Bp Oil International Limited

Bp Chemicals Limited

Naphtachimie S.a.

Eutech Engineering Solutions Limited

Didier C Lambert

Andre Martens

Bernard Descales

Jean-Richard Llinas

Michel Sanchez

Gilbert Ventron

Sebastien Osta

Claude Granzotto

Sylvie Bages

Alain Espinosa

Antoine Pasquier

A method of determining or predicting a value P.sub.x of a property (e.g. octane number) of a material X or a property of a product of a process from the material or yield of the process for example a blending, separation, or chemical (e.g. polymerization) process, which method comprises measuring the absorption D.sub.ix of the material at more than one wavelength in the region 600-2600 nm, comparing the the signals indicative of the absorptions or a derivative thereof with signals indicative of absorptions D.sub.im or derivatives thereof at the same wavelength for a number of standards S in a bank for which the property or yield P is known, and choosing from the bank at least one standard S.sub.m with property P.sub.m the standard having the smallest average value of the absolute difference at each wavelength i between the signal for the material and the signal for the standard S.sub.m to obtain P.sub.x, with averaging of the properties or yields P.sub.m when more than one standard S.sub.m is chosen. If desired the method can be used as such to control the process by comparison of P.sub.m with the desired value and adjustment of the process to minimize deviations from P.sub.m ; in an alternative process the signal (or function thereof) of the standard(s) with the smallest average value of the absolute difference may be used directly to control the process.

Method for determining properties using near infra-red (NIR) spectroscopy

A method of determining or predicting a value P.sub.x of a property of a feed X to a steam cracking process or yield of said process, which method comprises measuring the absorption D.sub.ix of said material at more than one wavelength in the region 600-2600 nm, comparing signals indicative of said adsorptions or a mathematical function thereof with signals indicative of absorptions D.sub.im or mathematical function thereof at the same wavelength for a number of standards S in a bank for which the said property or yield P is known, and choosing from the bank at least one standard S.sub.m with property P.sub.m said standard having the smallest average value of the absolute difference at each wavelength i between the signal for the material and the signal for the standard S.sub.m to obtain P.sub.x, with averaging of said properties or yields P.sub.m when more than one standard S.sub.m is chosen. If desired the method can be used as such to control the steam cracking process by comparison of P.sub.m with the desired value and adjustment of the process to minimize deviations from P.sub.m ; in an alternative process the signal (or function thereof) of the standard(s) with the smallest average value of the absolute difference may be used directly to control the process.

Cracking property determination and process control

An apparatus for on-line measuring physical property data of hydrocarbon products such as octane number, cetane number, density, vapour pressure and the like or gasoline/alcohol ratio, comprising means for providing (N)IR radiation in a predetermined spectral range; means for transmitting light at selected wavelengths in the (N)IR spectral region; means for delivering light from said transmitting means to a hydrocarbon product line; means for allowing an optical path length in the hydrocarbon product line; means for detecting the light transmitted through the said optical path; means for providing the obtained signal to be input to processing equipment for spectral analysis and correlating the spectral data to the physical property data of hydrocarbon products such as octane number, cetane number, density, vapour pressure and the like or gasoline/alcohol ratio.

Cracking property determination

A method of determining or predicting a value P.sub.x of a property of a material X, which is a feed to a process or a property of a product of a process from said material or yield of said process, which method comprises measuring the absorption D.sub.i x of said material at more than one wavelength in the region 600-2600 nm, comparing the said absorptions or a derivative thereof with absorptions D.sub.i m or derivatives thereof at the same wavelength for a number of standards S in a bank for which the said property or yield P is known, and choosing from the bank at least one standard S.sub.m with property P.sub.m said standard having the smallest average value of the absolute difference at each wavelength i between the absorption D.sub.i x (or derivative thereof) for the material and the absorption D.sub.i m (or derivative thereof) for the standards S.sub.m to obtain P.sub.x, with averaging of said properties or yields P.sub.m when more than one standard S.sub.m is chosen, and wherein said process is at least one of polymerization, an oligomerization or an organic reaction in which at least one of the reactant and a product is a functionalized compound.

Chemicals property determination

A method of determining or predicting a value P.sub.x of a property of a material X, which is a feed to a process or a property of a product of a process from said material or yield of said process, which method comprises measuring the absorption D.sub.i x of said material at more than one wavelength in the region 600-2600 nm, comparing the said absorptions or a derivative thereof with absorptions D.sub.i m or derivatives thereof at the same wavelength for a number of standards S in a bank for which said property or yield P is known, and choosing from the bank at least one standard S.sub.m with property P.sub.m said standard having the smallest average value of the absolute difference at each wavelength i between the absorption D.sub.i x (or derivative thereof) for the material and the absorption D.sub.i m (or derivative thereof) for the standard S.sub.m to obtain P.sub.x, with averaging of said properties or yields P.sub.m when more than one standard S.sub.m is chosen, and wherein said material X is a composition comprising part of a lubricating oil fraction obtainable from a vacuum distillation of oil.

Lubricant property determination

A method of determining or predicting a value P.sub.x of a property (e.g. octane number) of a material X or a property of a product of a process from said material or yield of said process, which method comprises measuring the absorption D.sub.ix of said material at more than one wavelength in the region 600-2600 nm, comparing the said absorptions or a derivative thereof with absorptions D.sub.im or the derivatives thereof at the same wavelength for a number of standards S in a bank for which the said property or yield P is known, and choosing from the bank at least one standard S.sub.m with property P.sub.m said standard having the smallest average value of the absolute difference at each wavelength i between the absorption D.sub.i x (or derivative thereof) for the material and the absorption D.sub.i m (or derivative thereof) for the standard S.sub.m to obtain the P.sub.x, with averaging of said properties or yields P.sub.m when more than one standard S.sub.m is chosen.

Property determination

The octane number of a product is directly determined from its near infrared (NIR) absorption spectrum in the wave number spectral range of from 6667 to 3840 centimeter .sup.-1. A number (n) of frequencies is selected within this range, and the (n) absorbance values are correlated with the octane number by using a multivariate regression analysis.

Method for optimizing control of a production unit

The properties of a liquid hydrocarbon blend are determined from the NIR (Near Infra Red) spectrum of the components of the blend. This is accomplished by: (a) determining with an IR spectrometer, the absorbance of the components of the blend at a certain number of frequencies in the spectral range 16667 to 3840 cm.sup.-1 starting from a defined base line, (b) determining for each component and each property, a spectral mixture index (SMI) by applying a correlation between the SMI and the absorbance values, and then (c) calculating the property (J) to be determined by applying a linear expression, J=f.sub.a SMI.sub.a.sup.J +f.sub.s SMI.sub.b.sup.J +f.sub.c SMI.sub.c.sup.J + . . . f.sub.o SMI.sub.o.sup.J where SMI.sup.J.sub.(a, b, c . . . ) is the Spectral Mixture Index for property J for each component (a, b, c . . . ) and f.sub.(a, b, c . . . ) is the fraction by volume of that component in the final blend. The correlation in (b) is determined experimentally by multivariate regression, and is dependent upon the type of spectrometer used, the property to be determined, and the frequencies used.

Method for the direct determination of physical properties of

The properties and yield of a product from a hydrocarbon conversion or separation process may be determined from the NIR (Near Infrared) spectrum of the feedstock. This is accomplished by: (a) determining with an IR spectrometer the absorbance of the feedstock at a certain number of frequencies in the spectral range 16667 to 3840 cm.sup.-1 starting from a defined base line, and then (b) determining the property or yield by applying a correlation between the property or yield and the absorbance values. The correlation is determined experimentally by multivariate regression and is dependent upon the type of spectrometer employed, the property or yield to be determined, and the frequencies used.

Method and apparatus for determining a property or yield of a

The flocculation threshold of a petroleum product containing asphaltenes is measured by measuring the radiation in the near infrared transmitted through a sample of the product in solution in a solvent in relation to the quantity of precipitant continuously added to the sample.

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Lavera, France

Didier C Lambert