Degussa & Henkel Kommanditgesellschaft Auf Aktien

Deutsche Gold- Und Silber-scheideanstalt Vormals Roessler

Degussa Aktiengesellschaft

Henkel & Cie G.m.b.h.

Henkel Kommanditgesellschaft Auf Aktien

Henkel Kommanditgesellschaft Auf Aktien (henkel Kgaa)

Henkel U. Cie

Dieter Kneitel

Wolfgang Roebke

Hans Strack

Ehrfried Parr

Erfried Parr

Klaus Heyne

Steffon Hasenzahl

The present invention concerns a method for the production of a titanium-containing zeolite whereby a synthesis gel is formed by combining and hydrolysing a hydrolysable silicon compound, a hydrolysable titanium compound and a basic quaternary ammonium compound in an aqueous medium, in quantities such that relative to the starting compounds the molar ratio of Si/Ti is greater than or equal to 30 and that of N/Si is 0.12 to less than 0.20, and the synthesis gel is then crystallised at a temperature of 150 &#xb0; C. to 220 &#xb0; C. for a period of less than 3 days, and a titanium-containing zeolite obtainable by this method.

Method for the production of a titanium-containing zeolite

There are produced crystalline zeolite powders of Type A with the composition

Process for preparing zeolite powder of type A (IV)

Crystalline zeolite powder of type A (III)

There are produced crystalline zeolite powders of Type A with the composition 1.0.+-.0.2 M.sub.2/n O:Al.sub.2 O.sub.3 :1.85.+-.0.5 SiO.sub.2 .multidot.y H.sub.2 O where M is a metal cation, n is its valence and y has a value up to 6 with 50 weight % of the particles not over 4.0.mu. and with a particle spectrum

Crystalline zeolite powder of type A (I)

Crystalline zeolite powder of type A (IV)

Crystalline zeolite powder of type A (V)

There are produced crystalline zeolite powders of Type A with the composition 1.0.+-.0.2 M.sub.2/n O:Al.sub.2 O.sub.3 :1.85.+-.0.5 SiO.sub.2 .multidot.y H.sub.2 O where M is a metal cation, n is its valence and y has a value up to 6 with 50 weight % of the particles not over 5.9.mu. and with a particle spectrum

Crystalline zeolite powder of type A (VI)

Alkali aluminum silicates, particularly a zeolitic molecular sieve powder with an average particle diameter of less than 10.mu. and having the portion of particles with a particle size above 45.mu. being less than 1 weight % are prepared by hydrothermal crystallization of an alkali aluminate-silicate mixture, separating the crystallization product from the mother liquor and drying with the proviso that the aqueous medium surrounding the crystallization product is adjusted to a pH value between 8.5 and 11 prior to the drying. The product is used as an ion exchanger, e.g., in dehardening water, particularly as a phosphate substitute in washing, rinsing and cleansing agents.

Process for the production of aluminum silicates

There are provided alkali aluminum silicates having a hydrophilic surface. They are prepared by mixing a crystalline, ion-exchanging alkali aluminum silicate with a hydrophilic material, preferably ortho-phosphoric acid or an alkali ortho phosphate.

Ion-exchanging aluminum silicate with hydrophilic surfaces

A crystalline zeolitic molecular sieve of Type A with the composition 1.0 .+-. 0.2 M.sub.2/n O : Al.sub.2 O.sub.3 : 1.85 .+-. 0.5 SiO.sub.2 . y H.sub.2 O where M is a metal cation, n its valence and y has a value up to 6 is prepared having particles with at least 99.5 weight % below 30.mu. diameter, as well as at least 90 weight % under 10.mu. and with 50 weight % below 6.5.mu. by hydrothermal crystallization of an alkali-aluminate silicate by pouring together an aqueous alkali silicate solution and a slightly concentrated aqueous alkali aluminate liquor, in a given case with simultaneous stirring in a receiver, allowing the synthesis premixture to solidify to a gel, adding to this gel a more highly concentrated aqueous alkali aluminate liquor at a temperature between 10.degree. and 100.degree. C. while stirring, allowing the thus obtained synthesis mixture to crystallize at a temperature between 20.degree. and 175.degree. C., preferably 100.degree. C., within 15 minutes and in a given case including a tempering step.

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Rodenbach, Germany

Dieter Kneitel