US Government As Represented by the Secretary of the Army

Deryn D Chu

Rongzhong Jiang

Dat Tien Tran

Charles C Rong

Michael Binder

Robert J Mammone

Charles W Walker, Jr

Judy Walker, Legal Representative

Methods and apparatus for generating electric power from a fuel cell are disclosed. In embodiments, a fuel cell for generating electric power includes: a first electrochemical cell including a first electrode and second electrode, wherein the first electrochemical cell is configured to generate a first stage electric power (P) from a fuel source; and a bi-cell including a second electrochemical cell and third electrochemical cell, wherein the second electrochemical cell includes a third electrode in fluid communication with the fuel source, and a fourth electrode, wherein the second electrochemical cell is configured to generate hydrogen gas from the fuel source and transport the hydrogen gas to a third electrochemical cell, and wherein the third electrochemical cell includes the fourth electrode, and a fifth electrode in fluid communication with a second air source, wherein the fourth electrode is configured for use by the second electrochemical cell as a cathode for hydrogen generation, and by the third electrochemical cell as an anode for hydrogen oxidation, and wherein the third electrochemical cell is configured to generate a second stage electric power (P).

Method and apparatus of an air breathing hydrogen fuel cell using direct liquid fuels

The present invention relates to a fuel cell having an anode; a cathode opposing the anode; a first electrolyte membrane disposed between the anode and the cathode; a second electrolyte membrane disposed between the anode and the cathode; and an A/C junction electrode disposed between the first electrolyte membrane and the second electrolyte membrane, the A/C junction electrode comprising a first gas diffusion layer; a second gas diffusion layer; a current collector disposed between the first gas diffusion layer and the second gas diffusion layer; a first catalyst layer disposed between the first electrolyte membrane and the first gas diffusion layer; and a second catalyst layer disposed between the second electrolyte membrane and the second gas diffusion layer.

Methods and apparatus of an anode/cathode (A/C) junction fuel cell with solid electrolyte

An apparatus and method for generating low pressure hydrogen gas from fuel solutions (i.e., alcohols) without the use of an external power source or external heat source. The apparatus comprises (a) a first chamber for fuel storage having an aperture, (b) a second chamber for the temporary storage of hydrogen gas generated having an aperture, (c) a first electrochemical cell (Cell-1) and (d) a second electrochemical cell (Cell-2). Cell-2 is disposed between the first chamber and the second chamber so that its anode is in fluid communication with the first chamber and its cathode is in fluid communication with the second chamber. Cell-1 is disposed on the opposite side of the first chamber from Cell-2 so that the anode therein is in fluid communication with the first chamber, and the cathode therein is in fluid communication with an oxidizing agent. The first chamber is sandwiched between Cell-1 and Cell-2. An air convection window or like device making ambient air available to the apparatus via Cell-1 is positioned on the side of Cell-1 opposite the fuel chamber. In operation, fuel is provided to the first chamber, the anode of Cell-1 is connected to the cathode of Cell-2, and the cathode of Cell-1 is connected to the anode of Cell-2, and hydrogen gas is continuously generated from the hydrogen chamber. The present invention may be used at room temperature.

Power-free apparatus for hydrogen generation from alcohol

A method and system for desulfurization comprising first and second metal oxides; a walled enclosure having an inlet and an exhaust for the passage of gas to be treated; the first and second metal oxide being combinable with hydrogen sulfide to produce a reaction comprising a sulfide and water; the first metal oxide forming a first layer and the second metal oxide forming a second layer within the walled surroundings; the first and second layers being positioned so the first layer removes the bulk amount of the hydrogen sulfide from the treated gas prior to passage through the second layer, and the second layer removes substantially all of the remaining hydrogen sulfide from the treated gas; the first metal oxide producing a stoichiometrical capacity in excess of 500 mg sulfur/gram; the second metal oxide reacts with the hydrogen sulfide more favorably but has a stoichometrical capacity which is less than the first reactant; whereby the optimal amount by weight of the first and second metal oxides is achieved by utilizing two to three units by weight of the first metal oxide for every unit of the second metal oxide.

Desulfurization apparatus and method

A passive fuel cell assembly, in which there is neither air pump, nor fuel pump, is comprised of a plurality of bi-cell units. Each bi-cell unit includes a first cell and a second cell, and each cell includes an electrode of a first polarity and an electrode of a second polarity, with an ion permeable membrane disposed therebetween. The bi-cell unit further includes a fuel container which comprises a housing defining a fuel chamber having a first and second open surface. The first and second cells are disposed on opposite sides so that electrodes of each cell having the first polarity are disposed in fluid contact with the fuel chamber. The assembly further includes an oxidizer supply member disposed between adjacent pairs of bi-cell units. The oxidizer supply member includes an oxidizer chamber having four sides to take in air, and having first and second open surfaces. The oxidizer supply member is disposed so that electrodes of the second polarity of adjacent bi-cell units are in fluid contact with the chamber of the oxidizer supply member. The various bi-cell units may be electrically interconnected in mixed series parallel relationship to obtain long operational life. The fuel cell bi-cell assembly may be configured to operate in conjunction with a liquid fuel such as an alcohol, and using air as an oxidizer.

Fuel cell assembly

A metal-air battery has an anode in which the electrochemically active material is molybdenum. The molybdenum may be in the form of a bulk body of material or it may comprise a particulate material dispersed with or in another material. In some instances, the molybdenum may comprise a member of an alloy or mixture. Also disclosed is a modular battery system which may include the molybdenum-based anode material.

Molybdenum/air battery and cell design

An electrolyte membrane assembly for use in a fuel cell or other electrochemical device includes an ion exchange membrane, a base electrolyte reservoir configured and operable to maintain a volume of a basic electrolyte solution in contact with at least some of the first face of the membrane, and an acid electrolyte reservoir configured and operable to maintain a volume of an acidic electrolyte in contact with at least a portion of the second face of the membrane. The membrane may be a cation exchange membrane or an anion exchange membrane. Also disclosed are fuel cells which incorporate the electrolyte membrane assembly.

High voltage methanol fuel cell assembly using proton exchange membranes and base/acid electrolytes

An electrochemical electrode probe includes an elongated body of a porous material disposed in a housing. The porous material is permeated with an electrolyte. A body of electrode material surrounds the porous body and functions as one electrode of an electrochemical system. A portion of the elongated body of porous material projects beyond the electrode body and functions to establish ionic and electrical conductivity with a sample of material which is to be tested. The sample of material functions as a working electrode, and the electrode body of the probe functions as a counter electrode/reference electrode. Further disclosed is an electrochemical analysis system which includes the probe and a support plate operable to retain a plurality of samples of test material thereupon. The probe is moved across the plate to sequentially measure the electrochemical properties of the various samples of material. Also disclosed are methods for using the system.

Electrochemical test apparatus and method for its use

An ionic conductive wire and method of forming an electrochemical cell in which an electric insulate tube is filled with an ionic conductive material. Terminals proximate the ends of the electric insulate tube are sealed with a fine porous material that is electric-insulate. The ionic conductive wire is movable such that it selectively connects at least two electric conductive materials to form an electrochemical cell.

Movable ionic conductive wire and method of forming an electrochemical cell

Methods of forming a platinum deposit on a nonconductive substrate are diosed, comprising the steps of hydrophobically treating a carbon black powder, forming a solution of chloroplatinic acid, suspending the hydrophobically treated carbon black powder in the chloroplatinic acid, immersing a nonconductive substrate in the chloroplatinic acid and adding formaldehyde to said chloroplatinic acid. The hydrophobically carbon black powder suspended in the chloroplatinic acid catalyzes and drives the reduction of platinum within the chloroplatinic acid toward the nonconductive substrate and reduces the chloroplatinic acid forming metallic platinum on the nonconductive substrate. In a preferred embodiment, a platinum deposit is formed on a glass substrate immersed in the chloroplatinic acid and the step of hydrophobically treating the carbon black powder is accomplished by adding a CF.sub.4 gas plasma to the carbon black powder.

Growing community of inventors

Potomac, MD, United States of America

Deryn D Chu