Martin Marietta Corporation

Other

United Technologies Corporation

Commonwealth Aluminum Corporation

Siemens Energy, Inc.

Martin Marietta Magnesia Specialties, Inc.

Martin Marietta Aluminum Inc.

Martin Marietta Corportion

Dennis C Nagle

John M Brupbacher

Leontios Christodoulou

Larry G Boxall

William M Buchta

Arthur V Cooke

Douglas W Townsend

Donald F Shepard

Michael E Marousek

Robert J Fenolia

Christopher E Byrne

William C Moshier

Stephen L Kampe

Larry G Christner

Paul John Zombo

Brij B Seth

Donald L Maricle

Richard H Van De Walle

Paul R Watson

Vinod Philip

In H Kim

Myron T McCall

A method for in-frame repairing of a thermal barrier coating () on a gas turbine component includes cleaning a desired surface portion () of the component without removing the component from the gas turbine. The method also includes roughening the surface portion in-frame, applying a bond coat () to the surface portion in-frame, and applying a ceramic topcoat () to the bond coat, in-frame. A system () for cleaning the surface portion in-frame includes an abrasive media () having a state change characteristic occurring at a temperature lower than an operating temperature of the gas turbine so that the abrasive media changes from a solid state to another state allowing the media to exit the gas turbine during operation. The system also includes an abrasive media sprayer () to direct a spray of the abrasive media at the desired surface portion.

In-frame repairing system of gas turbine components

A method of carbonizing cellulose-containing plants is disclosed. Wood is used as a precursor material which is carbonized under controlled temperature and atmosphere conditions to produce a porous carbon product having substantially the same cellular structure as the precursor wood. The porous carbonized wood may be used for various applications such as filters, or may be further processed to form carbon-polymer or carbon-carbon composites. The carbonized wood may also be converted to a ceramic such as silicon carbide. Additional processing may be used to form ceramic-metal or ceramic-ceramic composites.

Carbonized wood and materials formed therefrom

A method of carbonizing cellulose-containing plants is disclosed. Wood is used as a precursor material which is carbonized under controlled temperature and atmosphere conditions to produce a porous carbon product having substantially the same cellular structure as the precursor wood. The porous carbonized wood may be used for various applications such as filters, or may be further processed to form carbon-polymer or carbon--carbon composites. The carbonized wood may also be converted to a ceramic such as silicon carbide. Additional processing may be used to form ceramic-metal or ceramic--ceramic composites.

An article of manufacture comprises a substrate and an optically black surface on the substrate and having an absorptivity of more than about 0.89 and an emissivity more than about 0.86. The surface comprises boron particles plasma spray applied to the substrate using a powder selected from the group consisting of crystalline boron having a particle size finer than about 200 mesh and amorphous boron.

High-temperature, High-emissivity, optically black boron surface

A method is taught for the in-situ precipitation of ceramic materials in a metal matrix. By means of the solvent assisted reaction, metal-ceramic composites having highly superior properties may be obtained. The invention involves the reaction of the ceramic forming constituents in a metal solvent medium to provide very finely-dispersed ceramic particles in the metal matrix. Exemplary materials include titanium diboride in an aluminum matrix.

Metal-ceramic composites

The present invention resides in an optically black article comprising a substrate and an optically black coating adhered to the substrate. The coating has an absorptivity of at least about 0.92 and an emissivity of at least about 0.85, obtained by plasma spraying onto the substrate a composition comprising about 20% to about 50% by weight of a carbonyl metal and about 80% to about 50% by weight of a ceramic metal oxide. A preferred carbonyl metal is carbonyl iron. A preferred ceramic metal oxide is a yttria stabilized zirconia, having an average particle size in the range of about 10 microns to about 106 microns (140 mesh).

Diffuse black plasma sprayed coatings

High-temperature, high-emissivity, optically black boron surface

An arc-melting method is taught for the formation of metallic-second phase composite materials. The method involves the formation of an intermediate composite material comprising a relatively high loading of second phase particles dispersed in a metal matrix. This intermediate material is then combined with an additional amount of metal and arc-melted to form a final composite comprising a lower loading of the second phase particles dispersed in a final metallic matrix. The final metallic matrix may be comprised of a metal, metal alloy, or intermetallic, while the second phase particles may comprise ceramic materials such as borides, carbides, nitrides, silicides, oxides or sulfides.

Arc-melting process for forming metallic-second phase composites

The present invention relates to the formation of whisker reinforced metal matrix composites in which complex boride or carbide whiskers having an aspect ratio of greater than 10:1 are distributed throughout a metal, metal alloy, or intermetallic matrix. Exemplary complex boride whiskers include TiNbB, TiTaB, TiVB, NbHfB, and TiNbMoB. Exemplary complex carbide whiskers include TiNbC, TiVC, TiZrC, TiHfC, and TiTaC. A method for the in-situ formation of complex boride and complex carbide whiskers within metallic matrices is disclosed which involves reacting a mixture of individual complex ceramic-forming constituents in the presence of a metal to precipitate the desired complex ceramic whiskers in a metal matrix.

Metal-ceramic composites containing complex ceramic whiskers

This invention relates to a rapidly solidified product comprising a second phase in both a stable particulate form and a metastable flake form dispersed in an intermetallic matrix.

Rapidly solidified intermetallic-second phase composites

A method is taught for the in-situ precipitation of second phase materials, such as ceramic or intermetallic particles, in a substantial volume fraction of solvent metal matrix. The invention involves the propagating reaction of the second phase-forming constituents in a solvent metal medium to provide a porous composite of finely-dispersed second phase particles in the metal matrix. Exemplary materials include titanium carbide or titanium diboride in an aluminum matrix.

Process for forming porous metal-second phase composites

Magnesia pellets are formed from finely-divided, highly reactive, lightburned magnesia (MgO) particles by granulating such powders in conventional equipment using either an organic liquid or an organic liquid-binder mixture. The organic liquid may be an alcohol or a ketone the alkyl groups of which, independently, can have from 1 to 4 carbon atoms. Magnesium chloride and water are among disclosed binders which may be used in combination with said organic liquid. The organic liquid should be more than about 80% of any admixtures with water.

Granulation of magnesium oxide particles

The present invention relates to a process for the production of fine powder materials and the products of that process. The process involves the in-situ precipitation of second phase particles, such as ceramic or intermetalics, within a metal matrix, followed by separation of the particles from the matrix to yield a powder comprising the second phase particles. Particles formed by this process are typically in the size range of 0.01 to 10 microns and have controlled morphology, narrow size distribution, well defined stoichiometery and relatively high purity. Exemplary of second phase particles formed by this process are metal borides, carbides, nitrides, oxides, silicides and beryllides, including TiB.sub.2, ZrB.sub.2, VB.sub.2, MoB.sub.2, TiC, WC, VC, TiN, ZrSi.sub.2, MoSi.sub.2, Ti.sub.5 Si.sub.3, and TiBe.sub.12.

Growing community of inventors

Ellicott City, MD, United States of America

Dennis C Nagle