Arkema France

Denis Huze

Benoît Brule

Gilles Hochstetter

Mathieu Capelot

Patrice Gaillard

Thibaut Savart

Cyrille Mathieu

Arthur Pierre Babeau

François Tanguy

Marc Audenaert

Jerome Pascal

Nadine Decraemer

Axel Salinier

Emmanuel Rastelletti

Hervé Ster

The invention relates to a process for manufacturing a pre-impregnated fibrous material comprising a continuous fibre fibrous material and at least one thermoplastic polymer matrix, characterized in that said pre-impregnated fibrous material is made of a single unidirectional ribbon or a plurality of parallel ribbons unidirectional and in that said method comprises an impregnation step, in particular at the core, of said fibrous material being in the form of a roving or of several parallel rovings by said thermoplastic polymer being in powder form, said step of impregnation being carried out with said at least one thermoplastic polymer and said fibrous material the D90/D10 ratio of which by volume of the thermoplastic polymer particles ranges from 1.5 to 50, in particular from 2 to 10 and the ratio of the average diameter by volume (D50) thermoplastic polymer particles on the average diameter of the unit fibres of said fibrous material ranges from 3 to 40, except for an impregnation process in aqueous suspension of a fibrous material made of carbon fibres by a thermoplastic polymer, said D50/mean unit fibre diameter ratio being comprised from 3 to 8, and excluding any electrostatic process in voluntary charge.

Process for manufacturing a fibrous material pre-impregnated with thermoplastic polymer in powder form

A method of manufacturing an impregnated fibrous material including a fibrous material made of continuous fibers and at least one thermoplastic polymer matrix, the method including pre-impregnating the fibrous material while it is in the form of a roving or several parallel rovings with the thermoplastic material and heating the thermoplastic matrix for melting, or maintaining in the molten state, the thermoplastic polymer after pre-impregnation, the at least one heating step being carried out by means of at least one heat-conducting spreading part (E) and at least one heating system, with the exception of a heated calendar, the roving or the rovings being in contact with part or all of the surface of the at least one spreading part (E) and partially or wholly passing over the surface of the at least one spreading part (E) at the level of the heating system.

Method for manufacturing a fibrous material impregnated with thermoplastic polymer

The invention relates to a process for manufacturing a preimpregnated fibrous material containing a fibrous material made of continuous fibers and at least one thermoplastic polymer matrix, wherein the preimpregnated fibrous material is produced as a single unidirectional tape or of a plurality of parallel unidirectional tapes and wherein the process includes a step of impregnating, in particular fully and homogeneously, the fibrous material that is in the form of a roving or of several parallel rovings with the at least one thermoplastic polymer matrix that is in powder form, the impregnating step being carried out by a dry route in a tank and the control of the amount of the at least one thermoplastic polymer matrix in said fibrous material being achieved by control of the residence time of said fibrous material in the powder, with the exclusion of any electrostatic process with intentional charging.

Fluidized-bed process for manufacturing a fibrous material preimpregnated with thermoplastic polymer

The present invention relates to a method for producing a conductive composite material, as well as the composite material capable of being obtained by said method. The conductive material is obtained from a composite polymer matrix, which is formed by aggregation of composite conductive particles consisting of particles of a polymer matrix, having a diamter d50 of between 1 and 4000 &#x3bc;m, coated with a layer of electrically conductive material consisting of at least one metal. The ratio of the thickness of the conductive layer to the diameter d50 of the polymer matrix particles is between 0.0025:100 and 1.5:100, said thickness being less than 300 nm.

Method for producing a composite conductive material and composite material obtained in this way

Process for densification of a poly(arylene ether ketone) (PAEK) powder or of a mixture of poly(arylene ether ketone) (PAEK) powders, the process being mixing the powder or the mixture of powders, in a mixer equipped with a rotary stirrer including at least one blade, for a period of between 30 minutes and 120 minutes, preferably of between 30 and 60 minutes, at a blade-tip speed of between 30 m/s and 70 m/s, preferably of between 40 and 50 m/s.

Process for densification of poly(arylene ether ketone) powders

An impregnated fibrous material comprising a fibrous material made of continuous fiber and at least one thermoplastic polymer matrix, wherein the at least one thermoplastic polymer is an non-reactive amorphous polymer, the glass transition temperature of which is such that Tg&#x2265;80&#xb0; C., or a non-reactive semi-crystalline polymer, the melting temperature of which is Tf&#x2265;150&#xb0; C., the fiber volume ratio is constant in at least 70% of the volume of the tape or ribbon, the fiber ratio in the pre-impregnated fibrous material ranging from 45 to 65% by volume, the porosity rate in the pre-impregnated fibrous material being less than 10%.

Fibrous material impregnated with thermoplastic polymer

The invention concerns to the use of a powder comprising 99.95 to 95% of at least one polyamide and 0.05 to 5% of at least one silane for coating metals. This powder may be prepared by simple dry blending of the constituents. The silane can also be added to the molten polyamide in a mixing device and the resulting product reduced to powder. The addition of silane makes it possible to significantly improve electrostatic application by preventing a substantial portion of the powder from falling off during the electrostatic discharge which follows application, while providing lasting adhesion between the coating and metal. Advantageously, the silane is chosen from aminopropyltriethoxysilane and aminopropyltrimethoxysilane. The invention also concerns a method of coating an object with a film resulting from melting a thin layer of the powder.

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Fontaine sous Jouy, France

Denis Huze