Phillips 66 Company

Conocophillips Company

Phillips Petroleum Company

Other

Dhananjay B Ghonasgi

Jianhua Yao

Edward L Sughrue

Bruce B Randolph

Xiaochun Xu

Tushar V Choudhary

Warren M Ewert

Joseph B Cross

Hong Xie

Jonathan R Marda

Marvin M Johnson

James B Kimble

Steven E Lusk

Paul F Meier

Chengtian Wu

Michael David Wardinsky

M Bruce Welch

Roland Schmidt

Neal Donald McDaniel

Robert William Morton

Richard L Anderson

Jason J Gislason

Anthony O Baldridge

Maziar Sardashti

Larry D Swinney

Sourabh S Pansare

James A Suttil

Hsu-Hui Hsing

Jianhu Yao

Jonathan Marda

Karthikeyan Marimuthu

Robert W Morton

Xie Hong

Bruce M Welch

Methods that increase production of a liquid transportation fuel blend component by utilizing C5 hydrocarbon streams taken from both a refinery naphtha stream and an NGL fractionator pentanes plus stream. A high vapor pressure pentane fraction from the NGL fractionator is separated to remove isopentane and produce lower vapor pressure commodity natural gasoline. A refinery naphtha stream (that is optionally an FCC naphtha stream) is separated to produce a C5 olefins stream that is then oligomerized to produce an upgraded stream having lower vapor pressure and higher octane rating, then combined with the remainder of the naphtha stream as well as the isopentane stream to produce a gasoline blend component that meets specifications for vapor pressure and octane rating.

Pentane-enriched hydrocarbons to transportation fuel

Systems for the catalytic activation and/or dehydrogenation of a paraffin feed stream that is enriched in C5 alkanes to produce olefins that are then hydrated in the presence of water to produce C5 alcohols. Optionally, paraffin isomers are separated and the n-paraffins isomerized prior to catalytic activation and/or dehydrogenation.

Systems for converting light paraffins to alcohols

A process and system for the conversion of a feedstock comprising C3-C5 light alkanes to a C5+ hydrocarbon product, for example, a BTX-rich hydrocarbon product, by performing the alkane activation (first-stage) and the oligomerization/aromatization (second-stage) in separate stages, which allows each conversion process to occur at optimal reaction conditions thus increasing the overall hydrocarbon product yield. The alkane activation or first-stage is operated at a higher temperature than the second-stage since light alkanes are much less reactive than light olefins. Since aromatization of olefins is more efficient at higher pressure, the second-stage is maintained at a higher pressure than the first-stage. Further, fixed-bed catalysts are used in each of the first-stage and the second-stage.

Dual stage light alkane conversion to fuels

The present disclosure relates generally processes and systems for converting a mixture of light hydrocarbons to liquid transportation fuels by first cracking the light hydrocarbons to an intermediate comprising olefins, which is converted by contacting with a catalyst comprising at least one zeolite in two separate conversion stages with an intervening recovery of liquid product. The first stage conversion favors oligomerization of larger olefins to form diesel range products that are collected prior to directing unconverted smaller olefins to be oligomerized in a second stage conversion conducted at a higher temperature and lower pressure.

Two stage upgrading of light olefins

System for two stage upgrading of light olefins

Processes relating to thermal activation (or cracking) of ethane to an intermediate, low purity raw ethylene stream in a first stage. This stream is then mixed with a stream of biomass-derived ethanol that may contain four volume percent or more of water. The resulting mixture is reacted over a suitable catalyst at temperatures and pressures suitable to produce gasoline-range and diesel-range blend stock.

Ethane and ethanol to liquid transportation fuels

A process for converting ethane to liquid fuels may involve directing an ethane stream into an ethane cracking unit to produce an intermediate hydrocarbon stream and a raw ethylene stream; fractionating the intermediate hydrocarbon stream into a gasoline fraction and a diesel fraction; introducing the raw ethylene stream into an oligomerization unit; contacting the raw ethylene stream with an oligomerization catalyst to produce a liquid hydrocarbon stream and an off-gas stream; recycling an off-gas recycle stream from an off-gas stream of the oligomerization unit separation unit to an inlet of the oligomerization reactor; introducing at least part of the off-gas stream into a hydrogenation reactor to remove unconverted olefins; separating a hydrogen component and a plurality of light paraffin components in a post hydrogenation reactor separation unit using a PSA technology or membrane technology; and recycling the light paraffins stream into the ethane cracking unit.

Converting ethane to liquid fuels and chemicals

Converting ethane may include directing a gaseous stream from a gas well into a fractionator for fractionating and producing a post-fractionator ethane stream, which is directed into a thermal activation unit for heating and raising the temperature of the post-fractionator ethane stream thereby creating an activated ethane stream, which is directed into a quench tower thereby creating a quenched stream, which may be converted in a catalytic conversion unit to a mixed product stream containing hydrogen and C-Chydrocarbons; directing the mixed product stream into a first separation unit forming a stream of C+ hydrocarbon product and a stream of C-Chydrocarbons; directing the stream of C-Chydrocarbons into a catalytic hydrogenation reactor thereby imparting hydrogen into a post-hydrogenation reactor stream, which is directed directly into a second separation unit thereby creating a light hydrocarbons recycle stream, which may be recycled into the thermal activation unit, and a hydrogen and methane stream.

Systems relating to thermal activation (or cracking) of ethane to an intermediate, low purity raw ethylene stream in a first stage. The system then mixes this stream with a stream of raw biomass-derived ethanol that may contain more than four volume percent of water. The resulting mixture is reacted over a suitable catalyst at temperatures and pressures suitable to produce gasoline-range and diesel-range blend stock.

Systems for converting ethane and ethanol to liquid transportation fuels

A heated petroleum-derived hydrocarbon is contacted with a triglyceride feed in a thermal cracking zone to decompose and remove impurities prior to hydrotreating the mixture to fuel range hydrocarbon. This process allows the use of a variety of low cost triglyceride feeds while reducing fouling of process equipment and catalyst. The process also reduces the use of chemicals required for conventional degumming of triglyceride feeds.

Thermal cracking of impurities in triglyceride mixtures

This invention relates to a hydroprocessing process with improved catalyst activity when hydroprocessing petroleum based feedstock or an oxygen containing feedstock. This invention also relates to a hydrotreating process with improved hydrodesulfurization (HDS) activity of a hydrotreating catalyst such as Co/Mo by co-feeding carbon monoxide or its precursors. Such inventive process confirms that adding a small amount of CO to H2 in a hydrotreater for a few days leads to an increase in product sulfur due to the inhibition of CO on the hydrotreating catalyst such as Co/Mo. However, it has been unexpectedly found that after the CO was removed from the hydrogen stream, product sulfur levels decreased to values below they were before CO addition which means the activity of the hydrotreating catalyst increased after the CO treatment.

Hydroprocessing process with improved catalyst activity

An integrated process for the conversion of carbohydrate containing materials to gasoline boiling range hydrocarbons is disclosed. A carbohydrate containing material may be converted to a hydrogenated carbohydrate containing material with a bi-functional catalyst. The hydrogenated carbohydrate containing material may be reacted in the presence of another catalyst to form a reaction product containing non-aromatic and aromatic gasoline boiling range hydrocarbons.

Integrated process for converting carbohydrates to hydrocarbons

A triglyceride or a triglyceride/hydrocarbon combination can be heated to produce thermally treated feeds. The thermally treated feeds can then be contacted with a hydrotreating catalyst in a reaction zone.

Thermal treatment of triglycerides

Methods of oligomerizing hydrocarbons are disclosed. These methods include contacting olefins with an oligomerization catalyst in an oligomerization zone under oligomerization reaction conditions.

Oligomerization of hydrocarbons

Processes for the conversion of carbohydrates to gasoline boiling range hydrocarbons, and processes for increasing the solubility of carbohydrates used in such processes are disclosed. The solubility of carbohydrates may be increased by contacting the carbohydrate with an ion-exchange resin. The dissolved product may be hydrogenated and reacted in the present of a catalyst to form a reaction product containing non-aromatic and aromatic gasoline boiling range hydrocarbons.

Growing community of inventors

Bartlesville, OK, United States of America

Dhananjay B Ghonasgi