub.2 O.sub.3, determined with the same X-ray diffractometer in the same state of adjustment, is greater than 0.85; production processes for particles of substantially light-insensitive organic silver salt comprising silver behenate with these X-ray characteristics in the presence and substantial absence of organic solvent.

Thermographic recording material with improved image tone and/or

A recording material comprising a support and a thermosensitive element containing silver stearate, an organic reducing agent therefor in thermal working relationship therewith and a binder, wherein the silver stearate is not associated with mercury and/or lead ions and when the recording material is irradiated with a copper K.alpha..sub.1 X-ray source the ratio of the sum of the peak heights of the X-ray diffraction lines attributable to silver stearate at Bragg angles, 2.THETA., of 2.THETA., of 3.62.degree., 5.45.degree., 7.30.degree., 9.04.degree., 10.97.degree. and 12.71.degree. to the sum of the peak heights of the X-ray diffraction lines at Bragg angles, 2.THETA., of 25.60.degree., 35.16.degree. and 43.40.degree. of NIST standard 1976, rhombohedral Al.sub.2 O.sub.3, determined with the same X-ray diffractometer in the same state of adjustment on a sample of the recording material and a sample of the NIST standard 1976 cut to fit a sample holder of the X-ray diffractometer, divided by the square root of the quantity of silver in the recording material, expressed in g per m.sup.2, is greater than 2.2 m/g.sup.0.5 ; and a process for producing particles of substantially light-insensitive organic silver salt comprising silver stearate with these X-ray characteristics in the substantial absence of organic solvent.

Recording material with improved shelf-line producing prints upon

A recording material comprising a support and a thermosensitive element comprising silver palmitate, an organic reducing agent therefor in thermal working relationship therewith and a binder, wherein the silver palmitate is not associated with mercury and/or lead ions and when the recording material is irradiated with a copper K.alpha..sub.1 X-ray source the ratio of the sum of the peak heights of the X-ray diffraction lines attributable to silver palmitate at Bragg angles, 2.THETA., of 4.01.degree., 6.049.degree., 8.031.degree., 10.06.degree., 12.08.degree. and 14.09.degree. to the sum of the peak heights of the X-ray diffraction lines at Bragg angles, 2.THETA., of 25.60.degree., 35.16.degree. and 43.40.degree. of NIST standard 1976, rhombohedral Al.sub.2 O.sub.3, determined with the same X-ray diffractometer in the same state of adjustment on a sample of the recording material and a sample of the NIST standard 1976 cut to fit a sample holder of the X-ray diffractometer, divided by the square root of the quantity of silver in the recording material, expressed in g per m.sup.2, is greater than 3.09 m/g.sup.0.5 ; and a process for producing particles of substantially light-insensitive organic silver salt comprising silver palmitate with these X-ray characteristics in the substantial absence of organic solvent.

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Mortsel, Belgium

Dirk Bollen