Korea Research Institute of Chemical Technology

Sk Gas Co., Ltd.

Sk Energy Co., Ltd.

Sk Innovation Co., Ltd.

Korea National University of Transportation Industry-academic Cooperation Foundation

Kocat Inc.

Sk Innovation., Ltd.

Deuk Soo Park

Won Choon Choi

Yong Ki Park

Sun Woong Choi

Suk Joon Kim

Ung Gi Hong

Hee Young Kim

Yong Seung Kim

Chul Wee Lee

Na Young Kang

Seung Hoon Oh

Miyoung Lee

Dae Hyun Choo

Hong Chan Kim

Hawon Park

Daesung Park

Tae Jin Kim

Ji Min Kim

Bu Sub Song

Changyeol Song

Il Mo Yang

Ahn Seop Choi

Kwang An Ko

Jeong Ri Kim

Hyeongchan Ahn

Sang Yun Han

Jung Ho Kim

Jin Sung Kim

Kyung Min Kim

Mi Young Lee

Seong Jun Lee

Min Gyoo Park

Yoon Jae Yim

Tae-Jin Kim

Kyung Jong Oh

Hee Du Lee

Young Ki Park

Eun Sang Kim

Min Su Ko

Chul Jin Kim

Chang Hee Yang

Su Jin Gong

Seo Hyun Shim

Byungjun Kang

Chaeeun Yeo

Sungwon Kim

Hae Bin Shin

Sanghyeon Park

A method for producing olefins using a circulating fluidized bed process, includes: supplying a propane-containing hydrocarbon mixture and a dehydrogenation catalyst into a riser, which is a fast fluidization regime, to cause a dehydrogenation reaction; separating, from a propylene mixture, the catalyst which is a product of the dehydrogenation reaction; removing unseparated hydrocarbon compounds remaining in the catalyst separated in the separating; continuously regenerating the catalyst by mixing the catalyst stripped in the removing with a gas containing oxygen; circulating the catalyst regenerated in the continuously regenerating to the supplying and resupplying it into the riser; and preparing propylene by cooling, compressing, and separating the propylene mixture which is a reaction product separated in the separating.

Method for producing olefins using novel catalyst and circulating fluidized bed process

Disclosed is a catalyst for producing an olefin including an oxygen carrier material and a dehydrogenation catalyst. The catalyst allows hydrogen to be converted into water by using oxygen inside the lattice of an oxide catalyst without the additional supply of oxygen, and thus, the conversion can be increased while the decrease in selectivity, which is a disadvantage of an additional oxidative dehydrogenation reaction (ODHP), is suppressed.

Catalyst for producing olefin, including oxygen carrier material and dehydrogenation catalyst

Disclosed is a catalyst for producing an olefin, the catalyst having an excellent conversion and excellent selectivity, and a method for preparing the catalyst. The catalyst for producing an olefin, according to the present invention, includes: a support including alumina and an auxiliary support component; a main catalyst including an active metal oxide supported on the support; and a co-catalyst including an oxide of an alkali metal and a Group 6B transition metal.

Catalyst having enhanced conversion and selectivity for manufacturing olefin, and manufacturing method therof

Provided is a method for using selective non-catalytic reduction to reduce nitrogen dioxide in exhaust gas generated during an olefin production process. Nitrogen dioxide generated in a catalyst regeneration step of a continuous PDH process can be efficiently removed by the method of the present disclosure. Ultimately, the generation of visible fumes can be prevented through the removal of nitrogen dioxide.

Method for reducing nitrogen dioxide in exhaust gas generated during olefin production process

Disclosed is a method of producing an olefin using a circulating fluidized bed process, including: (a) supplying a hydrocarbon mixture including propane and a dehydrogenation catalyst to a riser which is in a state of a fast fluidization regime, and thus inducing a dehydrogenation reaction; (b) separating an effluent from the dehydrogenation reaction into the catalyst and a propylene mixture; (c) stripping, in which a residual hydrocarbon compound is removed from the catalyst separated in step (b); (d) mixing the catalyst stripped in step (c) with a gas containing oxygen and thus continuously regenerating the catalyst; (e) circulating the catalyst regenerated in step (d) to step (a) and thus resupplying the catalyst to the riser; and (f) cooling, compressing, and separating the propylene mixture, which is a reaction product separated in step (b), and thus producing a propylene product.

Method of producing olefin using circulating fluidized bed process

Disclosed is a catalyst for producing the olefin. The catalyst includes a support including alumina and a sub-support component, and a metal oxide impregnated on the support. The metal oxide includes anyone selected from an oxide of chromium, vanadium, manganese, iron, cobalt, molybdenum, copper, zinc, cerium and nickel; and the sub-support component includes anyone selected from zirconium, zinc and platinum.

Catalyst for producing olefin, and continuous reaction-regeneration olefin producing method using the catalyst

Disclosed are a catalyst for producing olefin and a preparation method thereof. The catalyst for producing olefin includes: a support including an alumina and a sub-support component; and a catalytic component comprising a metal component and an alkali metal impregnated on the support. The preparation method includes: providing a support comprising a sub-support component and an alumina; preparing pre-catalyst by dipping a metal component oxide in the support and calcining it; and dipping a metal component oxide and an alkali metal oxide in the pre-catalyst and calcining it.

Catalyst for producing olefin having enhanced stability, conversion rate and selectivity, and preparation method thereof

Disclosed is an olefin production method including: pretreating a catalyst by providing reduction gas to an alumina type catalyst to produce olefin from the hydrocarbon including not less than 90 wt % of LPG (Stage 1); producing the olefin by providing the catalyst pretreated at Stage 1 into Riser of Fast Fluidization Regime to dehydrogenate the hydrocarbon (Stage 2); separating the mixture of the produced propylene and the catalyst used at Stage 2, and regenerating the separated catalyst (Stage 3); and recycling the catalyst regenerated at Stage 3 to the process of Stage 1 (Stage 4).

Olefin production method comprising reduction pretreatment

Disclosed is an olefin production method which includes: (a) providing the regenerated catalyst and the hydrocarbon including not less than 90 wt % of LPG into Riser of Fast Fluidization Regime, and dehydrogenating in the presence of an alumina type catalyst; (b) separating an effluent from the dehydrogenation reaction into the catalyst and propylene mixture; (c) stripping to remove the hydrocarbon compound included in the catalyst separated at stage (b); (d) mixing the catalyst stripped at stage (c) with the gas including oxygen, and continuously regenerating it; (e) recycling the catalyst regenerated at stage (d) to stage (a), and providing it again into Riser; and (f) producing propylene product by cooling, compressing and separating propylene mixture of the reaction product separated at stage (b).

Olefin production method using circulating fluidized bed process

An embodiment of this invention provides a method of effectively producing propylene by separating reaction products obtained by dehydrogenating propane-containing feedstock, using an adsorption process in lieu of conventional low-temperature separation processes.

Method for separating propylene from dehydrogenation reaction products of propane-containing feedstock

Disclosed is a method of recovering 1,3-butadiene from a C4 stream containing butane, isobutane, 2-butene, 1-butene, isobutene, butadiene and acetylene. The process of recovering highly pure 1,3-butadiene includes acetylene conversion for selectively converting acetylene through liquid-phase hydrogenation, so that the acetylene content is decreased to 70 wt ppm or less, and 1,3-butadiene extraction using an extractive distillation column, a pre-separator, a solvent stripping column, a solvent recovery column, and a purification column. Through the acetylene conversion, the concentration of vinylacetylene is decreased to 70 wt ppm or less, after which 1,3-butadiene is recovered using only one extractive distillation column, thereby considerably decreasing the degree of utility and the loss of streams in the course of extraction. The number of units necessary for the process is decreased, thus remarkably reducing the time during which impurities can accumulate in a processing unit.

Process for 1,3-butadiene separation from a crude C4 stream with acetylene converter

Disclosed are a molecular sieve catalyst and a preparation method thereof to produce light olefins from cracking naphtha catalytically in severe environments of high temperature and high moisture. In detail, the catalyst is prepared by spray-drying and calcining the mixed slurry, in which 0.01&#x2dc;5.0 wt % of MnOand 1&#x2dc;15 wt % of POare simultaneously imbedded in catalyst which consists of zeolite, clay and inorganic complex. According to the present invention, the method that manganese and phosphate are imbedded simultaneously in zeolite and inorganic complex is used to increases thermal-stability of obtained spherical catalyst, and increase olefin yield of cracking hydrocarbon such as naphtha by protecting acid-site of zeolite. To synthesize the required catalyst, the important procedures are mixing ratio and mixing sequence of Mn, P, zeolite, and inorganic complex.

Catalyst for catalytic cracking of hydrocarbon, which is used in production of light olefin and production method thereof

A method of preparing ZSM-5, including: providing a nanocrystalline ZSM-5 seed having a size of 70-150 nm; adding the nanocrystalline ZSM-5 seed to a stock solution including water glass as a silica source, an alumina source, a neutralizer and water to form a reaction mixture; and maintaining the reaction mixture at 150-200&#xb0; C. to crystallize the reaction mixture. The method is advantageous in that ZSM-5 having small and uniform crystal sizes and including no impurities can be synthesized in a short period of time.

Method of preparing ZSM-5 zeolite using nanocrystalline ZSM-5 seeds

Disclosed is a catalytic cracking process for the production of light olefins from a hydrocarbon feedstock using fast fluidization, which is a preferred process for more efficiently increasing the production of light olefin hydrocarbons. According to this invention, a fast fluidization regime is applied to a fluidized bed catalytic cracking process of producing light olefins using zeolite, such that a volume fraction and distribution of the catalyst sufficient to induce the catalytic cracking reaction can be provided, thus effectively enhancing the production of light olefin hydrocarbons, in particular, ethylene and propylene, at high selectivity.

Catalytic cracking process using fast fluidization for the production of light olefins from hydrocarbon feedstock

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Gyeonggi-do, South Korea

Deuk Soo Park