Xerox Corporation

Denise Y Wright

Hadi K Mahabadi

John A Creatura

Michael F Cunningham

T Hwee Ng

Angelo J Barbetta

A process for the preparation of conductive polymeric particles with linear and crosslinked portions, which comprises mixing a monomer with at least one conductive filler, solvent, at least one polymerization initiator, and a chain transfer component; effecting solution polymerization by heating until from about 80 to about 100 weight percent of the monomer has been polymerized; drying the mixture by removing the solvent to yield an intimate blend of polymer with conductive filler; dispersing the aforementioned blend of polymer and conductive filler in at least one monomer with at least one polymerization initiator, a crosslinking agent and a chain transfer agent to form an organic phase; dispersing the resulting organic phase mixture in water containing a stabilizing component to obtain a suspension of particles with an average volume diameter of from about 0.05 to about 5 microns in water; polymerizing the resulting suspension by heating; and subsequently optionally washing and drying the polymeric product.

Process for preparing conductive polymeric particles with linear and

Process for the preparation of conductive polymeric particles with

A process for the preparation of carrier particles which comprises the dry coating of a carrier or carrier cores with conductive submicron polymeric particles containing from about 1 to about 50 weight percent of conductive fillers, and wherein said conductive polymer particles are prepared by mixing at least one monomer with a polymerization initiator, a crosslinking component and a chain transfer component; effecting bulk polymerization until from about 5 to about 50 weight percent of the monomer has been polymerized; terminating polymerization by cooling the partially polymerized monomer; adding thereto from about 1 to about 50 weight percent of a conductive filler or conductive fillers, followed by mixing thereof; dispersing the aforementioned mixture of conductive filler or fillers, and partially polymerized product in water containing a stabilizing component to obtain a suspension of particles with an average diameter of from about 0.05 to about 1 micron in water; polymerizing the resulting suspension by heating; subsequently washing and drying the product; thereafter heating the carrier core or carrier cores and the resulting conductive polymer particles to enable fusing thereof to said core or cores; and cooling the carrier particles obtained, which particles have a conductivity of from between about 10.sup. -4 to about 10.sup.-10 mho-cm.sup.-1.

Dry carrier coating and processes

A process for the preparation of a toner composition which comprises (1) mixing a water soluble monomer or monomers, and an oil soluble monomer or monomers with polymerization initiators, a crosslinking component and a chain transfer component; (2) effecting bulk polymerization until from about 10 to about 40 weight percent of the water soluble and oil soluble monomer or monomers have been polymerized; (3) cooling the product obtained; (4) mixing with the aforesaid partially polymerized product components comprised of charge control agents, pigments, dyes, initiators, chain transfer agents and crosslinking agents to formulate a uniform organic phase; (5) dispersing the organic phase into from between about 2 to about 5 times its volume of water containing from between about 1 to about 5 weight percent of a stabilizing component to form a suspension with an average particle size of from between about 5 to about 25 microns and a particle size distribution of from about 1.1 to about; and (6) suspension polymerizing to complete the conversion of said monomer, or said monomers to polymer.

Processes for the preparation of polymers

A process for the preparation of conductive submicron polymeric particles which comprises mixing at least one monomer with a polymerization initiator, a crosslinking component and a chain transfer component; effecting bulk polymerization until from about 10 to about 50 weight percent of the monomer has been polymerized; terminating polymerization by cooling the partially polymerized monomer; adding thereto from about 1 to about 50 weight percent of a conductive filler, or conductive fillers, followed by mixing thereof; dispersing the aforementioned mixture of conductive filler or fillers, and partially polymerized product in water containing a stabilizing component to obtain a suspension of particles with an average diameter of from about 0.05 to about 1 micron in water; polymerizing the resulting suspension by heating; and subsequently washing and drying the product.

Conductive composite particles and processes for the preparation thereof

A process for the preparation of polymeric particles which comprises mixing at least one monomer with a polymerization initiator, a crosslinking component and a chain transfer component; effecting bulk polymerization until partial polymerization results; dispersing the aforementioned partially polymerized monomer product in water containing a stabilizing component to obtain a suspension of particles in water and polymerizing the resulting suspension.

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Mississauga, Canada

Denise Y Wright