Huels Aktiengesellschaft

Chemische Werke Huls Aktiengesellschaft

Bayer Aktiengesellschaft

Chemische Werke Huels Aktiengesellschaft

Huls Aktiengesellschaft

Dieter Zerpner

Karl-Heinz Nordsiek

Roland Streck

Horst G Haag

Jaroslaw Monkiewicz

Albert Frese

Jurgen Wolpers

Gerhard Horpel

Juergen Wolpers

Klaus Zur Nedden

Hans Datene

A tire tread made for polydiene rubber crosslinked with 1,2-bis(N,N-dibenzylthiocarbamoyldisulfido)ethane and method of producing the same.

Tire treads with increased tread life, and method of manufacturing same

Polysulfide compounds and vulcanization compositions containing the polysulfide compounds, for use in vulcanizing rubbers, are disclosed, with the polysulfide compounds being of the formula ##STR1## wherein R.sup.1 -R.sup.4 are each, independently, hydrogen or C.sub.1 -C.sub.4 alkyl and n is 2 to 10 wherein the polysulfide compounds can be used alone or in a vulcanization composition containing the polysulfide compound, sulfur, one or more additional accelerators, one or more basic compounds and, optionally, conventional rubber additives, to provide vulcanized products with improved reversion stability and ageing stability.

Bis-(thiobenzoyldisulfido)-alkanes

Vulcanization of diene rubbers at a temperature of from 140.degree. to 200.degree. C. in the presence of 1 to 4.5 parts of a crosslinker having the formula ##STR1## wherein n denotes 2 or 6 and Bz denotes benzyl, in the simultaneous presence of a very small amount of sulfur and a small amount of a mercapto or sulfenamide accelerator or mixtures thereof affords elastomers having a previously unachieved outstanding ageing stability and reversion stability, after relatively short vulcanization times using economical amounts of chemicals while avoiding blooming phenomena in the vulcanizate.

Process for the preparation of diene rubber vulcanizates

A coupling agent for vulcanizable mixtures of rubbers and mineral fillers which is the reaction product of a 2(3)-chloroacetoxy-5-(2'-trialkoxysilyethyl)norbornane of the formula: ##STR1## wherein R.sup.1 is methyl and/or ethyl, with a thiosulfonic acid salt of the formula:

Coupling agents for vulcanizable mixtures of unsaturated rubbers and

Process for adjusting the cis-trans-double bond configuration in polyalkenamers produced by ring-opening polymerization of cis,cis-1,5-cyclooctadiene or 2-norbornene wherein the polymerization is performed in the presence of isoprene and/or a cyclic olefin with a double-bond pair in the 1,3-position.

Process for adjusting the cis-trans-double bond configuration in

Novel adhesion promoters having, on the one hand, groups capable of forming a stable chemical bond with the surface of silicic acids and silicates (siloxane bond) and, on the other hand, groups capable of forming, during vulcanization, a stable chemical bond with an elastomer (sulfur bridges) are provided. They are consequently suitable as adhesion promoters for the production of vulcanizates exhibiting a favorable filler/elastomer bond. They are oligosulfanes of the formula

Adhesion promoters for the production of volcanizates having a favorable

Silyl-group-containing 1,3-butadiene polymers are stabilized against self crosslinking by addition of epoxides having an epoxy oxygen content of 2-17% by weight.

Low molecular weight 1,3-butadiene polymers containing reactive silyl

Polybutadiene oils of 400-6,000 molecular weight, having double bonds which are 10 to 60% vinyl, 1 to 15% transvinylene and 25 to 85% cis-vinylene, and 3-20% by weight, corresponding to 0.4 to 3% by weight of bound silicon, of which are reactive silyl polymer units of the formula ##STR1## wherein X is a hydrolyzable group and Y and Z are the same as X or are H and/or alkyl of 1-8 carbon atoms, cycloalkyl of 5-12 carbon atoms, or optionally substituted phenyl; are useful as adhesion promoters for vulcanizable elastomer compositions comprising a mineral filler.

Polymeric adhesion promoters for vulcanizable mixtures of elastomers and

Polyolefin rubber compositions which are readily heat-sealable are provided by the addition of 5-100 parts by weight, based on the polyolefin elastomer, of a propylene polymer uniformly admixed therewith prior to vulcanization which is selected from the group consisting of polypropylene and copolymers of propylene with up to 20% by weight of ethylene, butene-1 or hexene-1 which polymer has a heptane-extractable portion of 5-60%, and I-value measured according to DIN 53 728 of 100-600 cm.sup.3 /g. and a yield point measured according to DIN 53 735 of 10-30 N/mm.sup.2.

Heat-sealable vulcanizates comprising polyolefin rubber and propylene

The properties of elastomeric vulcanizates are improved by compounding an elastomer prior to vulcanization with a polydodecenamer reinforcing resin derived from cyclododecene and cyclododecadiene and vulcanizing the compounded elastomer.

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Marl, Germany

Dieter Zerpner