Bayer Aktiengesellschaft

Dieter Kuhlmann

Karl-Heinz Ott

Friedrich Kowitz

Bernhard Arnold

Christian Lindner

Herbert Bartl

Leo Morbitzer

Harald Oertel

Wolfgang Wieder

Wolfgang Nentwig

The production of diene rubbers polymerized by means of Nd catalysts and having reduced cold flow and low intrinsic odor is effected by the polymerization of diolefines adiabatically at temperatures of -20.degree. to 150.degree. C. in the presence of inert organic solvents and in the presence of metallo-organic mixed catalysts based on neodymium carboxylate, by subsequently depressurizing the reaction mixture obtained in this manner by reducing the pressure, and by treating the reaction mixture thereafter with disulphur dichloride, sulphur dichloride and/or thionyl chloride.

Process for producing diene rubbers polymerized by means of Nd catalysts

ABS-moulding compositions of (a) 5 to 70% by weight of one or more graft products and (b) 95 to 30% by weight of one or more thermoplastic resins with a content of 0.05 to 1% by weight (based on total moulding composition) of a perfluoroalkane acid or a derivative thereof to improve notched impact strength.

ABS-Moulding compositions having high notched impact strength

ABS-moulding compositions of (a) 5 to 70% by weight of one or more graft products and (b) 95 to 30% by weight of one or more thermoplastic resins with a content of 0.05 to 2.0% by weight (based on total mixture) of a silico urethane derivative to improve notched impact strength.

ABS-moulding compositions having high notched impact strength

A thermoplastic moulding composition which comprises: (A) from 99.99 to 94% by weight of an ABS composition comprising: (a) from 5 to 70% by weight of one or more rubber-based graft polymers; and (b) from 95 to 30% by weight of one or more thermoplastic resins; and (B) from 0.01 to 6.0% by weight of one or more compounds corresponding to the following general formula: ##STR1## wherein R represents hydrogen, C.sub.1 -C.sub.4 -alkyl or carboxyl; R.sup.1 represents hydrogen or methyl; and R.sup.2 represents carboxyl, and which may also contain from 0.1 to 3% by weight of one or more compounds corresponding to the formula: ##STR2##

ABS moulding compounds having improved surface

The use of a liquid polymethyl phenyl siloxane or a liquid polydimethyl siloxane, in combination with calcium stearate, pentaerythritol tetrastearate, bis-stearylamide of ethylene diamine or mixtures thereof for improving the physical properties of ABS-polymers.

ABS-Polymers of high notched impact strength

Polymer dispersions having solids contents of from 45 to 65% by weight are continuously produced by copolymerizing a vinyl ester, ethylene and (meth)acrylamidoalkyl sulphonic acid or (meth)acryloyloxyalkyl sulphonic acid or ammonium or alkali salt thereof under an ethylene pressure of from 5 to 120 atms, at a temperature of from 0.degree. to 60.degree.C in the presence of an anionic emulsifier and with the aid of a free radical forming agent. The polymer dispersions are suitable as pigment binders.

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Pulheim, Germany

Dieter Kuhlmann